• 제목/요약/키워드: Porous Layer

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전기방사를 이용한 슈퍼캐퍼시터용 금속산화물/탄소나노섬유 복합체 (Electrospun Metal Oxide/Carbon Nanofiber Composite Electrode for Supercapacitor Application)

  • 양갑승;김보혜
    • 공업화학
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    • 제26권3호
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    • pp.239-246
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    • 2015
  • 나노 탄소재료를 복합화하면 기존 재료의 특성을 유지하면서 그 효율을 극대화할 수 있다. 여기에 이종원소를 부가하면 전기화학적인 특성이 디자인되므로, 나노 탄소재료의 복합화를 통해 한 종류의 나노 재료로부터 여러 강점을 얻을 수 있다. 특히 탄소나노섬유와 금속산화물을 복합화하면 탄소나노섬유의 전기이중층 뿐만 아니라 금속산화물의 산화 환원 반응을 이용하여 비축전 용량, 고율 특성, 수명 특성이 향상되고 높은 수준의 출력밀도가 유지되는 고용량 슈퍼 캐퍼시터용 전극 소재를 개발할 수 있다. 본 총설에서는 탄소의 고출력특성과 금속산화물의 고에너지 특성이 동시에 발현되는 금속산화물계 탄소나노섬유복합체의 제법과 응용에 대한 최신연구를 다루도록 하겠다.

융합형여과집진장치에서의 먼지입자와 원소수은의 제거 성능 특성 (Simultaneous Removal Characteristics of Particulate and Elemental Mercury in Convergence Particulate Collector)

  • 박영옥;정주영
    • 한국입자에어로졸학회지
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    • 제6권4호
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    • pp.173-183
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    • 2010
  • The high temperature pleated filter bags which were used during this study were made of pleated nonwoven fabric of heat and acid resistant polysulfonate fibers which can withstand the heat up to $300^{\circ}C$ and have a filtration area which is 3 to 5 times larger than the conventional round filter bags. Cartridge module packed with 3 kind of the sulfur impregnated activated-carbon based sorbents were inserted in the inner of the pleated filter bag. This type of pleated filter bag was designed to remove not only the particulate matter but also the gaseous elemental mercury. The electrostatic precipitator part can enhance the particulate removal efficiency and reduce the pressure drop of the pleated filter bag by agglomerated particles to form a more porous dust layer on the surface of the pleated bag which is increased the filter bag cleaning efficiency. In addition, the most of particles are separated from the flue gas stream through the cyclone and the electrostatic precipitator part which were installed at the lower part and main body part of the convergence particulate collector, respectively. Thus reduce particulate loading of the high temperature pleated filter bags were applied in this study to analyze the removal characteristics of particulate matter and gaseous elemental mercury.

말레에이트계 공중합체 I-l3막의 공기/물에서의 계면 특성 (The Air/water Interface Characteristics of Maleate Copolymer LB Films)

  • 신훈규;권영수;이범종;장정수;배진호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1995년도 춘계학술대회 논문집
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    • pp.220-223
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    • 1995
  • Stable polyion-complexed polymeric monolayrers were prepared by spreading perfluoroalkyl monomaleatd copolymers. C$_2$F$\_$8/MA-VE$_2$ and C$_2$F$\_$8/Mv-VE$_3$ on aqueous poly(allylamine) subphase. The monolayer properties have been studied by the surface pressure-area($\pi$-A) isotherms. The C$_2$F$\_$8/MA-VE$_3$containing longer oligoethyleneglycol pendant showed more expaned monolayer phase than the C$_2$F$\_$8/MA-VE$_2$ The polyion-complexed monolayers were transferable on various substrates, and the resulting Langmuir-Blodgett(LB) films were characterized b ET-IR spectroscopy and scanning electron microscopy(SEM) Two-dimensional crosslinking to from a polymer network was achieved by amide formation through heat treatment under vacuum with concurrent removel of perfluoroalkyl tails. SEM observation of this film ona porous membrane filter showed that the four layer film was sufficiently stable to cover the filter pore size of 0.1$\mu\textrm{m}$. The C$_2$F$\_$8/MA-VE$_3$revealed better covering capability than the C$_2$F$\_$8/MA-VE$_2$Immersion of this film in water or in benzend did not cause any change in its appearance and in FT-IR spectra.

