• 한국재료학회지
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• 제14권8호
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• pp.547-551
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• 2004

The sulfidation behaviour of Fe-XAl-0.3Y(X=5, 10, 14, 25 $wt.\%$) alloys was investigated at 1123 K in $H_2/H_{2}S$ gas atmosphere for $1\sim24$ hrs using SEM/EDX, XRD and EPMA. The weight changes of Fe-XAl-0.3Y alloys followed the parabolic rate law, Sulfidation rates of iron aluminide alloys with high Al content were one-twentieth lower than that of 5Al alloys. This is due to the formation of protective $Al_{2}O_3$ oxides on the surface of 10Al, 14Al and 25Al alloys. By calculating partial pressure of impurity oxygen contained $H_2/H_{2}S$ gas, the $Al_{2}O_3$ oxides formation could be explained using Fe-Al-S-O thermodynamic stability diagram. The sulfidation product scales of the 5Al alloy showed that thick iron sulfide scale(FeS) containing porosities formed during early stages of sulfidation. With continued sulfidation, aluminum sulfide was formed at the alloy/scale interface.

• Wind and Structures
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• 제16권1호
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• pp.47-60
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• 2013

A dominant opening in a windward wall, which generates large internal pressures in a building, is a critical structural design criterion. The internal pressure fluctuations are a function of the dominant opening area size, internal volume size and external pressure at the opening. In addition, many buildings have background leakage, which can attenuate internal pressure fluctuations. This study examines internal pressure in buildings for a range of dominant opening areas, internal volume sizes and background porosities. The effects of background porosity are incorporated into the governing equation. The ratio of the background leakage area $A_L$ to dominant opening area $A_W$ is presented in a non-dimensional format through a parameter, ${\phi}_6-A_L/A_W$. Background porosity was found to attenuate the internal pressure fluctuations when ${\phi}_6$ is larger than 0.2. The dominant opening discharge coefficient, ${\kappa}$ was estimated to lie between 0.05 to 0.40 and the effective background porosity discharge coefficient ${\kappa}^{\prime}_L$, was estimated to be between 0.05 to 0.50.

• Wind and Structures
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• 제16권1호
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• pp.61-91
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• 2013

An analytical model of internal pressure response of a leaky and quasi-statically flexible building with a dominant opening is provided by including the effect of the envelope external pressure fluctuations on the roof, in addition to the fluctuating external pressure at the dominant opening. Wind tunnel experiments involving a flexible roof and different building porosities were carried out to validate the analytical predictions. While the effect of envelope flexibility is shown to lower the Helmholtz frequency of the building volume-opening combination, the lowering of the resonant peak in the internal and net roof pressure coefficient spectra is attributed to the increased damping in the system due to inherent background leakage and envelope flexibility. The extent of the damping effects of "skin" flexibility and background leakage in moderating the internal and net pressure response under high wind conditions is quantified using the linearized admittance functions developed. Analytical examples provided for different combinations of background leakage and envelope flexibility show that alleviation of internal and net pressure fluctuations due to these factors by as much as 40 and 15% respectively is possible compared to that for a nominally sealed rigid building of the same internal volume and opening size.

• Structural Engineering and Mechanics
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• 제73권3호
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• pp.225-238
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• 2020

This work treats the axisymmetric buckling of functionally graded (FG) porous annular/circular nanoplates based on modified couple stress theory (MCST). The nanoplate is located at the elastic medium which is simulated by Kerr foundation with two spring and one shear layer. The material properties of the porous FG nanostructure are assumed to vary through the nanoplate thickness based on power-law rule. Based on two variables refined plate theory, the governing equations are derived by utilizing Hamilton's principle. Applying generalized differential quadrature method (GDQM), the buckling load of the annular/circular nanoplates is obtained for different boundary conditions. The influences of different involved parameters such as boundary conditions, Kerr medium, material length scale parameter, geometrical parameters of the nanoplate, FG power index and porosity are demonstrated on the nonlinear buckling load of the annular/circular nanoplates. The results indicate that with increasing the porosity of the nanoplate, the nonlinear buckling load is decreased. In addition, with increasing the material length scale parameter to thickness ratio, the effect of spring constant of Kerr foundation on the buckling load becomes more prominent. The present results are compared with those available in the literature to validate the accuracy and reliability. A good agreement is observed between the two sets of the results.

• 한국결정성장학회지
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• 제15권1호
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• pp.21-26
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• 2005

세라믹 분말 가압 성형 공정을 전산모사 하고 패킹의 임의성과 입자 배열의 효과를 평가하기 위해서 유사한 임의 다중 입자 배열을 사용하여 2차원 막대 배열 가압 성형 모델을 도입하였다. 3개의 Al₂O₃ 입자와 3개의 Al 입자를 가지고 기공과 관련된 가압 성형 공정을 균질화 탄성계수를 사용하여 외연적 유한요소 해석하였다. 해석 결과는 이전 해석 결과 및 실험 결과와 비교하였다. 마지막으로, 분말 입자의 마찰계수와 상대밀도의 관계를 얻기 위한 해석이 수행되었다.

