• Computers and Concrete
• /
• v.6 no.6
• /
• pp.491-503
• /
• 2009

This paper presents a design framework developed using axiomatic design (AD) theory that can be applied in the design process of porous concrete. The main contribution of this paper is the definition of an AD framework based on the needs and functional requirements of porous concrete. The framework shows how AD theory can be used to provide guidelines for proportioning and manufacturing porous concrete. The advantage of the AD approach is that it systemizes the way to decouple design parameters and makes designers to think rationally between what we want to achieve and how we propose to satisfy the functional requirements of porous concrete. In this paper, test results of laboratory-size porous concrete specimens under compression were analyzed to evaluate the performance of the porous concrete based on the desired functional requirements.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.8
• /
• pp.2773-2776
• /
• 2012

• Journal of the Korean Applied Science and Technology
• /
• v.37 no.5
• /
• pp.1200-1207
• /
• 2020

We have fabricated the supercapacitor composed of porous activated carbon, metal-organic framework (MOF) with polymer based solid state electrolyte as a "ion gel" and characterized its electrochemical behaviour as a function of the MOF contents. The electrochemical properties of the supercapacitor were analyzed via cyclic voltammetry(CV), electrochemical impedance spectroscopy(EIS) and galvanostatic charge/discharge test. As a results, the supercapacitor based on porous activated carbon/MOF composite showed the highest capacitance value at 0.5 wt% of MOF contents and decreased capacitance with increase MOF contents over the 0.5 wt%. Consequently, the porous activated carbon/MOF composite based supercapacitor is applicable to various aspect for energy storage device.

• Coupled systems mechanics
• /
• v.3 no.1
• /
• pp.27-52
• /
• 2014

For landfill monitoring and aftercare, long-term prognoses of emission and deformation behaviour are required. Landfills may be considered as heterogeneous porous soil-like structures, in which flow and transport processes of gases and liquids interact with local material degradation and mechanical deformation of the solid skeleton. Therefore, in the framework of continuous porous media mechanics a model is developed that permits the investigation of coupled mechanical, hydraulical and biochemical processes in municipal solid waste landfills.

• Carbon letters
• /
• v.4 no.1
• /
• pp.1-9
• /
• 2003

Recently, the control of pore-characteristics of nano-porous materials has been studied extensively because of their unique applications, which includes size-selective separation, gas adsorption/storage, heterogeneous catalysis, etc. The most widely adopted techniques for controlling pore characteristics include the utilization of pillar effect by metal oxide and of templates such as zeolites. More recently, coordination polymers constructed by transition metal ions and bridging organic ligands have afforded new types of nano-porous materials, porous metal-organic framework(porous MOF), with high degree and uniformity of porosity. The pore characteristics of these porous MOFs can be designed by controlling the coordination number and geometry of selected metal, e.g transition metal and rare-earth metal, and the size, rigidity, and coordination site of ligand. The synthesis of porous MOF by the assembly of metal ions with di-, tri-, and poly-topic N-bound organic linkers such as 4,4'-bipyridine(BPY) or multidentate linkers such as carboxylates, which allow for the formation of more rigid frameworks due to their ability to aggregate metal ions into M-O-C cluster, have been reported. Other porous MOF from co-ligand system or the ligand with both C-O and C-N type linkage can afford to control the shape and size of pores. Furthermore, for the rigidity and thermal stability of porous MOF, ring-type ligand such as porphyrin derivatives and ligands with ability of secondary bonding such as hydrogen and ionic bonding have been studied.

