• 제목/요약/키워드: Pore structure analysis

검색결과 297건 처리시간 0.024초

Sabkha층의 Hydrotest 시 입자파쇄 거동분석 (Behavior Analysis of Particle Crushing about Sabkha Layer under Hydrotest)

  • 김석주;한희수
    • 한국지반환경공학회 논문집
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    • 제14권9호
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    • pp.57-65
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    • 2013
  • 탄산질 모래는 낮은 구속압에서도 입자파쇄가 발생하며 이로 인해 높은 압축성을 나타내기 때문에 입자파쇄가 강도 및 변형특성에 중요한 영향을 미친다. 본 논문은 탄산질 모래로 구성된 Sabkha층에 Tank 설치를 위하여 시험성토 및 Hydrotest를 수행한 후 지반의 침하거동을 비교 분석한 것이다. 현장 Sabkha층 시료는 압밀시험결과 80~170kPa에서 입자파쇄가 발생하였고, 화학조성을 분석한 결과 석영질 모래에서 검출되지 않은 칼슘성분이 다량 검출되어 입자파쇄가 잘 일어날 수 있음을 알 수 있었다. 입자파쇄가 발생하지 않은 시험성토에서는 성토완료 이틀만에 간극수의 소산과 침하가 완료되었으나 입자파쇄응력보다 큰 200kPa의 하중이 재하된 Hydrotest에서는 충수 후 장기침하거동이 발생하여 시험성토의 침하거동과는 상이한 결과를 나타내었다. 따라서 현장 Sabkha층에 입자파쇄하중 이상의 하중이 재하될 경우 입자파쇄로 인한 즉시침하와 파쇄된 입자의 재배열로 인한 이차압축침하가 발생됨을 알 수 있었다.

Racemic and enantiomeric effect of tartaric acid on the hydrophilicity of polysulfone membrane

  • Sharma, Nilay;Purkait, Mihir Kumar
    • Membrane and Water Treatment
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    • 제7권3호
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    • pp.257-275
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    • 2016
  • The enantiomeric and racemic effects of tartaric acid (TA) on the properties of polysulfone (PSn) ultrafiltration membranes were studied in terms of morphology and hydrophilicity (HPCT) of membrane. Asymmetric membranes were prepared by direct blending of polyvinyl pyrrolidone (PVP) with D-TA and DL-TA in membrane casting solution. FTIR analysis was done for the confirmation of the reaction of PVP and TA in blended membranes and plain PSn membranes. Scanning electron microscope (SEM), field emission scanning electron microscope (FESEM) and atomic force microscopy (AFM) were used for analyzing the morphology and structure of the resulting membranes. The membranes were characterized in terms of pure water flux (PWF), hydraulic permeability and HPCT. PWF increased from $52L/m^2h$ to $79.9L/m^2h$ for plain and D-TA containing PSn membrane, respectively. Water contact angle also found to be decreased from $68^{\circ}$ to $55^{\circ}$. In Additionally, permeation and rejection behavior of prepared membranes was studied by bovine serum albumin (BSA) solution. A considerable increase in BSA flux (from $19.1L/m^2h$ for plain membrane to $32.1L/m^2h$ for D-TA containing membrane) was observed. FESEM images affirm that the pore size of the membranes decreases and the membrane permeability increases from 0.16 to 0.32 by the addition of D-TA in the membrane. D-TA increases the HPCT whereas; DL-TA decreases the HPCT of PSn membrane. PVP (average molecular weight of 40000 Da) with D-TA (1 wt%) gave best performance among all the membranes for each parameter.

