• Journal of Environmental Health Sciences
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• v.14 no.1
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• pp.1-9
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• 1988

석탄유도가스에 포함된 황화수소를 제거시킬 흡착제를 개발하기 위하여 알칼리 토금속, 천이원소 및 아연의 이온반경보다 이온반경이 작은 금속산화물을 산화아연에 첨가시켜 다공성 흡착제를 제조하였다. 600$\circ$C에서 이들 첨가시료를 2.09vol.% 황화수소와 질소가스 혼합기체로 반응시켜 초기속도를 측정하고, 같은 온도에서 사용된 흡착제를 공기로 재생시켰다. 사용된 금속산화물 첨가 흡착제중에서 CaO, TiO$_2$, $Fe_2O_3$, CuO, $Ga_2O_3$ 및 Si$_2$O가 ZnO 흡착제의 초기속도를 증가시켜 첨가제로 사용할 수 있음을 보였다.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.3
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• pp.187-193
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• 2019

Regarding physical absorption mechanism for fine particles(Dust), internal pore-bridging is a major parameter in porous media. In this paper, internal bridging pore system is invented through FA-based geopolymer and incorporated PLA (Polylactic Acid) fiber with biodegradability. With various mix proportions, compressive strength over 20MPa is obtained but PLA is little dissolved in the condition of NaOH 5mole and $30^{\circ}C$ of temperature, which was found that temperature rising accelerates PLA solubility. Within 24hours, beads type PLA is completely dissolved under $90{\sim}130^{\circ}C$ and NaOH 5~12mole of alkali. In room condition, geo-polymerization is limitedly occurs so that the internal pore after PLA dissolution is thought to be effective to absorption and storage of fine particles.

• Journal of the Korean Solar Energy Society
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• v.27 no.1
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• pp.75-81
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• 2007

Steam reforming of methane using Xe-arc solar simulator was studied for the application of concentrated solar energy into chemical reaction. The reactor, a volumetric absorber, consisted of a porous ceramic foam disk coated with commercial reforming catalyst. Operating temperature was in the range of $450\;-\;550^{\circ}C$ and the excess steam ratio to methane was from 3.0 to 5.0. At the steady-state condition, the conversion of methane Increased with temperature in the range of 15 % - 30 % and the experimentally determined conversion was found to be close to theoretical equilibrium conversion. It was also found that the CO selectivity slightly decreased with excess steam ratio. Finally, the conversion of methane decreased significantly with space velocity of reactants.

• Journal of the Korean Institute of Telematics and Electronics D
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• v.34D no.7
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• pp.30-36
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• 1997

Bump bonded piezoesistive silicon accelerometer was fabricated by the porous silicon micromachining and th eprocess technique of integrated circuit. The output voltage of the accelerometer fabricated on (111)-oreiented Si substrates with n/n$^{+}$n triple layers showed good linear characteristic of less than 1%. The measured sensitivity and the resonant frequency was about 743 .mu.V/g and 2.04 kHz, respectively. And the transverse sensitivity of 5.2% was measured from the accelerometer. Also, to investigate an influence on the output characteristics of the sensor due to bump bonding, the values of the piezoresistors were measured through thermal-cycling test in the temperature variation form -50 to 120.deg. C. Then, there was 0.014% resistance changes about 3.61 k.ohm., so sthe output charcteristics of the sensor was less affected by bump bonding.g.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.26 no.3
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• pp.246-251
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• 2013

Screen printing is commonly used to form the front/back electrodes in silicon solar cell. But it has caused high resistance and low aspect ratio, resulting in decreased conversion efficiency in solar cell. Recently the plating method has been combined with screen-printed c-Si solar cell to reduce the resistance and improve the aspect ratio. In this paper, we investigated the effect of light induced silver plating with screen-printed c-Si solar cells and compared their electrical properties. All wafers were textured, doped, and coated with anti-reflection layer. The metallization process was carried out with screen-printing, followed by co-fired. Then we performed light induced Ag plating by changing the plating time in the range of 20 sec~5min with/without external light. For comparison, we measured the light I-V characteristics and electrode width by optical microscope. During plating, silver ions fill the porous structure established in rapid silver particle sintering during co-firing step, which results in resistance decrease and efficiency improvement. The plating rate was increased in presence of light lamp, resulting in widening the electrode with and reducing the short-circuit current by shadowing loss. With the optimized plating condition, the conversion efficiency of solar cells was increased by 0.4% due to decreased series resistance. Finally we obtained the short-circuit current of 8.66 A, open-circuit voltage of 0.632 V, fill factor of 78.2%, and efficiency of 17.8% on a silicon solar cell.