• Journal of Industrial and Engineering Chemistry
• /
• v.67
• /
• pp.373-379
• /
• 2018

A transparent, freestanding Porous Aromatic Framework-97 (PAF-97) membrane was successfully synthesized via a one-step acid-catalyzed reaction. Due to the introduction of ether groups, the obtained PAF-97 membrane possesses enhanced structural flexibility, thus increasing the flexibility of the resulting membrane. This is proofed by the fact that the feeding pressure of the membrane reaches as high as 5.5 bar during the separation of gas mixtures. The Young's moduli of the membrane were 6.615 GPa and 11.11 GPa, either in a dry or hydrated state respectively. To be highlighted, under a feeding pressure of 3.6 bar, the PAF-97 membrane rendered the permeance values of $2.90{\times}10^{-7}$, $1.29{\times}10^{-8}mol\;m^{-2}s^{-1}Pa^{-1}$ for $CO_2$ and $CH_4$, respectively, with a $CO_2/CH_4$ permselectivity of 22.48.

• Steel and Composite Structures
• /
• v.44 no.5
• /
• pp.651-676
• /
• 2022

Most of the experimental, theoretical, and numerical studies on the stability of functionally graded composites are deterministic, while there are full of complex interactions of variables with an inherently probabilistic nature, this paper presents a non-intrusive framework to investigate the stochastic nonlinear buckling behaviors of porous functionally graded cylindrical shells exposed to inevitable source-uncertainties. Euler-Lagrange equations are theoretically derived based on the three variable refined shear deformation theory. Closed-form solutions for the shell buckling loads are achieved by solving the deterministic eigenvalue problems. The analytical results are verified with numerical results obtained from finite element analyses that are conducted in the commercial software ABAQUS. The non-intrusive framework is completed by integrating the Monte Carlo simulation with the verified closed-form solutions. The convergence studies are performed to determine the effective pseudorandom draws of the simulation. The accuracy and efficiency of the framework are verified with statistical results that are obtained from the first and second-order perturbation techniques. Eleven cases of individual and compound uncertainties are investigated. Sensitivity analyses are conducted to figure out the five cases that have profound perturbative effects on the shell buckling loads. Complete probability distributions of the first three critical buckling loads are completely presented for each profound uncertainty case. The effects of the shell thickness, volume fraction index, and stochasticity degree on the shell buckling load under compound uncertainties are studied. There is a high probability that the shell has non-unique buckling modes in stochastic environments, which should be known for reliable analysis and design of engineering structures.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.1
• /
• pp.283-285
• /
• 2014

• Journal of Ocean Engineering and Technology
• /
• v.23 no.6
• /
• pp.23-31
• /
• 2009

The interaction of incident monochromatic waves with a bottom-mounted vertical porous circular cylinder is investigated using the framework of the three-dimensional linear potential theory. The porosity of the circular cylinder is uniform vertically but varies in the circumferential direction. By adjusting the porosities of the circular cylinder, both the wave blocking performance of a porous semi-circular breakwater and the wave responses inside a circular harbor with an entrance are applied as calculation examples. It is found that the reflected waves, wave run-up, and wave forces are significantly reduced due to wall porosity, which are positive factors for a breakwater, and the amplification factor of a circular harbor at resonant frequencies is greatly reduced by a porous sidewall.

• Ocean Systems Engineering
• /
• v.12 no.1
• /
• pp.63-86
• /
• 2022

A refined projection-based purely Lagrangian meshfree method is presented towards reliable numerical analysis of fluid flow interactions with saturated/unsaturated porous media of uniform/spatially-varying porosities. The governing equations are reformulated on the basis of two-phase mixture theory with incorporation of volume fraction. These principal equations of mixture are discretized in the context of Incompressible SPH (Smoothed Particle Hydrodynamics) method. Associated with the consideration of governing equations of mixture, a new term arises in the source term of PPE (Poisson Pressure Equation), resulting in modified source term. The linear and nonlinear force terms are included in momentum equation to represent the resistance from porous media. Volume increase of fluid particles are taken into consideration on account of the presence of porous media, and hence multi-resolution ISPH framework is also incorporated. The stability and accuracy of the proposed method are thoroughly examined by reproducing several numerical examples including the interactions between fluid flow and saturated/unsaturated porous media of uniform/spatially-varying porosities. The method shows continuous pressure field, smooth variations of particle volumes and regular distributions of particles at the interface between fluid and porous media.