산왕거미 (Araneus ventricosus) 독 생성장치의 미세구조 분석 (Fine Structural Analysis of the Venom Apparatus in the Spider Araneus ventricosus)

  • 문명진;유민희
    • Applied Microscopy
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    • 제37권2호
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    • pp.53-63
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    • 2007
  • 왕거미과의 산왕거미(Araneus ventricosus)를 실험재료로 하여 독 생성장치의 미세구조를 주사전자현미경으로 관찰하였다. 두흉부에 위치한 거미의 독 생성장치는 위턱(chelicera)과 한 쌍의 독선으로 이루어졌으며, 각각의 위턱은 기저마디와 가동성 엄니(fang)가 관절된 형태를 이루고 있었다. 산왕거미의 위턱은 체축에 대해 직각 방향으로 접히는 새실젖거미아목(Labidognata)의 특성을 지니고 있었으며, 관절을 통해 연결된 두개의 마디는 마치 접이식 재크 나이프와 유사한 구조를 하고 있음이 확인되었다. 원통형의 엄니는 다수의 돌기가 형성된 위턱고랑(cheliceral groove)과 분화된 접번관절로 연결되어 있었다. 또한, 위턱고랑에는 4개의 앞엄니두덩이(promarginal teeth)와 3개의 후엄니두덩이(retromarginal teeth) 등, 총 7개의 큐티클성 엄니두덩이가 두 줄로 융기된 구조를 형성하고 있었다. 엄니의 말단에는 독액을 분비하는 단일분비구멍이 후연돌기와 면한 쪽의 표면을 통해 개구되어 있었으며, 굴곡운동시 엄니와 접하는 위턱고랑의 표면에는 거친 함몰부가 형성되어 있었고 다수의 미세한 분비 구멍들이 확인되었다.

$Pr_{2}O_{3}$ 첨가량에 따른 BSCT 세라믹의 미세구조 특성 (Microstructure properties with variation of doped amount $Pr_{2}O_{3}$ of BSCT ceramics)

  • 노현지;이성갑;박상만;윤상은;김지은;이영희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 제38회 하계학술대회
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    • pp.1283-1284
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    • 2007
  • The barium strontium calcium titanate((Ba,Sr,Ca)$TiO_3$) powders prepared by the sol-gel method and $MnCO_3$ as acceptor were mixed oxide method. The microstructure was investigated with variation of $Pr_{2}O_{3}$ amount. The BSCT powder and $Pr_{2}O_{3}$ were mixed with organic vehicle(Ferro. B75001). BSCT thick films were fabricated by the screen-printing method on alumina substrates. The bottom electrode was Pt and upper electrode was Ag, respectively. All BSCT thick films were sintered at $1420^{\circ}C$, for 2h. The result of the differential thermal analysis(DTA), exothermic peak at around $654^{\circ}C$ due to the formation of the polycrystalline perovskite phase. In the X-ray diffraction(XRD) patterns, all BSCT thick films showed the typical perovskite polycrystalline structure and no pyrochlore phase was dbserved. The microstructure investigated by scanning electron microscope(SEM). Pore and grain size of BSCT thick films were decreased with increasing amount of $Pr_{2}O_{3}$ dopant. And the average grain size and thickness of BSCT thick films doped with 0.1 mol% $Pr_{2}O_{3}$ was $3.09{\mu}m$, $60{\mu}m$, respectively. The relative dielectric constant decreased and dielectric loss decreased with increasing amount of $Pr_{2}O_{3}$ dopant, the values of the BSCT thick films no doped with $Pr_{2}O_{3}$ were 7443 and 4 % at 1 kHz, respectively.

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뿜칠 방수 멤브레인이 시공된 터널 라이닝의 수분이동에 관한 수치해석 연구 (A Numerical study on the Moisture Transport of Concrete Tunnel Linings with the Sprayable Waterproofing Membrane)

  • 이철호;최순욱;강태호;장수호
    • 터널과지하공간
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    • 제26권3호
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    • pp.212-219
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    • 2016
  • 뿜칠 방수 멤브레인은 숏크리트 사이에 시공되어 라이닝 크랙을 통한 누수를 방지하는 목적으로 최근 유럽 국가를 중심으로 시공 사례가 늘어가고 있다. 뿜칠 방수 멤브레인은 방수 시트에 비해 복잡한 단면에도 시공이 용이하기 때문에 이용 사례가 늘어갈 것으로 전망된다. 뿜칠 방수 멤브레인은 폴리머로 구성된 재료로서 투수성이 매우 낮지만 수분의 이동에 의해 포화가 되고 이로인해 콘크리트 재료에 간극수압이나 동결 문제를 일으킬 수 있는 우려가 있다. 본 연구에서는 뿜칠 방수 멤브레인의 수분이동과 계절변화를 고려하여 숏크리트 라이닝의 열-습도 전달 장기 해석을 수행하였다. 해석을 통해 뿜칠 방수 멤브레인의 수분 흡수 작용과 수분 이동으로 인한 상대습도 변화를 고찰할 수 있었으며 이로 인한 장기적 변화를 모사할 수 있었다.

