• Title/Summary/Keyword: Porous compact

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A Numerical Study on the Design of a Central Flow Distributor Device Stabilizing Flow Uniformity in a vehicular fuel cell stack (차량용 연료전지 스택의 안정적 반응 가스 공급을 위한 중앙 유동 분배기 형상 설계에 관한 수치적 연구)

  • Jung, Hye-Mi;Um, Suk-Kee;Jeong, Hui-Seok;Lee, Seong-Ho;Seo, Jeong-Do;Son, Yeong-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.554-557
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    • 2008
  • In this study, two types of central flow distributor designs are presented and compared to obtain the optimal compact design which has the least flow resistance and the uniform flow distribution in a vehicular fuel cell stack. For effective and reliable prediction on the thermo-flow characteristics of the reactants flow over the entire fuel cell stack domain, open channel flow in the bipolar plates of the power generating cells were simulated by applying a simplified flow resistance model with an empirical porous concept. A number of case studies were performed to figure out an optimal configuration of a central flow distributor device in terms of the time-dependent thermo-flow behavior and load-dependent flow distribution. The results showed that the stable and load-independent thermo-flow uniformity is very design specific, which is closely associated with the design of central manifolding devices in order to achieve the enhanced volumetric power density and the reliable long-lasting operating of fuel cells.

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A Method for Quantitative Measurement of Lateral Flow Immunoassay Using Color Camera (컬러 카메라를 이용한 측면유동 면역 어세이 정량분석 방법)

  • Park, Jongwon
    • Journal of Biomedical Engineering Research
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    • v.35 no.1
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    • pp.1-7
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    • 2014
  • Among semi-quantitative or fully quantitative lateral flow assay readers, an image sensor-based instrument has been widely used because of its simple setup, cheap sensor price, and compact equipment size. For all previous approaches, monochrome CCD or CMOS cameras were used for lateral flow assay imaging in which the overall intensities of all colors were taken into consideration to estimate the analyte content, although the analyte related color information is only limited to a narrow wavelength range. In the present work, we introduced a color CCD camera as a sensor and a color decomposition method to improve the sensitivity of the quantitative biosensor system which utilizes the lateral flow assay successfully. The proposed setup and image processing method were applied to achieve the quantification of imitatively dispensed particles on the surface of a porous membrane first, and the measurement result was then compared with that using a monochrome CCD. The compensation method was proposed in different illumination conditions. Eventually, the color decomposition method was introduced to the commercially available lateral flow immunochromatographic assay for the diagnosis of myocardial infarction. The measurement sensitivity utilizing the color image sensor is significantly improved since the slopes of the linear curve fit are enhanced from 0.0026 to 0.0040 and from 0.0802 to 0.1141 for myoglobin and creatine kinase (CK)-MB detection, respectively.

Consolidation to Bulk Ceramic Bodies from Oyster Shell Powder (굴 패각 분말로부터 벌크 세라믹 구조체 제조)

  • Cho, Kyeong-Sik;Lee, Hyun-Kwuon;Min, Jae Hong
    • Journal of Powder Materials
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    • v.23 no.3
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    • pp.221-227
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    • 2016
  • Waste oyster shells create several serious problems; however, only some parts of them are being utilized currently. The ideal solution would be to convert the waste shells into a product that is both environmentally beneficial and economically viable. An experimental study is carried out to investigate the recycling possibilities for oyster shell waste. Bulk ceramic bodies are produced from the oyster shell powder in three sequential processes. First, the shell powder is calcined to form calcium oxide CaO, which is then slaked by a slaking reaction with water to produce calcium hydroxide $Ca(OH)_2$. Then, calcium hydroxide powder is formed by uniaxial pressing. Finally, the calcium hydroxide compact is reconverted to calcium carbonate via a carbonation reaction with carbon dioxide released from the shell powder bed during firing at $550^{\circ}C$. The bulk body obtained from waste oyster shells could be utilized as a marine structural porous material.

Effect of Arsenic, Antimony, Bismuth and Lead on Passivation Behavior of Copper Anode (As, Sb, Bi, Pb가 조동의 부동태에 미치는 영향)

  • Ahana, Sung-Chen;Lee, Sang-Mun;Kim, Yong-Hwan;Chung, Won-Sub;Chung, Uoo-Chang
    • Journal of the Korean institute of surface engineering
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    • v.39 no.5
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    • pp.215-222
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    • 2006
  • The passivity behavior of copper anode containing impurities in copper sulfate solution for electrorefining process was studied at several different levels of impurities such as As, Sb, Bi and Pb. The passivity behavior was investigated by electrochemical techniques (galvanostatic, potentiodynamic and cyclic voltammetry tests) and surface analysis (optical microscopy, electron probe microanalysis, scanning electron microscopy). The results were that arsenic, antimony inhibited passivation and bismuth accelerated it and lead containing anode showed different passivity behavior from above anodes. The improved passivity characteristics could be explained by decrease in oxygen content in passivity film which resulted from a reaction among the impurities, oxygen and copper in the anode. The SEM image revealed that arsenic or antimony containing anode exhibited a porous passivity film and bismuth containing anode showed the compact passivity film and lead containing anode had loose passivity film on anode.

