• Title/Summary/Keyword: Pores

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Mechanical Properties of Cement Mortar: Development of Structure-Property Relationships

  • Ghebrab, Tewodros Tekeste;Soroushian, Parviz
    • International Journal of Concrete Structures and Materials
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    • 제5권1호
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    • pp.3-10
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    • 2011
  • Theoretical models for prediction of the mechanical properties of cement mortar are developed based on the morphology and interactions of cement hydration products, capillary pores and microcracks. The models account for intermolecular interactions involving the nano-scale calcium silicate hydrate (C-S-H) constituents of hydration products, and consider the effects of capillary pores as well as the microcracks within the hydrated cement paste and at the interfacial transition zone (ITZ). Cement mortar was modeled as a three-phase material composed of hydrated cement paste, fine aggregates and ITZ. The Hashin's bound model was used to predict the elastic modulus of mortar as a three-phase composite. Theoretical evaluation of fracture toughness indicated that the frictional pullout of fine aggregates makes major contribution to the fracture energy of cement mortar. Linear fracture mechanics principles were used to model the tensile strength of mortar. The predictions of theoretical models compared reasonably with empirical values.

Processing of Porous Ceramics with a Cellular Structure Using Polymer Beads

  • Ha, Jung-Soo;Kim, Chang-Sam
    • 한국세라믹학회지
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    • 제40권12호
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    • pp.1159-1164
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    • 2003
  • Two processing routes (i.e., the gel casting and polymer preform routes) using polymer beads were studied to fabricate porous ceramics with a cellular structure. The gel casting route, comprising the gel casting of a ceramic slurry mixed with polymer beads, was found to be inadequate to produce porous ceramic bodies with a interconnected pore structure, due to complete coating of the slurry on the polymer beads, which left just isolated pores in the final sintered bodies. The polymer preform route, involving the infiltration of a polymer beads preform with the ceramic slurry, successfully produced porous ceramics with a highly interconnected network of spherical pores. The pore size of 250-300 $\mu\textrm{m}$ was demonstrated and the porosity ranged from 82 to 86%. This process is advantageous to control the pore size because it is determined by the sizes of polymer beads used. Another feature is the avoidance of hollow skeleton, giving a high strength.

열수반응으로 합성된 수화규산소다의 팽창 특성 (Expansion Characteristics of the Hydrated Sodium Silicate which Synthesized by Hydrothermal Reaction)

  • 조호연;공양표;서동수
    • 한국세라믹학회지
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    • 제45권12호
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    • pp.845-850
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    • 2008
  • Hydrated sodium silicate was synthesized by hydrothermal reaction using anhydrous sodium silicate. The optimum additions of water was 25wt% to make hydrated sodium silicate with homogeneous and purposed water contents. Porous ceramics with homogeneous microstructure and spherical closed pore can be fabricated by elimination of the large pores(a few mm in size) which was formed during first heat treatment through the decomposition of water. Spherical closed pore was formed above $600^{\circ}C$ and the pore size was increased with increasing second heat treatment temperature due to growth of pores. The size of spherical closed pore was varied from 35 to $233\;{\mu}m$ and specific gravity was varied from 0.2 to 1.02 depending on the combinations of the first and second heat treatment temperature.

Microfabrication of Vertical Carbon Nanotube Field-Effect Transistors on an Anodized Aluminum Oxide Template Using Atomic Layer Deposition

  • Jung, Sunghwan
    • Journal of Electrical Engineering and Technology
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    • 제10권3호
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    • pp.1169-1173
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    • 2015
  • This paper presents vertical carbon nanotube (CNT) field effect transistors (FETs). For the first time, the author successfully fabricated vertical CNT-based FETs on an anodized aluminum oxide (AAO) template by using atomic layer deposition (ALD). Single walled CNTs were vertically grown and aligned with the vertical pores of an AAO template. By using ALD, a gate oxide material (Al2O3) and a gate metal (Au) were centrally located inside each pore, allowing the vertical CNTs grown in the pores to be individually gated. Characterizations of the gated/vertical CNTs were carried and the successful gate integration with the CNTs was confirmed.

열간정수압소결(HIP) 시킨 고온초전도체의 조직과 특성 (Microstructure and Properties of High Tc Superconductor fabricated by Hot Isostatic Pressing)

  • 송진태;아기하마료소
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1988년도 춘계학술대회 논문집
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    • pp.17-19
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    • 1988
  • $YBa_2Cu_3O_{7-x}$ oxide superconductors were fabricated by the hot isostatic pressing (HIP). It was shown that their structures were orthorombic and constited of a single (123) phase. While as-sintered compacts had many pores, they were remarkably reduced by Hiping. The on-set and off set temperature of (123) compound sintered at $950^{\circ}C$ in oxygen and hiping at $880^{\circ}C$ were the highest and it showed 0 resistance at $90^{\circ}K$. The critical current density ($J_c$) of the above superconductor was $27A/cm^2$ and it also showed a number of twin structures, which are typical of high $T_c$ superconductor. It seemed that the low current density may be due to the many pores of starting-sintered compacts.

