• Title/Summary/Keyword: Porous Membrane

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Effects of Nickel Supports on Hydrogen Permeability of Vanadium based Membrane (니켈 지지체를 이용한 바나듐기 분리막의 수소 투과특성)

  • Cho, Kyoungwon;Choi, Jaeha;Jung, Seok;Kim, Raymundk.I.;Hong, Taewhan;Ahn, Joongwoo
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.3
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    • pp.200-205
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    • 2013
  • The separation of hydrogen depends on porosity, diffusivity and solubility in permeation membrane. Dense membrane is always showing a solution diffusion mechanism but porous membrane is not showing. Therefore, porous membrane has a good hydrogen flux due to pore is carried out transferred media. This mechanism is named as the Knudsen diffusion. Hydrogen molecules or hydrogen atoms are diffused along pore that is a mean free path. In this study, complex layer hydrogen permeation membrane was fabricated by hot press process. And then, it was evaluated and calculated to relationship between hydrogen permeability and membrane porosity.

Modeling of Water Transport in Porous Membrane for PEMFC Humidifer (PEMFC 가습기 용 다공성 중공사막의 물전달 모델링)

  • Hwang, Jun Y.;Park, J.Y.;Kang, K.;Kim, J.H.;Kim, K.J.;Lee, M.S.
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.96.2-96.2
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    • 2011
  • Water transport through the microporous membrane was modeled considering capillary condensation as well as capillary flow in porous media as a function of pore diameter and relative humidity at the surface. The present model was adopted by the numerical simulation of non-isothermal, non-homogenous flow in a shell and tube typed gas to gas membrane humidifier for PEMFC (proton exchange membrane fuel cell) and the result shows good agreement with experimental data.

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Submerged Horizontal and Vertical Membrane Wave Barrier

  • Kee S.T.
    • Journal of Ocean Engineering and Technology
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    • v.19 no.2 s.63
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    • pp.1-11
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    • 2005
  • In the present paper, the hydrodynamic properties of a Rahmen type flexible porous breakwater with dual fixed pontoon system interacting with obliquely or normally incident small amplitude waves are numerically investigated. This system is composed of dual vertical porous membranes hinged at the side edges of dual fixed pontoons, and a submerged horizontal membrane that both ends are hinged at the steel frames mounted pontoons. The dual vertical membranes are extended downward and hinged at bottom steal frame fixed into seabed. The wave blocking and dissipation mechanism and its effects of permeability, Rahmen type membrane and pontoon geometry, pretensions on membranes, relative dimensionless wave number, and incident wave headings are thoroughly examined.

Fabrication of Micro-Porous Membrane via a Solution Spreading Phase Inversion Method (용액 퍼짐 상분리법을 통한 마이크로 기공 분리막 제조)

  • Choi, Ook;Park, Chul Ho
    • Membrane Journal
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    • v.29 no.2
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    • pp.105-110
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    • 2019
  • Porous membranes are widely used in industry for removing particulate matter. Unlike conventional porous membrane fabrication methods, the solution spreading phase separation method can form pores very simply. The first step is to wet the mesh with the support layer, then to let the polysulfone solution flow into a solvent without water. The solvent is readily vaporized and the polysulfone is made into a thin film. When the polysulfone solution is mixed with water to form pores, the pore size can be adjusted according to the concentration ratio of the polysulfone solution. The thickness of the membrane is easily controlled by the concentration of the solution. The porous separator has the formation of meshes intact and is very useful for forming a three-dimensional structure. The solution spreading phase separation method proposed in this study is characterized by its high cost competitiveness compared with conventional membranes due to its low production cost and easy process control.

Exophytic bone formation using porous titanium membrane combined with pins in rabbit calvarium. (핀 고정 천공형 티타늄막을 이용한 수직적 체조제증대술에 관한 연구)

  • Kim, Young;Kwon, Young-Hyuk;Park, Joon-Bong;Herr, Yeek;Chung, Jong-Hyuk
    • Journal of Periodontal and Implant Science
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    • v.36 no.2
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    • pp.273-288
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    • 2006
  • The purpose of this study was to evaluate exophytically vertical bone formation in rabbit calvaria by the concept of guided bone regeneration with a custom-made porous titanium membrane combined with bone graft materials. For this purpose, a total of 12 rabbits were used, and decorticated calvaria were created with round carbide bur to promote bleeding and blood clot formation in the wound area. Porous titanium membranes (0.5 mm in pore diameter, 10 mm in one side, 2 mm in inner height) were placed on the decorticated calvaria, fixed with metal pins and covered with full-thickness flap. Experimental group I was treated as titanium membrane only. Experimental group II, III, IV was treated as titanium membrane with BBM, titanium membrane with DFDB and titanium membrane with FDB. The animals were sacrificed at 8 and 12 weeks after surgery, and new bone formation was assessed by histomorphometric as well as statistical analysis. 1. Porous titanium membrane was biocompatable and capable of maintaining the regeneration space. 2. At 8 and 12 weeks, all groups demonstrated exophytic bone formation and there was a statistical significant difference among different groups only at 12 weeks. 3. The DFDB group revealed the most new bone formation compared to other groups (p<0.05). 4. At 12 weeks, DFDB and FDB groups showed the most significant resorption of graft materials (p<0.05). 5. The BBM was not resorbed at all until 12 weeks. 6. The fixation metal pin revealed excellent effect in peripheral sealing. On the basis of these findings, we conclude that a porous titanium membrane may be used as an augmentation membrane for guided bone regeneration, and DFDB as an effective bone forming graft material. The fixation of the membrane with pin will be helpful in GBR technique. However, further study is required to examine their efficacy in the intraoral experiments.