• Journal of the Microelectronics and Packaging Society
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• v.29 no.4
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• pp.41-47
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• 2022

Ag sintering technologies have received great attention as it was applied to the inverter of Tesla's electric vehicle Model III. Ag sinter bonding technology has advantages in heat dissipation design as well as high-temperature stability due to the intrinsic properties of the material, so it is useful for practical use of SiC and GaN devices. This study was carried out to understand the sinter joining temperature effect on the robust Ag sintered joints in air without pressure within 10 min. Electroplated Ag finished Cu dies (3 mm × 3 mm × 2 mm) and substrates (10 mm × 10 mm × 2 mm) were introduced, respectively, and nano Ag paste was applied as a bonding material. The sinter joining process was performed without pressure in air with the bonding temperature as a variable of 175 ℃, 200 ℃, 225 ℃, and 250 ℃. As results, the bonding temperature of 175 ℃ caused 13.21 MPa of die shear strength, and when the bonding temperature was raised to 200 ℃, the bonding strength increased by 157% to 33.99 MPa. When the bonding temperature was increased to 225 ℃, the bonding strength of 46.54 MPa increased by about 37% compared to that of 200 ℃, and even at a bonding temperature of 250 ℃, the bonding strength exceeded 50 MPa. The bonding strength of Ag sinter joints was directly influenced by changes in the necking thickness and interfacial connection ratio. In addition, developments in the morphologies of the joint interface and porous structure have a significant effect on displacement. This study is systematically discussed on the relationship between processing temperatures and bonding strength of Ag sinter joints.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.20 no.4
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• pp.274-279
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• 2008

In the perspective of saving energy in buildings, high performance of insulation and air tightness for improving the heating and the cooling efficiency has brought the positive effect in an economical view. However, these building energy saving technologies cause the lack of ventilation, which is the direct cause of increasing the indoor contaminants, and it is also very harmful to residents because they spend over 90% of their time in the indoor area. Therefore, the ventilation is important to keep indoor environment clean and it can also save energy consumption. In this study, a HEPA type breathing wall is designed as a passive ventilation system to collect airborne particles and to supply fresh outdoor air. To make fine porous structures, polymer nano fibers which were made by electro spinning method are used as a precursor. The nano fibers are coated with SiO2 nano particles and finally the HEPA type breathing wall is made by sintering in the electric furnace at $300\sim500^{\circ}C$. The pressure drops of nano ceramic structure are 8.2, 25.5 and 44.9 mmAq at the face velocity of 2.0, 5.9 and 8.8 cm/s, respectively. Also the water vapor permeability is $3.6g/m^2{\cdot}h{\cdot}mmHg$. In this research, the porous nano ceramic structures are obtained and the possibility for the usage of a material for HEPA type breathing wall can be obtained.

• Korean Journal of Materials Research
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• v.19 no.6
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• pp.325-329
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• 2009

Titanium dioxide thin films were fabricated as hydrogen sensors and its sensing properties were tested. The titanium was deposited on a $SiO_2$/Si substrate by the DC magnetron sputtering method and was oxidized at an optimized temperature of $850^{\circ}C$ in air. The titanium film originally had smooth surface morphology, but the film agglomerated to nano-size grains when the temperature reached oxidation temperature where it formed titanium oxide with a rutile structure. The oxide thin film formed by grains of tens of nanometers size also showed many short cracks and voids between the grains. The response to 1% hydrogen gas was ${\sim}2{\times}10^6$ at the optimum sensing temperature of $200^{\circ}C$, and ${\sim}10^3$ at room temperature. This extremely high sensitivity of the thin film to hydrogen was due partly to the porous structure of the nano-sized sensing particles. Other sensor properties were also examined.

• Membrane Journal
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• v.16 no.1
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• pp.25-30
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• 2006

The NaA zeolite membrane was synthesized on the surface of a porous ${\alpha}$-alumina support from the reaction solution composed of 1Si : 1Na : 4Na $6H_{2}O$. The pervaporation performance of the synthesized NaA zeolite membrane was investigated for the iso-propyl alcohol (IPA) aqueous solution according to the different feed concentration and the different operating temperature. The total flux decreases by increasing the feed IPA concentration and increases by increasing the temperature. The total flux was about $4.0{\times}10^3g/m^2\;hr\;at\;60^{\circ}C$ and 0.6 mole fraction of IPA and the separation factor was $1.8{\times}10^7\;at\;60^{\circ}C$ and 0.8 mole fraction of IPA. The separation performance of water through the NaA membrane was found to be superior to that obtainable with a distillation process just by comparison of the vapor-liquid equilibrium data.

• Journal of the Korean Ceramic Society
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• v.30 no.11
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• pp.881-890
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• 1993

MAS system has narrow sintering temp. range due to the liquid phae sintering and thereby densify rapidly. And especially, its poor mechanical properties limitedthe industrial application. In this study, the improvement of mechanical properties and densification is suggested by the consideration of the toughening mechanisms and isolated pore generation mechanism which is derived by the liquid phase sintering theory in 3Y-TZP added composites. After Pressureless sintering up to 140$0^{\circ}C$ for 5hr, the dihedral angle and contact angle are analyzed by the observation of microstructure. As a result of microstructure analysis, the sintering stage of the specimen sintered for 5hr is analyzed as solid-skeleton stage. And the isolated pore generation mechanisms are considered as (1) The swelling of the liquid phase is predominent due to the facts that dihedral angle is larger than 60$^{\circ}$, contact angle is large and that liquid volume fraction is smaller than 10%. (2) The porous characteristics of the MAS system is also suggested as: the SiO2-rich liquid film is firstly formed at the srface and therefore this reduces the contiguity of the pore, which induces the isolated pore. The strength and fracture toughness increased with the addition of 3Y-TZP and the main fracture toughness improvement mechanisms are analyzed as the crack deflection.