• Title/Summary/Keyword: Porous Ceramics

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Effect of Pore Formers and Sintering Temperatures on Microstructure and Bending Strength of the Porous Zirconia Ceramics (기공 형성제 조절과 소결 온도의 변화가 다공질 지르코니아 세라믹스의 미세구조 및 강도에 미치는 영향)

  • Lee, Eun-Jung;Song, In-Hyuck;Ha, Jang-Hoon;Hahn, Yoo-Dong;Kim, Yang-Do
    • Journal of Powder Materials
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    • v.18 no.6
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    • pp.502-509
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    • 2011
  • In this study, a novel-processing route for fabricating microcellular zirconia ceramics has been developed. The proposed strategy for making the microcellula zirconia ceramics involved hollow microspheres as pore former. Compared to conventional dense microspheres pore former, well-defined pore structured zirconia ceramics were successfully fabricated. Effects of hollow microsphere content and sintering temperature on microstructure, porosity, pore distribution, and strength were investigated in the processing of microcellular zirconia ceramics.

Processing of Polymer-derived Microcellular Ceramics Containing Reactive Fillers

  • Kim, Young-Wook;Jang, Doo-Hee;Eom, Jung-Hye;Song, In-Hyuck;Kim, Hai-Doo
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.101-102
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    • 2006
  • Processing techniques for producing microcellular silicon carbide, mullite, and cordierite ceramics have been developed by a reaction method that incorporates a polysiloxane and reactive fillers. The techniques developed in this study offer substantial flexibility for producing microcellular ceramics whereby cell size, cell density, degree of interconnectivity, composition, and porosity can all be effectively controlled. It is demonstrated that the adjustment of filler composition enables the possibility of tailoring the composition and properties of the microcellular ceramics. The present results suggest that the proposed novel processing techniques are suitable for the manufacture of microcellular ceramics with high morphological uniformity.

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Fabrication and Properties of Bioactive Porous Ceramics for Bone Substitution (뼈 대체용 생체활성 다공질 세라믹스의 제조 및 특성)

  • Lee, Lak-Hyoung;Ha, Jung-Soo
    • Journal of the Korean Ceramic Society
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    • v.45 no.10
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    • pp.584-588
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    • 2008
  • Porous hydroxyapatite(HA) and HA-coated porous $Al_2O_3$ possessing pore characteristics required for bone substitutes were prepared by a slurry foaming method combined with gelcasting. The HA coating was deposited by heating porous $Al_2O_3$ substrates in an aqueous solution containing $Ca^{2+}$ and ${PO_4}^{3-}$ ions at $65{\sim}95^{\circ}C$ under ambient pressure. The pore characteristic, microstructure, and compressive strength were investigated and compared for the two kinds of samples. The porosity of the samples was about 81% and 80% for HA and $Al_2O_3$, respectively with a highly interconnected network of spherical pores with size ranging from 50 to $250{\mu}m$. The porous $Al_2O_3$ sample showed much higher compressive strength(25 MPa) than the porous HA sample(10 MPa). Fairly dense and uniform HA coating(about $2{\mu}m$ thick) was deposited on the porous $Al_2O_3$ sample. Since the compressive strength of cancellous bone is $2{\sim}12$ MPa, both the porous HA and HA-coated porous $Al_2O_3$ samples could be successfully utilized as scaffolds for bone repair. Especially the latter is expected suitable for load bearing bone substitutes due to its excellent strength.

Flexural Strength of Macroporous Silicon Carbide Ceramics (거대기공 다공질 탄화규소 세라믹스의 꺾임강도)

  • Lim, Kwang-Young;Kim, Young-Wook;Song, In-Hyuck;Bae, Ji-Soo
    • Journal of the Korean Ceramic Society
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    • v.48 no.5
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    • pp.360-367
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    • 2011
  • Macroporous silicon carbide (SiC) ceramics were fabricated by powder processing and polymer processing using carbon-filled polysiloxane as a precursor. The effects of the starting SiC polytype, template type, and template content on porosity and flexural strength of macroporous SiC ceramics were investigated. The ${\beta}$-SiC powder as a starting material or a filler led to higher porosity than ${\alpha}$-SiC powder, owing to the impingement of growing ${\alpha}$-SiC grains, which were transformed from ${\beta}$-SiC during sintering. Typical flexural strength of powder-processed macroporous SiC ceramics fabricated from ${\alpha}$-SiC starting powder and polymer microbeads was 127 MPa at 29% porosity. In contrast, that of polymer-processed macroporous SiC ceramics fabricated from carbon-filled polysiloxane, ${\beta}$-SiC fillers, and hollow microspheres was 116MPa at 29% porosity. The combination of ${\alpha}$-SiC starting powder and a fairly large amount (10 wt%) of $Al_2O_3-Y_2O_3$ additives led to macroporous SiC ceramics with excellent flexural strength.