Submerged Membrane Breakwaters I: A Rahmen Type System Composed of Horizontal and Vertical Membranes

  • Kee, Sung-Tae
    • International Journal of Ocean Engineering and Technology Speciallssue:Selected Papers
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    • v.5 no.1
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    • pp.14-21
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    • 2002
  • In the present paper, the hydrodynamic properties of a Rahmen-type, flexible, porous breakwater interacting with obliquely or normal- incident small amplitude waves are numerically investigated. This system is composed of dual vertical porous membranes, hinged at the side edges of a submerged horizontal membrane. The dual vertical membranes are extended downward and hinged at seabed. The effects of permeability, Rahmen-type membrane breakwater geometry, pre-tensions on membranes, relative dimensionless wave number, and incident wave headings are thoroughly examined.

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Fabrication of triazine-based Porous Aromatic Framework (PAF) membrane with structural flexibility for gas mixtures separation

  • Wang, Lei;Jia, Jiangtao;Faheem, Muhammad;Tian, Yuyang;Zhu, Guangshan
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.373-379
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    • 2018
  • A transparent, freestanding Porous Aromatic Framework-97 (PAF-97) membrane was successfully synthesized via a one-step acid-catalyzed reaction. Due to the introduction of ether groups, the obtained PAF-97 membrane possesses enhanced structural flexibility, thus increasing the flexibility of the resulting membrane. This is proofed by the fact that the feeding pressure of the membrane reaches as high as 5.5 bar during the separation of gas mixtures. The Young's moduli of the membrane were 6.615 GPa and 11.11 GPa, either in a dry or hydrated state respectively. To be highlighted, under a feeding pressure of 3.6 bar, the PAF-97 membrane rendered the permeance values of $2.90{\times}10^{-7}$, $1.29{\times}10^{-8}mol\;m^{-2}s^{-1}Pa^{-1}$ for $CO_2$ and $CH_4$, respectively, with a $CO_2/CH_4$ permselectivity of 22.48.

Membrane for the Removal of Volatile Organic Compounds from Air (대기중의 휘발성 유기물 제거용 분리막)

  • Deng, S.;Lang, K.;Wang, J.;Tremblay, A.;Matsuura, T.
    • Membrane Journal
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    • v.7 no.1
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    • pp.22-30
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    • 1997
  • Porous asymmetric membranes were prepared from polyetherimide polymer by the phase-inversion technique under different conditions. The performance of the membranes was tested for the removal of acetone vapour from nitrogen. A membrane which showed a high acetone permeability and a high selectivity was chosen and tested further for the separation of different organic vapours from nitrogen. The molecular structure of organic vapours and the selectivity were correlated. A strong correlation was also found between the chromatographic retention time of the organic vapour and the selectivity. These experimental results led to the conclusion that the sorption is the factor governing the separation of volatile organic compounds from nitrogen. A membrane was also prepared by coating the surface of a porous polyetherimide membrane with silicone rubber. The performance of membranes with and without silicone rubber coating was compared.

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Preparation of Inorganic Ultrafiltration Membrane by Anodic Oxidation in Oxalic Acid (수산전해액하에서 양극산화에 의한 무기 UF막의 제조)

  • Lee, Chang-Woo;Hong, Young-Ho;Chang, Yoon-Ho;Hahm, Yeong-Min
    • Applied Chemistry for Engineering
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    • v.9 no.4
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    • pp.536-541
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    • 1998
  • The porous size alumina membrane was prepared by anodic oxidation with current method in an aqueous solution of oxalic acid. The aluminum metal plate was pretreated with thermal oxidation, chemical polishing and electropolishing before anodic oxidation. Membrane thickness and pore size distribution were investigated with several anodizing conditions; reaction temperature, cumulative charge, electrolyte concentration and current density. The porous alumina membrane obtained was $55{\sim}75{\mu}m$ thick with straight micropore of 45~100nm. Also, the porous alumina membrane has an uniform pore diameter and pore distribution. It was inorganic ultrafiltration membrane as a kind of the ceramic membrane.

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Responses of Submerged Double Hull Pontoon/Membrane Breakwater

  • Kee S.T.
    • Journal of Ocean Engineering and Technology
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    • v.19 no.2 s.63
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    • pp.19-28
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    • 2005
  • The present paper outlines the numerical investigation of the incident wave interactions with fully submerged and floating dual double hull pontoon/vertical porous membrane breakwaters. Two dimensional five fluid-domains hydro-elastic formulation was carried out in the context of linear wave body interaction theory to study the wave interaction with the double hull of pontoon-membranes. The submerged circular pontoon is consisted of double hulls, which is filled with water in the void space between the outer structure and inner solid buoyant structure. Hydrodynamic characteristics of the proposed system with dual floating double-hull-pontoons filled with water have been studied numerically for the various incident waves. This study is a beginning stage research for the dual double hull porous pontoons/vertical porous membranes breakwaters which is ideally designed in order to suppress significantly the transmitted and reflected waves simultaneously.