• 한국세라믹학회지
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• 제46권1호
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• pp.35-40
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• 2009

Using zirconia and poly (methyl methacrylate-coethylene glycol dimethacrylate) (PMMA) microbeads, macroporous zirconia ceramics were fabricated by a simple pressing method. Effects of template size and content on microstructure, porosity, and flexural and compressive strengths were investigated in the processing of the macroporous zirconia ceramics. Three different sizes of microbeads (8, 20, and $50{\mu}m$) were used as a template for fabricating the macroporous ceramics. The porosity increased with increasing the template size at the same template content. The flexural and compressive strengths were primarily influenced by the porosity rather than the template size. However, the strengths increased with decreasing the template size at the same porosity. By controlling the template size and content, it was possible to produce macroporous zirconia ceramics with porosities ranging from 58% to 75%. Typical flexural and compressive strength values at 60% porosity were ${\sim}30\;MPa$ and ${\sim}75\;MPa$, respectively.

• 한국세라믹학회지
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• 제46권1호
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• pp.108-115
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• 2009

In this study, a novel-processing route for producing microcellular zirconia ceramics has been developed. The proposed strategy for making the microcellular zirconia ceramics involves hollow microsphere as a pore former which has extremely low density of $0.025\;g/cm^3$. Effects of hollow microsphere content and sintering temperature on microstructure, porosity, pore distribution, and compressive strength were investigated in the processing of microcellular zirconia ceramics. By controlling the content of hollow microsphere, it was possible to make the porous zirconia ceramics with porosities ranging from 45% to 75%. Typical compressive strength value of microcellular zirconia ceramics with ${\sim}65%$ porosity was over 50 MPa. By adjusting the mixing ratio of large and small zirconia powders, it was possible to control the pore structure from close to open pores.

• 한국세라믹학회지
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• 제45권9호
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• pp.537-543
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• 2008

Effect of template size ratio on porosity and mechanical properties of porous zirconia ceramics were investigated using two different size (${\sim}8{\mu}m$ and ${\sim}50{\mu}m$ in diameter) of polymethyl methacrylate-coethylene glycol dimethacrylate (PMMA) microbeads as sacrificial templates. Porosity of the porous zirconia ceramics increased with decreasing the template size ratio ($8{\mu}m: 50{\mu}m$) whereas the compressive and flexural strengths of the porous zirconia ceramics increased with increasing the template size ratio. By controlling the template size ratio, sintering temperature and sintering time, it was possible to produce porous zirconia ceramics with porosities ranging from 57% to 69%. Typical flexural and compressive strength values of porous zirconia ceramics with ${\sim}60%$ porosity were ${\sim}37\;MPa$ and ${\sim}85\;MPa$, respectively.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2009년도 추계학술발표대회
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• pp.38.2-38.2
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• 2009

Regeration of natural tissuesor to create biological substitutes for defective or lost tissues and organs through the use of cells. In addition to cells and their porous, drugs are required to promote tissue regeneration. Therefore, the present studies were prepared using simvastatim loaded porous poly(lactide-co-glycolide) (PLGA) by double emulsion solvent evaporation water-in-oil-in-water technique (W/O/W) as drug delivery system strategies for injuring tissue. The resulting microspheres were evaluated for morphology, particle size, encapsulation efficiency, degradation of PLGA microspheres in vitro drug release and in vitro cell viability. Scanning electronic microscopic (SEM) showed that the porosities of the particles was changed by experimental conditions and cultured cells were attached well on porous microspheres surface. The X-ray diffraction (XRD) and differential scanning calometry (DSC) analysis indicate thatsimvastatim was highly dipersed in the microsphere at amorphousstate.

• 한국염색가공학회지
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• 제11권6호
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• pp.1-6
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• 1999

The porosities of PET fibers were investigated using a nitrogen porosimeter according to oxygen plasma treatment and dyeing with a disperse dye, and they were discussed in terms of the change of internal micro-structure of the PET fiber. The total pore volume, surface area and average pore size of the plasma treated PET fibers increased expectably compared with the untreated sample. The PET fibers treated with oxygen plasma and then dyed with a disperse dye were increased significantly in the surface area and the total pore volume comparing with those of plasma treated only, but decreased in the average pore size. The increase of the surface area, after dyeing, of the plasma treated PET fibers was due to addition of the surface area of the dye itself to that of the PET fiber. The increase of the total pore volume of the plasma treated PET fibers by dyeing, which is the opposite result to the general idea that the pore volume of fibers would be reduced by occupation of dye molecules in the pores, could be explained by the free-volume model. This is that the amorphous region in the fiber expanded by occupation of dye molecules, and the marginal space surrounding dyes was generated as many smaller pores, and the decrease of the average pore size of the dyed sample also could be explained The decrease of the average pore size was caused by the splitting of a larger pore into smaller pores.