• Title/Summary/Keyword: Pore volume

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Effect of Reaction Conditions of Pyrolysis on the Characteristics of Sludge Char (열분해 조건에 따른 슬러지 Char 특성 변화)

  • Cha, Jin-Sun;Park, Young-Kwon
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.851-856
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    • 2011
  • In this study, char was produced via pyrolysis of sewage sludge and the effects of reaction conditions(temperature, heating rate, reaction time) on characteristics of char were investigated. As temperature increased from $300^{\circ}C$ to $800^{\circ}C$, the surface area of sludge char increased in general but decreased at $700^{\circ}C$ temporarily. The effect of heating rate on specific surface area and pore volume of char was not large. Meanwhile, specific surface area and pore volume increased with reaction time but average pore diameter decreased.

Synthesis of Porous 4-Vinylpyridine Divinylbenzene Resin and It's Properties (다공성 4-비닐피리딘디비닐벤젠 수지의 합성과 그의 성질)

  • Dong Won Kim;Hae Young Song;Suh Jung Muck;Jae Jick Oh;Beom Gyu Lee
    • Journal of the Korean Chemical Society
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    • v.29 no.3
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    • pp.283-286
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    • 1985
  • The non porous and porous 4-vinylpyridine-divinylbenzene ion exchange resins were synthesized by the suspension polymerization method. The functional groups of these resins were identified by means of infrared adsorption spectroscopy. The pore volume and pore spectra of these synthesized resins were determined with a mercury porosimeter. The influence of diluent and percentage of divinylbenzene on the pore size and volume of the porous 4-vinylpyridine-divinylbenzene copolymer, P-4VPDVB, 50-100 mesh was discussed. The ion exchange capacity of non-porous and porous 4-vinylpyridine divinylbenzene resins was 5.0meq/g, respectively.

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Influence of the Water Vapor Content on the Hydrogen Reduction Process of Nanocrystalline NiO

  • Jung, Sung-Soo;An, Hyo-Sang;Lee, Jai-Sung
    • Korean Journal of Metals and Materials
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    • v.48 no.4
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    • pp.315-319
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    • 2010
  • In this study, the hydrogen reduction behavior of ball-milled NiO nanopowder was investigated depending on the partial pressure of water vapor. The hydrogen reduction behavior was analyzed by thermogravimetry and hygrometry under heating to 873 K in hydrogen. In order to change the partial pressure of the water vapor, the dew point of hydrogen was controlled in the range of 248 K~293 K by passing high-purity hydrogen through a saturator that contained water. Interestingly, with the increase in the dew point of the hydrogen atmosphere, the first step of the hydrogen reduction process decreased and the second step gradually increased. After the first step, a pore volume analysis revealed that the pore size distribution in the condition with a higher water vapor pressure shifted to a larger size, whereas the opposite appearedat a lower pressure. Thus, it was found that the decrease in the pore volume during the chemical reaction controlled process at a dew point of 248 K caused a reduction in retardation in the diffusion controlled process.

A Fundamental Study on Vibrated Crushed-stone Pile for the Improvement of Liquefaction Resistance (액상화 방지를 위한 진동쇄석말뚝에 관한 기초적 연구)

  • 천병식
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 2000.04a
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    • pp.105-111
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    • 2000
  • If a saturate sand is subjected to ground vibrations it tends to compact and decrease in volume. if drainage is unable to occur the tendency to decrease in volume results in an increase in pore water pressure and if the pore water pressure build up to the point at which it is equal to the overburden pressure the effective stress becomes zero the sand loses its strength completely. This phenomenon is called "Liquefaction" It is associated primarily but not exclusively with saturated cohesion soils. The attention and study on liquefaction have been growing since the earthquake in Niigita Japan in 1964. Many researchers on liquefaction effect have been carried out in many countries under the potential influence of earthquake including Japan. However little research on liquefaction has been reported in Korea because Korea has been considered to be safe from earthquake. The term "liquefaction" is only known among geotechnical engineers,. In this paper overview of liquefaction and the evaluation on the applicability of vibrated crushed-stone pile as a liquefaction prevention method are presented.ethod are presented.

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Strain gradient based static stability analysis of composite crystalline shell structures having porosities

  • Fenjan, Raad M.;Faleh, Nadhim M.;Ridha, Ahmed A.
    • Steel and Composite Structures
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    • v.36 no.6
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    • pp.631-642
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    • 2020
  • This paper studies nonlinear stability behavior of a nanocrystalline silicon curved nanoshell considering strain gradient size-dependency. Nanocrystallines are composite materials with an interface phase and randomly distributed nano-size grains and pores. Imperfectness of the curved nanoshell has been defined based on an initial deflection. The formulation of nanocrystalline nanoshell has been established by thin shell theory and an analytical approach has been used in order to solve the buckling problem. For accurately describing the size effects related to nano-grains or nano-pores, their surface energies have been included. Nonlinear stability curves of the nanoshell are affected by the size of nano-grain, curvature radius and nano-pore volume fraction. It is found that increasing the nano-pore volume fraction results in lower buckling loads.