Pulverization and Densification Behavior of YAG Powder Synthesized by PVA Polymer Solution Method

  • Im, Hyun-Ho;Lee, Sang-Jin
    • Korean Journal of Materials Research
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    • v.30 no.11
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    • pp.573-580
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    • 2020
  • YAG (Yttrium Aluminum Garnet, Y3Al5O12) has excellent plasma resistance and recently has been used as an alternative to Y2O3 as a chamber coating material in the semiconductor process. However, due to the presence of an impurity phase and difficulties in synthesis and densification, many studies on YAG are being conducted. In this study, YAG powder is synthesized by an organic-inorganic complex solution synthesis method using PVA polymer. The PVA solution is added to the sol in which the metal nitrate salts are dissolved, and the precursor is calcined into a porous and soft YAG powder. By controlling the molecular weight and the amount of PVA polymer, the effect on the particle size and particle shape of the synthesized YAG powder is evaluated. The sintering behavior of the YAG powder compact according to PVA type and grinding time is studied through an examination of its microstructure. Single phase YAG is synthesized at relatively low temperature of 1,000 ℃ and can be pulverized to sub-micron size by ball milling. In addition, sintered YAG with a relative density of about 98 % is obtained by sintering at 1,650 ℃.

Multiepoch Optical Images of IRC+10216 Tell about the Central Star and the Adjacent Environment

  • Kim, Hyosun;Lee, Ho-Gyu;Ohyama, Youichi;Kim, Ji Hoon;Scicluna, Peter;Chu, You-Hua;Mauron, Nicolas;Ueta, Toshiya
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.2
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    • pp.36.1-37
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    • 2021
  • Six images of IRC+10216 taken by the Hubble Space Telescope at three epochs in 2001, 2011, and 2016 are compared in the rest frame of the central carbon star. An accurate astrometry has been achieved with the help of Gaia Data Release 2. The positions of the carbon star in the individual epochs are determined using its known proper motion, defining the rest frame of the star. In 2016, a local brightness peak with compact and red nature is detected at the stellar position. A comparison of the color maps between 2016 and 2011 epochs reveals that the reddest spot moved along with the star, suggesting a possibility of its being the dusty material surrounding the carbon star. Relatively red, ambient region is distributed in an Ω shape and well corresponds to the dusty disk previously suggested based on near-infrared polarization observations. In a larger scale, differential proper motion of multiple ring-like pattern in the rest frame of the star is used to derive the average expansion velocity of transverse wind components, resulting in ~12.5 km s-1 (d/123 pc), where d is the distance to IRC+10216. Three dimensional geometry is implied from its comparison with the line-of-sight wind velocity determined from half-widths of submillimeter emission line profiles of abundant molecules. Uneven temporal variations in brightness for different searchlight beams and anisotropic distribution of extended halo are revisited in the context of the stellar light illumination through a porous envelope with postulated longer-term variations for a period of 10 years.

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Effect of Partially Oxidized Ti Powder on Electrical Properties and Microstructures of $BaTiO_3$-based Ceramics ($BaTiO_3$계 세라믹스의 전기적 성질과 미세조직에 미치는 부분산화 Ti 분말 첨가의 영향)

  • Kim, Jun-Gyu;Jo, Won-Seung;Park, Gyeong-Sun
    • Korean Journal of Materials Research
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    • v.10 no.10
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    • pp.671-676
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    • 2000
  • $BaTiO_3$-based ceramics with partially oxidized Ti powders were prepared by sintering at $1350^{\circ}C$ for 1 h in v vacuum, and then heated in air. In this study, the effect of partially oxidized Ti powders on electrical properties and microstructures of $BaTiO_3$-based ceramics was investigated. It was found out that the semiconductive $BaTiO_3$-based ceramics beζame to show excellent PTCR (more than $10^5$) characteristic by adding 5~7 vol% of partially oxidized Ti powder. Also, it was found out that the sintered compact had extremely porous and fine-grained microstructure. The relative density and grain size of sintered compact with 5 vol% of partially oxidized Ti powders were 54% and $1.3\;{\mu\textrm{m}}$, respectively. The mechanism for the development of PTCR characteristic in $BaTiO_3$-based ceramics with partially oxidized Ti powders due to the adsorption of oxygen at grain boundaries, and could be explained, based on Heywang model.

