• 제목/요약/키워드: Pores

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APPLICATION OF THREE DIMENSIONAL CULTURE OF ADULT RAT HAPATOCYTES IN POLYURETHANE FOAM PORES FOR AN ARTIFICIAL LIVER SUPPORT SYSTEM

  • Funatsu, K.;Matsushita, T.;Ijima, H.;Iwahashi, T.
    • 한국응용약물학회:학술대회논문집
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    • 한국응용약물학회 1994년도 춘계학술대회 and 제3회 신약개발 연구발표회
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    • pp.137-144
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    • 1994
  • Spherical multicellular aggregates of adult rat hepatocytes (spheroid) which have tissue like structure, were formed and immobilized in the pores of polyurethane foam (PUF) which was used as a culture substratum. These hepatocyte/spheroids, about 100 $\mu\textrm{m}$ in diameter, have maintained higher differentiated functions than those of hepatocyte/monolayer for about 3 weeks in serum-free medium. Then, we designed a prototype module of an artificial liver support system using a PUF/spheroid packed-bed, in which hepatocyte/spheroids were immobilized at high density. The urea synthesis activity of the artificial liver was maintained at least 10 days in 100% rat blood plasma. We start examining the performance of hybrid artificial liver in an ex vivo extracorporeal experiment with an acute hepatic failure rat.

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Preparation of crack-free YBCO films by EPD on silver

  • Soh, Deawha;Li, Yingmei;Korobova, N.
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2003년도 춘계종합학술대회
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    • pp.359-362
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    • 2003
  • Electrophoretic deposition (EPD) of alcohol YBCO suspensions on the Ag wire electrode is studied. Poly(ethylene glycol) was coordinated to a structure formed by the EPD process with YBCO particles. The suspension is characterized in terms of zeta potential and conductivity. The d.c electric fields of 200-300 V/cm are applied for 1-10 min. The optimal condition for the EPD allows modifying the properties and microstructure of the deposited films. Superconducting coatings with nanometer-sized pores and a preferred orientation along the c-axis were prepared from the result with chemically modified precursor solution. In contrast, YBCO coatings of submicrometer-sized pores and randomly orientated grains were prepared from the solution without PEG.

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실리카겔 공극에서의 이산화탄소 및 메탄 하이드레이트 상평형 측정 및 열역학적 예측 (Phase Equilibrium of the Carbon Dioxide and Methane Hydrate in Silica Gel Pores and Thermodynamic Prediction)

  • 강성필
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.477-480
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    • 2007
  • Hydrate phase equilibrium for the binary CO2+water and CH4+water mixtures in silica gel pore of nominal 6, 30, and 100 nm were measured and compared with the cacluated results based on van der Waals and Platteeuw model. At a specific temperature three-phase hydrate-water-vapor (HLV) equilibrium curves for pore hydrates were shifted to the higher-pressure condition depending on pore sizes when compared with those of bulk hydrates. Notably, hydrate phase equilibria for the case of 100 nominal urn pore size were nealy identical with those of bulk hydrates. The activities of water in porous silica gels were modified to account for capillary effect, and the calculation results were generally in good agreement with the experimental data.

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모노리스 타입 마이크로 촉매 연소기의 담층 내부 물질전달 및 반응 관계에 관한 연구 (Investigation on the Relationship between Mass Transfer and Reaction within the Washcoat of Monolith Type Micro-scale Catalytic Combustor)

  • 이광구;스즈키 유지
    • 한국연소학회지
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    • 제20권2호
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    • pp.46-53
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    • 2015
  • The relationship between mass transfer and reaction within the washcoat is investigated in a monolith type micro-scale Pt-catalytic combustor. Nondimensionalized balance equation of butane is applied in a simplified washcoat geometry having the shape of slab. Both Thiele modulus and effectiveness factor are considered to compare reaction rate and diffusion rate according to the operation temperature and the diameter of alumina nano-pores. The effect of reaction becomes stronger as the temperature increases, while the effect of diffusion becomes relatively dominant as the diameter of nano-pores increases. From the analysis of butane distribution within the washcoat, design criterion for the thickness of washcoat is discussed.

미세다공성 세라믹 막에서의 가공응축기구에 의한 휘발성 유기화합물의 분리 (Pore Condensation-Based Separation of VOCs by a Microporous Ceramic Membrane)

  • Cha, Jun-Seok
    • Journal of Korean Society for Atmospheric Environment
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    • 제12권E호
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    • pp.19-28
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    • 1996
  • A pore concensation-based separation technique was studied experimentally using toluene and xylene in a nitrogen stream. The removal rate of toluene and xylene on a microporous ceramic membrane was enhanced by increasing the partial pressure difference across the membrane, but the selectivity was reduced with increasing flux of nitrogen. This was found both in vacuum and pressure modes of operation. The experimental results from this study suggest that the pores mear the inlet portion of the module were filled with the organic solvent while the pores near the exit section of the module were slightly opened as the solvent concentration was depleted along the module. In the case of xylene, the rate of N$_{2}$ permeation was reduced considerably relative to toluene, resulting in a much higher separation gactor. Condensibility of xylene appeared to be higher than that of toluene, the potential for pore condensation-based separation of xylene was also found to be higher than that for toluene.

