• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.467-467
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• 2011

Reflecting the growing importance of nanomaterials in science and technology, controlling the porosity combined with well-defined structural properties has been an ever-demanding pursuit in the related fields of frontier researches. A number of reports have focused on the synthesis of various nanoporous materials so far and, recently, the nanomaterials with multimodal porosity are getting an emerging importance due to their improved material properties compared with the mono porous materials. However, most of those materials are obtained in bulk phases while the spherical nanoparticles are one of the most practical platforms in a great number of applications. Here, we report on the synthesis of the core-shell silica nanoparticles with double mesoporous shells (DMSs). The DMS nsnoparticles are spherical and monodispersive and have two different mesoporous shells, i.e., the bimodal porosity. It is the first example of the core-shell silica nanoparticles with the different mesopores coexisting in the individual nanoparticles. Furthermore, the carbon and silica hollow capsules were also fabricated via a serial replication process.

• Nuclear Engineering and Technology
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• 제50권2호
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• pp.297-305
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• 2018

Fuel assembly (FA) bow in pressurized water reactor (PWR) cores is considered to be a complex process with a large number of influencing mechanisms and several unknowns. Uncertainty and sensitivity analyses are a common way to assess the predictability of such complex phenomena. To perform such analyses, a structural model of a row of 15 FAs in the reactor core is implemented with the finite-element code ANSYS Mechanical APDL. The distribution of lateral hydraulic forces within the core row is estimated based on a two-dimensional Computational Fluid Dynamics model with porous media, assuming symmetric or asymmetric core inlet and outlet flow profiles. The influence of the creep rate on the bow amplitude is tested based on different creep models for guide tubes and fuel rods. Different FA initial states are considered: fresh FAs or FAs with higher burnup, which may be initially straight or exhibit an initial bow from previous cycles. The simulation results over one reactor cycle demonstrate that changes in the creep rate and the hydraulic conditions may have a considerable impact on the bow amplitudes and the bow patterns. A good knowledge of the specific creep behavior and the hydraulic conditions is therefore crucial for making reliable predictions.

• 한국재료학회지
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• 제20권12호
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• pp.691-698
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• 2010

Magnesium hydroxide-melamine core-shell particles were prepared through the coating of melamine monomer on the surface of magnesium hydroxide in the presence of phosphoric acid. The melamine monomer was dissolved in hot water but recrystallized on the surface of magnesium hydroxide by quenching to room temperature in the presence of phosphoric acid. The core-shell particle was applied to low-density polyethylene/ ethylene vinyl acetate (LDPE/EVA) resin by melt-compounding at $180^{\circ}C$ as flame retardant. The effect of magnesium hydroxide and melamine content has been studied on the flame retardancy of the core-shell particles in LDPE/EVA resin according to the preparation process and purity of magnesium hydroxide. Magnesium hydroxide prepared with sodium hydroxide rather than with ammonia solution revealed higher flame retardancy in core-shell particles with LDPE/EVA resin. At 50 wt% loading of flame retardant, core-shell particles revealed higher flame retardancy compared to that of the exclusive magnesium hydroxide in LDPE/EVA composite, and it was possible to satisfy the V0 grade in the UL-94 vertical test. The synergistic flame retardant effect of magnesium hydroxide and melamine core-shell particles was explained as being due to the endothermic decomposition of magnesium hydroxide and melamine, which was followed by the evolution of water from the magnesium hydroxide and porous char formation due to reactive nitrogen compounds, and carbon dioxide generated from melamine.

• Advances in nano research
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• 제10권2호
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• pp.115-128
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• 2021

In this article, free vibration behavior of electro-magneto-thermo sandwich Timoshenko beam made of porous core and Graphene Platelet Reinforced Composite (GPLRC) in a thermal environment is investigated. The governing equations of motion are derived by using the modified strain gradient theory for micro structures and Hamilton's principle. The magneto electro are under linear function along the thickness that contains magnetic and electric constant potentials and a cosine function. The effects of material length scale parameters, temperature change, various distributions of porous, different distributions of graphene platelets and thickness ratio on the natural frequency of Timoshenko beam are analyzed. The results show that an increase in aspect ratio, the temperature change, and the thickness of GPL leads to reduce the natural frequency; while vice versa for porous coefficient, volume fractions and length of GPL. Moreover, the effect of different size-dependent theories such as CT, MCST and MSGT on the natural frequency is investigated. It reveals that MSGT and CT have most and lowest values of natural frequency, respectively, because MSGT leads to increase the stiffness of micro Timoshenko sandwich beam by considering three material length scale parameters. It is seen that by increasing porosity coefficient, the natural frequency increases because both stiffness and mass matrices decreases, but the effect of reduction of mass matrix is more than stiffness matrix. Considering the piezo magneto-electric layers lead to enhance the stiffness of a micro beam, thus the natural frequency increases. It can be seen that with increasing of the value of WGPL, the stiffness of microbeam increases. As a result, the value of natural frequency enhances. It is shown that in hc/h = 0.7, the natural frequency for WGPL = 0.05 is 8% and 14% less than its for WGPL = 0.06 and WGPL = 0.07, respectively. The results show that with an increment in the length and width of GPLs, the natural frequency increases because the stiffness of micro structures enhances and vice versa for thickness of GPLs. It can be seen that the natural frequency for aGPL = 25 ㎛ and hc/h = 0.6 is 0.3% and 1% more than the one for aGPL = 5 ㎛ and aGPL = 1 ㎛, respectively.

