• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.325-326
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• 2006

Using $6wt%Y_2O_3-2wt%Al_2O_3$ as sintering additives and Si as a raw powder, the continuously porous in-situ $Si_2N_2O-Si_3N_4$ bodies were fabricated by multi-pass extrusion process and their microstructures were investigated depending on the addition of carbon (0-9wt%) in the mixture powder. The introduction of $Si_2N_2O$ fibers observed in the unidirectional continuous pores as well as in the pore-frame regions of the nitrided bodies can be an effective method in increasing the filtration efficiency. In the case of no carbon addition, the network type $Si_2N_2O$ fibers with high aspect ratio appeared in the continuous pores with diameters of 150-200 nm. However, in the case of 9wt% C addition, the fibers were found without any network type and had diameters of 200-250 nm.

• 한국지반공학회논문집
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• 제20권8호
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• pp.77-87
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• 2004

본 논문에서는 국내 서남해안 11개 지역에서 수행된 63회의 피에조콘 시험결과와 176개의 선행압밀하중 자료로부터 국내 연약지반의 선행압밀하중 예측을 위한 오차 역전파 알고리즘으로 학습된 피에조콘 인공신경망 모델을 구축하였다. 전체 자료 중 147개의 자료만이 인공신경망 모델 구축을 위한 학습과정에 사용되었으며 학습에 사용되지 않은 29개의 자료를 구축된 인공신경망의 검증에 활용하였다. 또한 기존의 경험모델 및 이론모델과 비교하여 제안된 인공신경망 모델의 유용성을 확인하였다. 연구를 통하여 4-4-9-1의 구조를 갖는 간단한 다층 인공신경망이 구축되었으며 입력값으로는 피에조콘 선단저항력 $q_T$, 관입간극수압 $u_2$그리고 지반의 총상재하중 $\sigma_{vo}$ 및 유효상재하중 $\sigma'_{vo}$ 이 사용되었다. 제안된 인공신경망 모델은 학습되지 않은 새로운 검증자료에 대한 예측을 통하여 입력변수들과 선행압밀 하중 간의 비선형적 상관관계를 성공적으로 모델하는 것으로 검증되었으며 정확성면에서는 기존의 이론모델과 국내외 경험모델과 비교할 때 월등히 향상된 예측능력을 가진 것으로 나타났다. 뿐만 아니라 제안된 모델은 국내 특정지 역에 대한 모델이 아니라 서남해안의 다양한 지반특성을 갖는 지반에서 수행된 자료를 바탕으로 구축되어 데이터베이스에 포함되지 않은 지역에 대하여도 매우 타당성있는 예측결과를 주어 특정지역에 국한된 지역의존적 예측이 아닌 일반화된 지역에서 적용할 수 있을 것으로 판단된다.

• Archives of Pharmacal Research
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• 제9권4호
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• pp.193-199
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• 1986

The release of heparin from monolithic devices composed of different ratios of polythylene oxide (PEO MW 20,000) and hydrophobic polydimethylsiloxane or polyurethane was investigated. Water soluble PEO blended into the polymers provided a controlled release of heparin. The release rate of heparin could be controlled by varying the content of PEO. The heparin release rate from the devices increased as the content of PEO in the devices increased. The release mechanism may be associated with the creation of pore of domain through the devices following the swelling and the change in the physical structure of the polymer network. Hydrophobic polydimethylsiloxanes and polyurethanes containing PEO can provide an antith rombogenic material for prologed release of heparin from blended system.

• 한국분말재료학회지
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• 제25권3호
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• pp.203-207
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• 2018

Plastic pollution is threatening human health and ecosystems, resulting in one of the biggest challenges that humanity has ever faced. Therefore, this study focuses on the preparation of macroporous carbon from biowaste (MC)-supported manganese oxide ($MnO_2$) as an efficient, reusable, and robust catalyst for the recycling of poly(ethylene terephthalate) (PET) waste. As-prepared $MnO_2/MC$ composites have a hierarchical pore network and a large surface area ($376.16m^2/g$) with a narrow size distribution. $MnO_2/MC$ shows a maximum yield (98%) of bis(2-hydroxyethyl)terephthalate (BHET) after glycolysis reaction for 120 min. Furthermore, $MnO_2/MC$ can be reused at least nine times with a negligible decrease in BHET yield. Based on this remarkable catalytic performance, we expect that $MnO_2$-based heterogeneous catalysts have the potential to be introduced into the PET recycling industry.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2019년도 춘계 학술논문 발표대회
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• pp.32-33
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• 2019

This study evaluated the effect of amorphous steel fibers on the spalling characteristics of high-strength concrete. with mix proportions of polypropylene (PP) fibers of 0.15% by concrete volume, and proportions of amorphous steel fibers of 0.3% and 0.5% by concrete volume. In the range of 0.3 vol% of amorphous steel fiber, the effect of suppression of the spalling and the prevention of degradation of strength was shown, but it was evaluated to be ineffective in the suppression of the spalling due to interferences in formation of pore network in the range of 0.5 vol.%.

• 한국정보전자통신기술학회논문지
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• 제3권4호
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• pp.10-15
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• 2010

Cortical bone is composed of an osteon, which is a subunit of the cortical bone. At the center of the osteon, Haversian is located and it consists of blood vessels and nerves. Osteon is known to be inclined 5 to 15 degrees with respect to the long axis of a cortical bone, but the reason why it is inclined is not clear. Using the poroelastic calculation provides the pore pressure varies at the lacunar-canalicular network from -200KPa to 200KPa. This estimation is close to the result shown in the previous literature and it helps further cell culture experiment for elucidating the bone remodeling process.