Study on the control of marine biofouling developed on the surface of porous ceramics (세라믹 다공체 표면에 발생하는 해양 생물 오손 억제에 관한 연구)

  • Kang, Jimin;Kang, Seunggu;Kim, YooTack
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.5
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    • pp.218-224
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    • 2015
  • Recently, removing methods of red tide has been attempted by filtering the organisms using the ceramic porous bodies. However, the marine biofouling could be developed on the surfaces of porous ceramic body after use for more than one month, and it might decrease the function of the specimen. In this paper, a method of inhibiting marine biofouling by changing the physical properties or surface-modification of ceramic porous body was studied. After experiment with six different ceramic porous bodies, it was found that the specimen of lower porosity and water absorption showed the least amount of biofouling. In addition, by increasing the surface roughness with silica particles bonded to the surface of specimen, the amount of biofouling caused by large marine life such as barnacle and mussel could be decreased. On the other hand, when the surface of specimen was coated and fused by glass powder, the amount of biofouling was rather increased. This might be due to eluted inorganic ions from the glass which can promote the growth of the microorganism. In conclusion, the environmental-friendly methods to reduce the amount of marine biofouling, such as controlling the physical properties and the surface roughness of the porous ceramics, can be possible without the use of dangerous substances. So it is expected for the results obtained to be applicable to a marine structure.

The Effect of Processing Conditions on the Gradient Pore Structure of Diatomite by Centrifugal Molding (경사 기공 구조를 가지는 규조토의 제조에 원심 분리 성형 공정 변수들이 미치는 영향)

  • Ha, Jang-Hoon;Oh, Eun-Ji;Ahmad, Rizwan;Song, In-Hyuck
    • Journal of Powder Materials
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    • v.19 no.4
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    • pp.304-309
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    • 2012
  • The purpose of our study was to develop the fabrication method of porous diatomite ceramics with a porosity gradient by centrifugal molding. The processing variables of centrifugal molding were derived from Stoke's law of sedimentation, which were the radius of the particles, the acceleration due to centrifugal molding and the dynamic viscosity of the slurry. And these could be controlled by ball-milling conditions, centrifugal conditions, and the addition of methyl cellulose, respectively. The effects of processing conditions on the gradient pore structure of diatomite were investigated by particle size analysis, scanning electron microscope, and mercury porosimeter.

Processing of Cellular SiC Ceramics Using Polymer Microbeads

  • Lee, Sung-Hee;Kim, Young-Wook
    • Journal of the Korean Ceramic Society
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    • v.43 no.8 s.291
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    • pp.458-462
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    • 2006
  • A simple pressing process using a SiC powder, $Al_2O_3-Y_2O_3$ sintering additive, and polymer microbeads for fabricating cellular SiC ceramics is demonstrated. The strategy for making the cellular ceramics involves: (i) forming certain shapes using a mixture of a SiC powder, $Al_2O_3-Y_2O_3$ sintering additive, and polymer microbeads by pressing; (ii) heat-treatment of the formed body to burn-out the microbeads; and (iii) sintering the body. By controlling the microsphere content and sintering temperature, it was possible to adjust the porosity in a range of 16% to 69%. The flexural and compressive strengths of cellular SiC ceramics with $\sim$40% porosity were $\sim$60 MPa and $\sim$160 MPa, respectively.

Preparation of Porous $Al_2O_3$-AIN-Mullite and $Al_2O_3$-AIN-SiC

  • Kim, Byung-Hoon;Na, Yong-Han
    • The Korean Journal of Ceramics
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    • v.1 no.3
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    • pp.147-151
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    • 1995
  • Porous composite of $Al_2O_3$ and AIN based mullite and SiC can be prepared by alumium reaction synthesis and atmosphere controllied sintering in order to improve the durability of a gas filter body. The porous $Al_2O_3$-AIN-mullite, which has a strength of 168 kg/$\textrm{cm}^2$ and porosity of 51.59%, could be obtained by stmospheric firing at $1600^{\circ}C$ and the porous $Al_2O_3$-AIN-SiC with a porosity of 33% and strength of 977 kg/$\textrm{cm}^2$, could also be prepared. The average pore size has been changed from 0.2$\mu\textrm{m}$ in a reduction atmosphere and to 2$\mu\textrm{m}$ in an air atmosphere, respectively.

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