• Title/Summary/Keyword: Pores

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Properties of Concrete Precast Pavers using Non-Cement Binders (무시멘트 결합재를 사용한 콘크리트 보도블록의 특성)

  • Lee, Won-Gyu;Jo, Eun-Seok;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.35-36
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    • 2018
  • Korea has many problems due to the asphalt pavement or impermeable pavement. Many methods are being implemented to improve water circulation. Among them, permeable packaging materials are used. However, existing permeable packaging materials have a problem of causing efflorescence and clogging the pores. The pores of the permeable packing material are clogged and the permeability is lost. This leads to economic problems and product problems. The purpose of this study was to develop a block to prevent efflorescence.

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Simulation of brittle fracture of autoclaved aerated concrete

  • Kadashevich, I.;Stoyan, D.
    • Computers and Concrete
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    • v.7 no.1
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    • pp.39-51
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    • 2010
  • The system of pores of autoclaved aerated concrete (AAC) is described by the so-called cherry-pit model, a random system of partially interpenetrating spheres. For the simulation of fracture processes, the solid phase is approximated by an irregular spatial network of beams obtained by means of the so-called radical tessellation with respect to the pore spheres. FE calculations using standard software (ANSYS) yield the strain energies of the beams. These energies are used as fracture criterion according to which highly loaded beams are considered as broken and are removed from the network. The paper investigates the relationship between mean fracture strength and microstructure for structures close to real AAC samples and virtual structures with particular geometrical properties.

PREPARATION OF POLY(ETHYLENE-CO-VINYL ALCOHOL) MEMBRANE VIA THERMALLY INDUCED PHASE SEPARATION

  • Matsuyama, Hideto;Shang, Mengxian;Teramoto, Masaaki
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.74-77
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    • 2004
  • Porous membranes were prepared via thermally induced phase separation (TIPS) of (ethylene-co-vinyl alcohol) (EVOH)/glycerol mixtures. The liquid-liquid (L-L) phase boundaries are shifted to higher temperature when the ethylene contents in EVOH increase. Moreover, the kinetic study proved that the growth of droplets formed by the general liquid-liquid (L-L) phase separation obeyed a power-law scaling relationship in the later stage of spinodal decomposition (SD). A new phase separation mechanism was presented, in which the L-L phase separation could be resulted from the crystallization. The hollow fiber membranes were prepared. The membranes showed asymmetric structures with skin layer near the outer surface, the larger pores just below the skin layer and the smaller pores near the inner surface. The effect of ethylene content (EC) in EVOH, cooling water bath temperature and take-up speed on membrane performance was investigated.

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Electrodeposition of Polypyrrole Nanowires within Vertically Oriented Mesoporous Silica Template

  • Kang, Ho-Suk;Lee, Ho-Chun;Kwak, Ju-Hyoun
    • Journal of the Korean Electrochemical Society
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    • v.14 no.1
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    • pp.22-26
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    • 2011
  • Polypyrrole (Ppy) nanowire has been electrochemically synthesized via vertically oriented mesoporous silica template. The mesoporous template is also electrochemically deposited on indium tin oxide coated (ITO) glass from tetraethyl orthosilicate (TEOS) and cetyltrimethylammonium bromide (CTAB) surfactant. The highly ordered silica template is demonstrated to be 100~120nm thick with the pores of 4~5 nm diameter by scanning electron microscope (SEM) and transmission electron microscope (TEM). Ppy is formed to fill pores of the silica template from pyrrole solution by electrochemical oxidation. The Ppy in Ppy/silica/ITO composite was found to exhibit reversible electrochemical activity, as characterized by cyclic voltammetry (CV).

A Structural Study of the Oxidized High Modulus Pitch Based Carbon Fibers by Oxidation in Carbon Dioxide

  • Roh, Jae-Seung
    • Carbon letters
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    • v.5 no.1
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    • pp.27-33
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    • 2004
  • Structural changes of high modulus carbon fiber by oxidation in carbon dioxide gas using SEM, TEM, and XRD have been observed. It was shown that the originally high modulus carbon fiber is composed of highly ordered graphitic crystalline area and non-crystalline area. It was observed that the La increases during the whole oxidation process. It was shown that the oxidation of high modulus carbon fiber initiates at the non-crystalline area and at the ends of fiber. The large pores developed in fiber by direction of fiber length at high temperature ($1,100^{\circ}C$), and the small pores developed on the fiber surface at low temperature ($900^{\circ}C$). In conclusion, it is found that the oxidation of the carbon fiber was progressed through the imperfection.