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펌프 타입 화장품 도포에 따른 피부 표면 평가와 온도 측정 (Assesment of Human Skin Surface and Measurement of Temperature upon Applying Pump Type Cosmetics)

  • 조완구;박지은
    • 한국응용과학기술학회지
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    • 제27권2호
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    • pp.144-151
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    • 2010
  • Over the years, scientists have developed many test methods to evaluate the efficacy of skin care products. The needs for objective assessment have stimulated to develop instruments that are capable of reliably monitoring some parameters in evaluating skin conditions. The beauty is evaluated as a measure of smoothness of skin surface. Quantitative size measurements of skin pores is also important concept to evaluate the their conditions. The purpose of this paper is to measure the temperature change of skin and the size of pores in the skin. The pore sizes were changed by its varying skin temperature. They were decreased by applying a essence which is contained with propellant and contents.

활성탄의 세공이 자연유기물질의 흡착에 미치는 영향 (Effect of pore characteristics of activated carbon on adsorption of natural organic matter)

  • 박정순;홍성호
    • 상하수도학회지
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    • 제25권2호
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    • pp.249-255
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    • 2011
  • It is complicate problem to optimize removing natural organic matter (NOM) by activated carbon in drinking water treatment because the activated carbon has heterogeneous surface area and pore structure. Seven different coals based activated carbons which have different pore structures were used in the study. Sand filtered effluents which normally used as GAC adsorber influent were used. The molecular weight distribution showed that most of the NOM was bigger than 10,000Da. In this study, systematical approaches such as characteristics of surface area and pore volume were evaluated on NOM adsorption. Especially, the adsorption capacities for NOM were evaluated by effect of micro-pores and meso-pores in surface area and pore structure. The results show that the higher ratio of meso-pore compare to the micro-pore has not only the better adsorption capacities for NOM but also the higher strongly-adsorbable fraction. Therefore, the overall adsorption capacity is increased with higher meso-pore ratio with existing of reasonable micro-pore surface area and volume.

실리카겔 공극에서의 이산화탄소 및 메탄 하이드레이트 상평형 측정 및 열역학적 예측 (Phase Equilibrium of the Carbon Dioxide and Methane Hydrate in Silica Gel Pores and Thermodynamic Prediction)

  • 강성필
    • 신재생에너지
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    • 제3권2호
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    • pp.47-52
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    • 2007
  • Hydrate phase equilibrium for the binary $CO_{2}$+water and $CH_{4}$+water mixtures in silica gel pore of nominal 6, 30, and 100 nm were measured and compared with the cacluated results based on van der Waals and Platteeuw model. At a specific temperature three-phase hydrate-water-vapor (HLV) equilibrium curves for pore hydrates were shifted to the higher-pressure condition depending on pore sizes when compared with those of bulk hydrates. Notably, hydrate phase equilibria for the case of 100 nominal nm pore size were nearly identical with those of bulk hydrates. The activities of water in porous silica gels were modified to account for capillary effect, and the calculation results were generally in good agreement with the experimental data.

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Y2O3가 분산된 Fe-C 및 Fe-CNT 소결체의 미세구조 및 기계적 특성 (The Microstructure and Mechanical Properties of Y2O3-Dispersed Fe-C and Fe-CNT Sintered Steels)

  • 임진영;안중호
    • 한국분말재료학회지
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    • 제24권4호
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    • pp.298-301
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    • 2017
  • In the present work, we use multiwall carbon nanotubes (MWCNT) as the starting material for the fabrication of sintered carbon steel. A comparison is made with conventionally sintered carbon steel, where graphite is used as the starting material. Milling is performed using a horizontal mill sintered in a vacuum furnace. We analyze the grain size, number of pores, X-ray diffraction patterns, and microstructure. Changes in the physical properties are determined by using the Archimedes method and Vickers hardness measurements. The result shows that the use of MWCNTs instead of graphite significantly reduces the size and volume of the pores as well as the grain size after sintering. The addition of $Y_2O_3$.to the Fe-MWCNT samples further inhibits the growth of grains.

Quantitative Assessment of Variation in Poroelastic Properties of Composite Materials Using Micromechanical RVE Models

  • Han, Su Yeon;Kim, Sung Jun;Shin, Eui Sup
    • International Journal of Aeronautical and Space Sciences
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    • 제17권2호
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    • pp.175-183
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    • 2016
  • A poroelastic composite material, containing different material phases and filled with fluids, serves as a model to formulate the overall ablative behaviors of such materials. This article deals with the assessment of variation in nondeterministic poroelastic properties of two-phase composite materials using micromechanical representative volume element (RVE) models. Considering the configuration and arrangement of pores in a matrix phase, various RVEs are modeled and analyzed according to their porosity. In order to quantitatively investigate the effects of microstructure, changes in effective elastic moduli and poroelastic parameters are measured via finite element (FE) analysis. The poroelastic parameters are calculated from the effective elastic moduli and the pore-pressure-induced strains. The reliability of the numerical results is verified through image-based FE models with the actual shape of pores in carbon-phenolic ablative materials. Additionally, the variation of strain energy density is measured, which can possibly be used to evaluate microstress concentrations.