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산소 분리를 위한 무공성 세라믹- 금속 복합 무기막 (Dense Ceramic-metal Composite Inorganic Membranes for Oxygen Separation)

  • 김진수
    • 한국막학회:학술대회논문집
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    • 한국막학회 2002년도 춘계 총회 및 학술발표회
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    • pp.35-41
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    • 2002
  • Dense oxygen ionic conducting materials can be used for oxygen separation membranes at high temperatures. However, they show relatively low permeation flux because of their large resistances. To reduce resistances and improve the oxygen permeation flux, thin dense yttria-stabilized-zirconia (YSZ)/Pd composite dual-phase membranes were fabricated by a new approach that combines the reservoir method and chemical vapor deposition (CVD). A thin porous YSZ layer was coated on a porous alumina support by dip-coating the YSZ suspension. A continuous Pd phase was formed inside pores of the YSZ layer by the reservoir method. The residual pores of the YSZ/Pd layer were plugged with yttria/zirconia by CVD to ensure the gas tightness of the membranes. The oxygen permeation fluxes through these composite membrane were 2.0$\times$10$^{-8}$ mol/cm$^2$.s and 4.8$\times$10$^{-8}$ mol/cm$^2$.s at 105$0^{\circ}C$ when air and oxygen were used as the permeate gases, respectively. These oxygen permeation values are about 1 order of magnitude higher than those of pure YSZ membranes prepared under similar conditions.

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The flow of $CO_{2}$ and $N_{2}$ gases through Asymmetric polytherimide Membrane

  • Park, You-In;Lee, Kew-Ho
    • 한국막학회:학술대회논문집
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    • 한국막학회 1995년도 제3회 심포지움 (분리막 연구의 최신동향)
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    • pp.73-85
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    • 1995
  • The asymmetric hollow fiber membranes were prepared by the wet spining of polyetherimide dope solution and the effect of hollow fiber structures on the permeation characteristics of carbon dioxide and nitrogen gases through these membrane were investigated. As the concentration of the $\gamma$-butyrolactone (GBL) in dope solution, acting as a swelling agent was increased, the structure of hollow fiber was changed from the finger to sponge type. The permeabilities of gases (CO$_{2}$, N$_{2}$) through these membrane were measured over the wide range of pressure under different temperature. The effect of water vapor on the permeabilities of gases was also investigated. The measured permeabilities showed the different characteristics depending on the structure of membranes. It was found that the flow through the pores were dominant over the polymers matrix. Blocking effect by water vapor in the pores of skin layer greatly improved the ideal separation factor of carbon dioxide/nitrogen.

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무가압분말 충전성형법에 의한 다공성 세라믹스의 제조 및 특성 : II. 뮬라이트 & 코디어라이트 (The Fabrication and Characteristics of Porous Ceramics by Pressureless Powder Packing Forming Method ; II, Mullite & Cordierite)

  • 박정현;황명익;김동희;최환욱;김용남
    • 한국세라믹학회지
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    • 제36권6호
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    • pp.671-678
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    • 1999
  • Porous ceramics were fabricated from pressureless powder packing forming method using mullite and cordierite powders granulate by spray drying. The bending strength and shrinkage of porous ceramics were increased and their porosity were decreased with increasing temperature. It showed homogeneous distribution of 2$\mu\textrm{m}$ intergranular pores of mullite at 1400$^{\circ}C$, 2.5$\mu\textrm{m}$ intergranular pores of cordierite at 1300$^{\circ}C$ respedtively. Above that temperature intragranular particles were sintered and sintering by intergranular necking was extremely proceeded. In the test of thermal shock resistance sudden decrease of bending strength to $\Delta$T was not shown because intergranular large pore prevented sudden crack propagation.

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양생조건 및 함수율이 콘크리트의 중성화 및 투기성에 미치는 영향에 관한 실험적 연구 (An Experimental Study on the Effect of Curing Condition and Moisture Content Ratio on the Carbonation and Air Permeability of Concrete)

  • 유재강;이강우;강석표;권영진;배기선;김무한
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2000년도 가을 학술발표회논문집(I)
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    • pp.403-408
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    • 2000
  • Hardened concrete contains pores of varying types and sizes, and therefore the transport of air through concrete can be considered. The rate of permeability will not only depend on the continuity of pores, but also on the moisture contents in concrete. In this paper, the effects of curing conditions and moisture content ratios on the carbonation and air permeability are investigated according to the accelerated carbonation test. The results are follows. 1) Compressive strength, carbonation velocity and air permeability are influenced by the moisture content and curing method. 2) The relationship between carbonation velocity coefficient and air permeability coefficient has been quite well established.

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고Alumina질 다공성 세라믹스의 내열충격성 및 내Slag성 (기공크기에 따른) (Thermal Spalling and Resistance to Slag Attack in Porous High Alumina Ceramic (According to Pore Size))

  • 김병훈;나용한
    • 한국세라믹학회지
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    • 제30권9호
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    • pp.747-753
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    • 1993
  • The investigation was carried out to study the behaviors of the pore size and porosity, the mechanical strength, the resistance to thermal spallings and slag attacks according to particle sizes of starting raw materials in porous high Alumina ceramics. This porous ceramics have been used in processing of the clean steel by the blowing of the inert gas. The required properties in the practice are the suitable pores size, the sharp pores distribution for a uniform blowing of the gas, the strong corrosion resistance to slags and molten metals and the resistance to thermal spalling. The optimized properties in porous high alumina ceramics of the specimen No. 3 was found to be the very low slag intrusion and the superior resistance to thermal spalling because of the suitable pore size of 2.5${\mu}{\textrm}{m}$, the porosity of 30% and the high sinterability.

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