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Surface Protection Obtained by Anodic Oxidation of New Ti-Ta-Zr Alloy

  • Vasilescu, C.;Drob, S.I.;Calderon Moreno, J.M.;Drob, P.;Popa, M.;Vasilescu, E.
    • Corrosion Science and Technology
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    • v.17 no.2
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    • pp.45-53
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    • 2018
  • A new 80Ti-15Ta-5Zr wt% alloy surface was protected by anodic oxidation in phosphoric acid solution. The protective oxide layer (TiO2, ZrO2 and Ta suboxides and thickness of 15.5 nm) incorporated $PO{_4}^{3-}$ ions from the solution, according to high resolution XPS spectra. The AFM analysis determined a high roughness with SEM detected pores (20 - 50 nm). The electrochemical studies of bare and anodically oxidized Ti-15Ta-5Zr alloy in Carter-Brugirard saliva of different pH values and saliva with 0.05M NaF, pointed to a nobler surface for the protected alloy, with a thicker electrodeposited oxide layer acting as a barrier against aggressive ions. The oxidized alloy significantly decreased corrosion current densities and total quantity of ions released into the oral environment in comparison with the bare one, at higher polarisation resistance and protective capacity of the electrodeposited layer. The impedance data revealed a bi-layered oxidation film formed by: a dense, compact, barrier layer in contact with the metallic substrate, decreasing the potential gradient across the metal/oxide layer/solution interface, reducing the anodic dissolution and a more permissive, porous layer in contact with the electrolyte. The open circuit potential for protected alloy shifted to nobler values, with thickening of the oxidation film signifying long-term protection.

Development of Specific Organ-Targeting Drug Delivery System (III)-In Vitro Study on Liver-Targeting Adriamycin Delivery System using Human Serum Albumin Microspheres- (장기표적용 약물수송체의 개발에 관한 연구(제 3보 -알부민 미립구를 이용한 Adriamycin의 간 표적용 수송체에 관한 in vitro 연구-)

  • Kim, Chong-Kook;Hwang, Sung-Joo;Yang, Ji-Sun
    • Journal of Pharmaceutical Investigation
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    • v.19 no.4
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    • pp.195-202
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    • 1989
  • In attempt to improve the chemotherapeutic activity of adriamycin, adriamycin-entrapped HSA microspheres were prepared and investigated by the various in vitro experiments. The shape, surface characteristics and size distribution of HSA microspheres are observed by scanning electron microscopy. The in vitro drug release, albumin matrix degradation by protease of HSA microspheres were studied. The shape of HSA microspheres were spherical and the surface was smooth and compact. The size of HSA microspheres ranged from 0.4 to $2.5\;{\mu}m$ and have average diameters of 0.5 to $0.7\;{\mu}m$. The size distribution of HSA microspheres prepared by ultrasonication was mainly affected by albumin concentration and heating time in the process of hardening. In in vitro, almost all adriamycin was released from HSA microspheres for 8 hr. Analysis of the resulting adriamycin release profiles demonstrated that adriamycin is released from the microspheres in two distinct steps, a fast phase (until 30 min) followed by a much slower sustained release phase. Drug release, which is due to diffusion, was depended on the rate of matrix hydration. Drug release was largely affected by albumin concentration and heating temperature during the process of hardening. Albumin matrix degradation of HSA microspheres was affected by heating temperature and albumin concentration. Higher temperature and longer times generally produce harder, less porous, and slowly degradable microspheres.

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Modeling and validation of a parabolic solar collector with a heat pipe absorber

  • Ismail, Kamal A.R.;Zanardi, Mauricio A.;Lino, Fatima A.M.
    • Advances in Energy Research
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    • v.4 no.4
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    • pp.299-323
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    • 2016
  • Cylindrical parabolic solar concentrators of small concentration ratio are attractive options for working temperatures around $120^{\circ}C$. The heat gained can be utilized in many applications such as air conditioning, space heating, heating water and many others. These collectors can be easily manufactured and do not need to track the sun continuously. Using a heat pipe as a solar absorber makes the system more compact and easy to install. This study is devoted to modeling a system of cylindrical parabolic solar concentrators of small concentration ratio (around 5) fitted with a heat pipe absorber with a porous wick. The heat pipe is surrounded by evacuated glass tube to reduce thermal losses from the heat pipe. The liquid and vapor flow equations, energy equation, the internal and external boundary conditions were taken into consideration. The system of equations was solved and the numerical results were validated against available experimental and numerical results. The validated heat pipe model was inserted in an evacuated transparent glass tube as the absorber of the cylindrical parabolic collector. A calculation procedure was developed for the system, a computer program was developed and tested and numerical simulations were realized for the whole system. An experimental solar collector of small concentration, fitted with evacuated tube heat pipe absorber was constructed and instrumented. Experiments were realized with the concentrator axis along the E-W direction. Results of the instantaneous efficiency and heat gain were compared with numerical simulations realized under the same conditions and reasonably good agreement was found.