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슬롯 형상이 경사충격파 간섭유동의 피동제어에 미치는 영향에 관한 연구 (Effects of Slot Configurations on the Passive Control of Oblique-Shock-Interaction Flows)

  • 장성하;이열
    • 한국항공우주학회지
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    • 제34권12호
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    • pp.18-24
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    • 2006
  • 슬롯과 다공판을 이용한 충격파와 난류 경계층 간섭유동의 피동제어에 관한 연구가 수행되었다. 슬롯의 다양한 형상 변화가 간섭유동에 미치는 영향이 관찰되었으며, 이를 위하여 간섭유동 후방에서 피토/벽압력 분포 및 쉴리렌, 유맥선, 오일막 간섭 줄무늬 형상과 같은 유동가시화 결과 등이 얻어졌다. 유동방향의 슬롯의 경우 간섭유동 후방에서 제어되지 않은 경우와 비교하여 보다 높은 피토압력이 국소적으로 관찰되었으나, 폭방향 슬롯제어는 전체적으로 제어되지 않은 경우에 비하여 피토압력 크기에서 큰 장점을 보이지 않았다.

다공벽을 이용한 충격파 강도의 피동제어 (Passive control of strength of shock wave)

  • 최영상;권순범;조철영
    • 대한기계학회논문집B
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    • 제21권1호
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    • pp.174-184
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    • 1997
  • A shock wave, being an irreversible process, gives rise to entropy increase. A great deal of effort has been made to control shock wave and boundary layer interaction related to energy losses as well as problems of vibration and noise. In the present study, tests are performed on a roof mounted half circular arc in an indraft type supersonic wind tunnel to evaluate the effects of porosity, length and depth of cavity in passive control of shock wave on the attenuation of shock strength by reviewing the measured static pressures at the porous wall and cavity. Also the flow field is visualized by a Schlieren system. The results show that in the present study the porosity of 8% produced the largest reduction of pressure fluctuations and that for the same porosity, the strength of shock wave decreases with the increasings of the depth and length of cavity.

플라즈마 제트에서의 분말 용융특성에 따른 Y2O3 코팅층의 미세조직 형성거동 (Effects of Powder Melting Degree on Microstructural Features of Plasma Sprayed Y2O3 Coating)

  • 강상운;백경호
    • 한국재료학회지
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    • 제26권5호
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    • pp.229-234
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    • 2016
  • In this study, the degree of particle melting in $Y_2O_3$ plasma spraying and its effects on coating characteristics have been investigated in terms of microstructural features, microhardness and scratch resistance. Plasma sprayed $Y_2O_3$ coatings were formed using two different powder feeding systems: a system in which the powder is fed inside the plasma gun and a system in which the powder is fed externally. The internal powder spraying method generated a well-defined lamellae structure that was characterized by a thin porous layer at the splat boundary and microcracks within individual splats. Such micro-defects were generated by the large thermal contraction of splats from fully-molten droplets. The external powder spraying method formed a relatively dense coating with a particulate deposition mode, and the deposition of a higher fraction of partially-melted droplets led to a much reduced number of inter-splat pores and intra-splat microcracks. The microhardness and scratch resistance of the $Y_2O_3$ coatings were improved by external powder spraying; this result was mainly attributed to the reduced number of micro-defects.

Plasma-Sprayed $Al_2O_3-SiO_2$ Multi-Oxide Films on Stainless Steel Substrate

  • Korobova, N.;Soh, Deawha
    • 한국항해항만학회:학술대회논문집
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    • 한국항해항만학회 2000년도 추계학술대회논문집
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    • pp.116-119
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    • 2000
  • The advantage of plasma-sprayed coating is their good resistance against thermal shock due to the porous state of the coated layer with a consequently low Youngs modulus. However, the existence of many pores with a bimodal distribution and a laminar structure in the coating reduces coating strength and oxidation protection of the base metals. In order to counteract these problems, there have been many efforts to obtain dense coatings by spraying under low pressure or vacuum and by controlling particle size and morphology of the spraying materials. The aim of the present study is to survey the effects of the HIP treatment between 1100 and 130$0^{\circ}C$ on plasma-sprayed oxide coating of A1$_2$O$_3$, A1$_2$O$_3$-SiO$_2$on the metal substrate (type C18N10T stainless steel). These effects were characterized by phase identification, Vickers hardness measurement, and tensile test before and after HIPing. These results show that high-pressure treatment has an advantage for improving adhesive strength and Vickers hardness of plasma-sprayed coatings.