• Bulletin of the Korean Chemical Society
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• 제16권12호
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• pp.1167-1172
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• 1995

A coverage of about 1 μm-sized pores of a membrane filter by four monolayers of maleic acids copolymers and poly(allylamine) (PAA) was attained by Langmuir-Blodgett (LB) technique through a covalent cross-linking followed a polyion complexation at the air-water interface. The copolymers were prepared to have side chains of hydrocarbon tail, carboxyl, and/or oligoether in the repeat unit. The surface pressure-area isotherms showed that the monolayers on an aqueous PAA have more expanded area than on pure water. The monolayers were transferable on a calcium fluoride substrate and a fluorocarbon membrane filter as Y deposition type, and the resulting LB films were characterized by FT-IR spectroscopy and scanning electron microscopy. A polymer network produced through interchain amide formation was confirmed in as-deposited films. The films were heat-treated in order to complete the cross-linking. SEM observation of the heat-treated film on a porous membrane filter showed that the four layer film was sufficiently stable to cover the filter pore of about 1 μm. Immersion of the film in water or in chloroform did not cause any change in its appearance on SEM and in FT-IR spectra.

• Geomechanics and Engineering
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• 제12권5호
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• pp.849-862
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• 2017

With growing interests in using bacterial biopolymers in geotechnical practices, identifying mechanical properties of soft gel-like biopolymers is important in predicting their efficacy in soil modification and treatment. As one of the promising candidates, dextran was found to be produced by Leuconostoc mesenteroides. The model bacteria utilize sucrose as working material and synthesize both soluble and insoluble dextran which forms a complex and inhomogeneous polymer network. However, the traditional rheometer has a limitation to capture in situ properties of inherently porous and inhomogeneous biopolymers. Therefore, we used the particle tracking microrheology to characterize the material properties of the dextran polymer. TEM images revealed a range of pore size mostly less than $20{\mu}m$, showing large pores > $2{\mu}m$ and small pores within the solid matrix whose sizes are less than $1{\mu}m$. Microrheology data showed two distinct regimes in the bacterial dextran, purely viscous pore region of soluble dextran and viscoelastic region of the solid part of insoluble dextran matrix. Diffusive beads represented the soluble dextran dissolved in an aqueous phase, of which viscosity was three times higher than the growth medium viscosity. The local properties of the insoluble dextran were extracted from the results of the minimally moving beads embedded in the dextran matrix or trapped in small pores. At high frequency (${\omega}>0.2Hz$), the insoluble dextran showed the elastic behavior with the storage modulus of ~0.1 Pa. As frequency decreased, the insoluble dextran matrix exhibited the viscoelastic behavior with the decreasing storage modulus in the range of ${\sim}0.1-10^{-3}Pa$ and the increasing loss modulus in the range of ${\sim}10^{-4}-1\;Pa$. The obtained results provide a compilation of frequency-dependent rheological or viscoelastic properties of soft gel-like porous biopolymers at the particular conditions where soil bacteria produce bacterial biopolymers in subsurface.

• 전기화학회지
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• 제3권2호
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• pp.85-89
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• 2000

Lithium ion Battery(LIB)의 음극 활물질로써 리튬을 대체하기 위한 노력으로 phenol resin을 탄화시킨 탄소재료를 사용하였다. Phenol resin을 소성하면 축합반응을 일으키면서 탄화되어 무정형 탄소가 된다. 무정형 탄소는 층간거리가 넓어 리튬의 삽입과 탈리가 용이하지만 탄소간의 결합력이 약하여 구조적 붕괴가 일어난다. 이러한 문제를 해결하기 위해 세공형성제로서 $ZnCl_2$를 사용하였다. $ZnCl_2$는 생성된 물질에서 3차원적 망상구조로 성장하는 개방세공을 형성하는 세공형성제로서 뿐만 아니라, 벌크 첨가제가 도핑된 느슨한 구조를 형성하는 미세세공 형성제로서 작용하였다. SEM을 통해서 구조적 차이를 알 수 있었으며, XRD분석으로 층간의 거리를 알 수 있었다. CV측정을 통해 두 가지 샘플에 대한 산화와 환원 반응의 차이를 알아보았다.

• 터널과지하공간
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• 제26권4호
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• pp.293-303
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• 2016

이산화탄소 지중저장 기술은 이산화탄소 저감을 위한 가장 효과적인 방법 중 하나로 주목받고 있다. 본 연구에서는 이산화탄소 저장조건을 실험실에서 모사하였다. 사암과 셰일 시료를 1M NaCl 용액에 포화시킨 후 $45^{\circ}C$, 10기압의 조건에서 4주 동안 반응시키며 물리적 성질과 미세구조적 성질의 변화를 측정하였다. 부피, 밀도, 탄성파속도, 포아송비, 동탄성계수 등 모든 항목에서 사암 시료에 비해 셰일 시료의 물리적 성질 변화가 크게 나타났다. X선 단층촬영을 통한 미세구조 분석 결과 두 가지 시료 모두에서 공극의 총개수가 감소하였고, 각각의 공극들이 가지는 평균 부피, 평균 표면적, 평균 등가직경 등이 변화하였다. 이는 이산화탄소와 광물의 반응으로 인한 점토 광물의 팽창 및 유출이 원인인 것으로 판단된다. 본 연구결과는 이산화탄소 지중저장 시 발생되는 암반의 물리적, 미세구조적 변화를 예측하는 데 효과적으로 이용될 것으로 기대된다.