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Microstructural Evoluation from the Oxidation-Reduction of Mn-Zn Ferrite Single Crystal (망간징크 페라이트 단결정의 산화-환원반응에 따른 미세구조의 변화)

  • 윤상영;김문규
    • Journal of the Korean Ceramic Society
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    • v.27 no.5
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    • pp.652-660
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    • 1990
  • Oxidation of Mn-Zn ferrite was made in air at various temperatures ranging from 400$^{\circ}C$ to 1150$^{\circ}C$. Subsequent reduction fo these oxidized samples was also made in air at 1300-1350$^{\circ}C$ where the spinel phase of Mn-Zn ferrite is stable. Morphological observation revealed that the shape of precipitated hematite was plate or lath type on the close-packed habit plane of {111} ferrite which has a definite orientation relationship. The growth of precipitates showed the behavior fo parabolic dependence of the oxidating time. An apparent activation energy for the growth was found to be 125${\pm}$3Kcal/mol. The fact that pores are observed along the precipitates illustrates the oxidation to occur dominantly by the counterdiffusion of cations and ction vacancies. For the reductio reaction pores are found to form at the site once occupied by the precipitates and at the surface. This observation illustrates that the oxygen volitalization from interior region to the surface is the dominant process for the reduction reaction.

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Realistic pore structure of Portland cement paste: experimental study and numerical simulation

  • Ma, Hongyan;Li, Zongjin
    • Computers and Concrete
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    • v.11 no.4
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    • pp.317-336
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    • 2013
  • In this study, the pore structure of Portland cement paste is experimentally characterized by MIP (mercury intrusion porosimetry) and nitrogen adsorption, and simulated by a newly developed status-oriented computer model. Cement pastes with w/c=0.3, 0.4 and 0.5 at ages from 1 day to 120 days are comprehensively investigated. It is found that MIP cannot generate valid pore size distribution curves for cement paste. Nevertheless, nitrogen adsorption can give much more realistic pore size distribution curves of small capillary pores, and these curves follow the same distribution mode. While, large capillary pores can be effectively characterized by the newly developed computer model, and the validity of this model has been proved by BSE imaging plus image analysis. Based on the experimental findings and numerical simulation, a hypothesis is proposed to explain the formation mechanism of the capillary pore system, and the realistic representation of the pore structure of hydrated cement paste is established.

Preparation of Crack-free YBCO Films by EPD on Silver

  • Soh, Dea-wha;Li, Young-mae;Korobova N.;Park, Sung-Jai
    • Journal of information and communication convergence engineering
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    • v.1 no.1
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    • pp.27-30
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    • 2003
  • Electrophoretic deposition (EPD) of alcohol YBCO suspensions on the Ag wire electrode is studied. Poly(ethylene glycol) was coordinated to a structure formed by the EPD process with YBCO particles. The suspension is characterized in terms of zeta potential and conductivity. The d.c electric fields of 200-300 V/cm are applied for 1-10 min. The optimal condition for the EPD allows modifying the properties and microstructure of the deposited films. Superconducting coatings with nanometer-sized pores and a preferred orientation along the c-axis were prepared from the result with chemically modified precursor solution. In contrast, YBCO coatings of submicrometer-sized pores and randomly orientated grains were prepared from the solution without PEG.

A Study on the Fabrication of Porous Nickel Substrates (다공성 니켈지지체의 제조에 관한 연구)

  • 신동엽;조원일;백지흠;조병원;강탁;윤경석
    • Journal of the Korean institute of surface engineering
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    • v.28 no.3
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    • pp.123-132
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    • 1995
  • While a nickel mesh and an expanded nickel sheet are used as current collectors for supporting active anode materials in rechargeable batteries, a porous nickel substrate is studied extensively for its 3-dimensional structure which has high capabilities for active materials and current collection. Optimum plating conditions were studied by polarization measurement. Scanning Electron Microscopy (SEM) showed that both electroless-and electro-plated nickel on an urethane substrate were highly porous and consisted of nearly spherical pores. The diameter and the channel size of the pores were found to be 300~500 $\mu\textrm{m}$ and 50~200$\mu\textrm{m}$, respectively. The shape of skeleton resembled a triangular prism with length extending about 50~100 $\mu\textrm{m}$.

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Novel Methods for Measuring the Surface Hardness of Anodic Oxide Films on Aluminum Alloy (알루미늄 합금 양극산화피막의 표면경도 측정법)

  • Moon, Sungmo
    • Journal of the Korean institute of surface engineering
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    • v.53 no.1
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    • pp.36-42
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    • 2020
  • In this study, two novel methods to measure the surface hardness of anodic oxide films on aluminum alloys are reported. The first method is to impregnate oil-based ink into pores in the anodic oxide film and then to clean the ink on the surface using ethanol, resulting in an impregnation of inks only inside of the pores in anodic oxide film. The second method is to coat the anodic oxide film surface with thin Au layer less than 0.1 ?. Both the ink-impregnating method and Au-coating method provided clear indentation marks on the anodic oxide film surface when it was indented using a pyramidal-diamond penetrator. Thus, Vickers hardness of anodic oxide films on aluminium alloy could be measured successfully and precisely from the anodic film surface. In addition, advantages and disadvantages of the ink-impregnating method and Au-coating method for the measurement of surface hardness of anodic oxide films are discussed.