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Ellipsometry를 이용한 Low-k SiOCH 박막의 유전특성에 관한 연구 (A Study of the Dielectric Characteristics of the Low-k SiOCH Thin Films by Ellipsometry)

  • 이인환;황창수;김홍배
    • 한국전기전자재료학회논문지
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    • 제21권12호
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    • pp.1083-1089
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    • 2008
  • We studied the dielectric characteristics of low-k SiOCH thin films by Ellipsometry. The SiOCH thin films were prepared by deposition of BTMSM precursors on p-Si wafer by CCP-PECVD method. The nano-porous structural organic/inorganic hybrid-type of SiOCH thin films correlated directly to the formation of low dielectrics close to pore(k=1). The structural groups including highly dense pores in SiOCH thin films originated the anisotropic geometry type of network structure directing to complex refractive characteristics of SiOCH single layer on the p-Si wafer. The linearly polarized beam of Xe-ramp in the range from 190 nm to 2100 nm introduced to the surface of SiOCH thin film, and the reflected beam was Elliptically polarized by complex refractive coefficients of SiOCH dipole groups. The amplitude variation $\Psi$ and phase variation $\Delta$ of the relative reflective coefficients between perpendicular and parallel components to the incident plane were measured by Ellipsometry. The complex optical constants n and k as well as the dielectric constant and thickness of SiOCH thin films were driven by the measured value of $\Psi$ and $\Delta$.

Carbon Dioxide Reforming of Methane Over Mesoporous $Ni/SiO_2$ Catalyst

  • Kim, Dae Han;Sim, Jong Ki;Seo, Hyun Ook;Jeong, Myung-Geun;Kim, Young Dok;Lim, Dong Chan;Kim, Sang Hoon
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.166-166
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    • 2013
  • Mesoporous $SiO_2$-supported Ni catalysts (Ni/$SiO_2$ and Ni/$TiO_2$/$SiO_2$) were fabricated by atomic layer deposition (ALD), and their catalytic activity and stability were investigated in carbon dioxide reforming of methane (CRM) reaction at $800^{\circ}C$ The Ni/$SiO_2$ catalysts showed high stability as a result of confinement of Ni particles with a mean size of ~10 nm within the pores of $SiO_2$ support. Besides, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and transmission electron microscopy (TEM) results showed that the Ni nanoparticles were partially buried inside the $SiO_2$ support. The strong interaction between Ni and the $SiO_2$ support could also be advantageous for long-term stability of the catalyst. In case of the Ni/$TiO_2$/$SiO_2$ catalyst, it was found that the catalytic activity of 10 nm-sized Ni nanoparticles was not much influenced by $TiO_2$ addition.

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Polymer Light-Emitting Diode with Controlled Nano-Structure

  • Park, O-Ok;Lim, Yong-Taik;Park, Jong-Hyeok;Lee, Ho-Chul;Kim, Tae-Ho;Lee, Hang-Ken
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.194-194
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    • 2006
  • Polymer light-emitting diodes(PLEDs) have great potential application in large area flat panel displays and general lighting so intense academic and industrial research, and impressive scientific and technological progress has been achieved in this field. However, the efficiency and stability of PLEDs till need to be improved in order to fully realize the advantages of low cost and ease of fabrication provided by organic materials. Here, we report our effort to enhance the PLED' s performance in two approaches : 1) Utilizing nano-structured materials such as nano particles, clay, nano porous silica in active layer 2) Modifying the device structure in nano scale to improve not only the device efficiency but also its stability.

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