• 대한기계학회논문집B
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• 제38권3호
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• pp.271-277
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• 2014

원자로 노심 입구에 위치한 내부 구조물들은 형상 및 노심 입구까지의 상대적 거리에 따라 노심 입구 유량분포에 상당한 영향을 미칠 수 있다. 본 연구에서는 원자로 내부 구조물 형상 처리 방법이 축소 APR+ 유동분포 예측 정확도에 미치는 영향을 조사하기 위해 상용 전산유체역학 소프트웨어인 ANSYS CFX R.14를 사용하여 원자로 내부 구조물들의 실제 형상을 고려한 계산을 수행하였고 다공성 매질 가정을 적용한 계산 결과와 비교하였다. 결론적으로 노심 입구 상류에 위치한 원자로 내부 구조물의 실제 형상을 고려함으로써 노심 입구 유량 분포를 더 정확하게 예측할 수 있었다. 따라서 충분한 계산 자원이 확보된 조건인 경우라면 정확한 노심 입구 유량분포를 계산하기 위해 노심 입구 상류에 위치한 원자로 내부 구조물들(예: 하부지지구조물 바닥판 및 노내 계측기 노즐 지지판)의 실제 형상을 고려해서 계산하는 것이 필요하다.

• Structural Engineering and Mechanics
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• 제85권5호
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• pp.593-605
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• 2023

This work presents a comparison between analytical and finite element analysis for bending of porous sandwich functionally graded material (FGM) plates. The plate is rectangular and simply supported under static sinusoidal loading. Material properties of FGM are assumed to vary continuously across the face sheets thickness according to a power-law function in terms of the volume fractions of the constituents while the core is homogeneous. Four types of porosity are considered. A refined higher-order shear with normal deformation theory is used. The number of unknowns in this theory is five, as against six or more in other shear and normal deformation theories. This theory assumes the nonlinear variation of transverse shear stresses and satisfies its nullity in the top and bottom surfaces of the plate without the use of a shear correction factor. The governing equations of equilibrium are derived from the virtual work principle. The Navier approach is used to solve equilibrium equations. The constitutive law of the porous FGM sandwich plate is implemented for a 3D finite element through a subroutine in FORTRAN (UMAT) in Abaqus software. Results show good agreement between the finite element model and the analytical method for some results, but the analytical method keeps giving symmetric results even with the thickness stretching effect and load applied to the top surface of the sandwich.

• Archives of Pharmacal Research
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• 제8권1호
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• pp.7-14
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• 1985

Membrane-coated tablet of isonicotinic acid hydrazide (INAH) which releases INAH at the zero-order kinetics was deveoped. It consisted of a soluble tablet core surrounded by a porous membrane which controls the diffusion rate. Tablet cores were prepared by compressing granules of INAH and polyvinyl chloride (PVC) dissolved in methyl ethyl ketone in which micronized sucrose were suspended. Diffusion rate of INAH from the tablet through the membrane was constant until the loaded INAH in the core was almost released. The rate was independent of pH of the dissolution medium. Water-soluble sucrose particles behaved as a poreproducing material in the water-insoluble PVC film coat. The pH independency of the rate was probably due to the high solubility of INAH in the water of wide pH range. The diffusion rate of INAH could be controlled by chnaging the composition of the membrane or the coat weight. This membrane-coated INAH tablet seemed to be a powerful candidate for the controlled release drug delivery system (DDS) of INAH or other highly watersoluble drugs.

• Nuclear Engineering and Technology
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• 제38권8호
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• pp.733-752
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• 2006

Severe accidents in PWRs are characterized by a continuously changing geometry of the core due to chemical reactions, melting and mechanical failure of the rods and other structures. These local variations of the porosity and other parameters lead to multi-dimensionnal flows and heat transfers. In this paper, a comprehensive set of multi-dimensionnal models describing heat transfers, thermal-hydraulics and melt relocation in a reactor vessel is presented. Those models are suitable for the core description during a severe accident transient. A series of applications at the reactor scale shows the benefits of using such models.

• Archives of Pharmacal Research
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• 제5권2호
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• pp.61-70
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• 1982

Sulfisoxazole, a chemotherapeutic agent, was microencapsulated with ethylcellulose by means of phase separation form cyclohexane by temperatture change. The size distribution was determined by use of standard sieves and the effect of core to wall ratio was noted. To examine their shapes and usrface characteristics, the microcapsules were observed with a scanning electron microscope. Release of the drug from microcapsules into pH 7.5 buffer medium was studied. The release pattern was found to have similar properties to the release of a drug from an insoluble porous matrix reported. The apparent diffusion coefficient of sulfisoxazole was measured for the transport of the drug from the core of microcapsules into the surronding sink condition. The apparent diffusion coefficient increased with increasing capsule size.

• Advances in environmental research
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• 제4권2호
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• pp.69-81
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• 2015

A new magnetite-silica core/shell nanocomposite ($Fe_3O4@nSiO_2@mSiO_2$) was synthesized and functionalized with trimethylchlorosilane (TMCS). The prepared nanocomposite was used for the removal of diesel oil from aqueous media. The characterization of magnetite-silica nanocomposite was studied by X-ray diffraction (XRD), Fourier transform infrared (FTIR), transmission electron microscopy (TEM), surface area measurement, and vibrating sample magnetization (VSM). Results have shown that the desired structure was obtained and surface modification was successfully carried out. FTIR analysis has confirmed the presence of TMCS on the surface of magnetite silica nanocomposites. The low- angle XRD pattern of nanocomposites indicated the mesoscopic structure of silica shell. Furthermore, TEM results have shown the core/shell structure with porous silica shell. Adsorption kinetic studies indicated that the nanocomposite was able to remove 80% of the oil contaminant during 2 h and fit well with the pseudo-second order model. Equilibrium studies at room temperature showed that the experimental data fitted well with Freundlich isotherm. The magnetic property of nanocomposite facilitated the separation of solid phase from aqueous solution.