Thermal Insulation Properties of Epoxy/Mesoporous Carbon Composites

  • Heo, Gun-Young;Seo, Min-Kang;Oh, Sang-Yeob;Choi, Kyeong-Eun;Park, Soo-Jin
    • Carbon letters
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    • v.12 no.1
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    • pp.53-56
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    • 2011
  • This study aimed to investigate the influence of mesoporous carbons on the thermal insulation properties of epoxy/mesoporous carbon composites. The mesoporous carbon (CMK-3) was prepared by conventional templating method using SBA-15. The epoxy/mesoporous carbon composites were prepared by mixing the synthesized CMK-3 with diglycidylether of bisphenol A (DGEBA). As experimental results, the curing reactivities of the DGEBA/CMK-3 composites were found to decrease with the addition of the CMK-3. Also, the thermal conductivities of DGEBA/CMK-3 composites were found to decrease with increasing CMK-3 content. This could be interpreted in terms of the slow thermal diffusion rate resulting in pore volume existing in the gaps in the interfaces between the mesoporous carbon and the DGEBA matrix.

Characteristics of methane sorption in surface modified activated carbon (표면개질 된 활성탄의 메탄흡장 특성)

  • Yun, Seok-Min;Kim, Ju-Wan;Jo, Won-Jun;Kim, Young-Ho;Lee, Young-Seak
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.73-76
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    • 2007
  • In this study, methane gas adsorption ability of activated carbon (AC) with surface functional group effect, adsorbed methane amount was evaluated after nitric acid and ureatreatment of AC surface. Specific surface area and pore distribution of AC were studied though nitrogen adsorption isotherm at 77 K. Micro pore volume was calculated through H-K method. Adsorbed methane amount was evaluated through volume method at room temperature by using auto adsorption apparatus. Adsorbed methane amount of AC was found to increase with to specific surface area increase.Correlation proposed between the methane adsorption amount and surface nature indicates that the surface nature plays an important role on the adsorption amount at a given temperature.

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이온통로에서 음이온 투과성 연구

  • Seo, Bong-Im;Sim, Eun-Ji
    • Proceeding of EDISON Challenge
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    • 2014.03a
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    • pp.287-299
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    • 2014
  • Bicarbonate anion ($HCO_3{^-}$) takes the role of major buffer systems in our body by maintaining the pH at 7.4. Epithelial $HCO_3{^-}$ secretion also hydrolyzes the mucus which protects body from noxious infections. It has been widely known that such infections are closely related to $HCO_3{^-}$ permeability through membrane and, thus, increasing the $HCO_3{^-}$ permeability is essential. To evaluate the $HCO_3{^-}$ permeability through ion channels, the free energy changes relevant to ion pumping are calculated with the Integral Equation Formalism-PCM (IEF-PCM) theory. Molecular structures of various anions including $HCO_3{^-}$ were optimized with the density functional theory at the level of B3LYP/6-311++G(d,p) in gas and solution phase. In addition, the anion permeability is significantly influenced by the relative size of the anion and pore. We introduce a shifted volume factor model that describes the pore size effect when the charged solutes transfer through ion channels. We found excellent agreement between experimental and calculated permeability when our novel model of the size effect was taken into account to.

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The Basic Study on the Spun Concrete Pipes using Blast-Furnace Slag Powder (고로슬래그 미분말을 사용한 콘크리트 흄관에 대한 기초적 연구)

  • 조영근;김승진;박유신;성기웅;손진군
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10b
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    • pp.939-944
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    • 2000
  • This study examines both strength development and pore volume of high temperature curing mortar, using a blast-furnace slag powder (BFS). This study experiments with various pre-steaming period, differing curing temperature and the replacement of BFS. According to the results, the strength development of BFS mortar is stronger when higher curing temperature are used(as opposed to standard curing). Also, regardless of the curing method, pore volume decreases as the curing time increases. From these results we can identify the optimum conditions required pre-steaming period, differing curing temperature and the replacement to produce BFS mortar properties.

Effect of ERCO Coating on the Carbonation Resistance of High Volume Mineral Admixture Concrete (ERCO 도포가 혼화재 다량치환 콘크리트의 탄산화저항성에 미치는 영향)

  • Kim, Sangsup;Yun, Jeongwan;Kim, Minyoung;Choi, Youngdoo;Han, Mincheol;Han, Cheongoo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.05a
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    • pp.23-24
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    • 2015
  • As this study is an experiment for solving problem on the carbonation acceleration of high volume admixture concrete, the capillary pore getting filled up by saponification as cooking oil gets absorbed to the concrete surface in case of applying a cooking oil based coating agent to the concrete has been verified in the previous studies. Accordingly, this study has performed a comparative experiment on the cooking oil and the anticorrosive coating agent sold on the market while the result followed by this experiment has shown the fact of indicating similar carbonation penetration depth and porosity.

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