Effect of the Calcium Nitrate Solution Treatment on the Tensile, Bending, and Shear Properties of Silk Fabric

  • Park, Su-Zin;Kang, Ji-Young;Seol, Da-Won;Yang, Hye-Min;Lee, Ji-Min;Ahn, Ye-Ji;Han, Seo-Young;Kim, Jong-Jun
    • 패션비즈니스
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    • 제14권6호
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    • pp.39-52
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    • 2010
  • Interests in creating three-dimensionally designed fabric materials are growing rapidly in the sectors of the fashionable textiles with the creativity, new functions, and aesthetics. A number of finishing methods have been developed and proposed to add or create new functions and designs for silk fabrics. Due to the strong hydrogen bonds between the molecules of silk fibroins, the thermal treatment methods used in thermoplastic fiber processing, which can easily deform the synthetic filament fabrics to endow three-dimensional appearance to the fabrics, are not applicable to the silk fabric treatment. In order to modify the fine structure of silk fiber, neutral salt solution treatment methods have been suggested. In this study, the effect of the calcium nitrate solution on the physical and mechanical properties of silk fabrics was investigated by using the KES(Kawabata Evaluation System) equipment. Based on these findings, relationships between parameters, for example, the thickness and the compressional energy, the thickness and the compressional linearity, and the air permeability and the pore area statistical analysis were investigated. The relationships between the process parameters such as treatment temperature/time and the resulting fabric property parameters were also analyzed by using several SAS procedures.

식용 제비집으로부터 비극성 비드기술을 활용한 시알산의 분리정제방법에 관한 연구 (A Study on Purification Process of Sialic Acid from Edible Bird's Nest Using Affinity Bead Technology)

  • 김동명;정주영;이형곤;권용성;백진홍;한인석
    • 한국해양바이오학회지
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    • 제12권2호
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    • pp.81-90
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    • 2020
  • Sialic acid, which is contained in about 60-160 mg/kg in the edible bird's nest (EBN), is known to facilitate in the proper formation of synapses and improve memory function. The objective of this study is to extract effectively the sialic acid from edible bird's nest using affinity bead technology (ABT). After preparing the non-polar polymeric bead "KJM-278-28A" having a porous network structure, and then desorbed sialic acid was concentrated and dried. The analysis of the physicochemical properties of bead "KJM-278-28A" showed that the particle size was 400-700 ㎛, the moisture holding capacity was 67-70%, the surface area (BET) was 705-900 ㎡/g, and the average pore diameter 70-87 Å. The adsorption capacity of the bead "KJM-278-28A" for sialic acid was shown a strong physical force to bind sialic acid to the bead surface of 400 mg/L. In addition, as a result of analyzing the adsorption and desorption effects of sialic acid on water, ethanol, and 10% ethanol on the bead, it was confirmed that desorption effectively occurs from the beads when only ethanol is used. As a result of HPLC measurement of the separated sialic acid solution, a total of four sialic acid peaks of N-acetyl-neuraminic acid (Neu5Ac), α,β-anomer of Neu5Ac and N-glycoly-neuraminic acid were identified. Through these results, it was confirmed that it is possible to separate sialic acid from EBN extract with efficient and high yield when using ABT.

호흡기를 통한 약액 전달을 위한 진세노사이드 초미세입자 분무장치 제작 (Fabrication of an ultra-fine ginsenoside particle atomizer for drug delivery through respiratory tract)

  • 이병철;박진수;양웅모
    • 대한융합한의학회지
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    • 제2권1호
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    • pp.5-12
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    • 2021
  • Objectives: The purpose of this study is to fabricate an ultra-fine ginsenoside particle atomizer that can provide a new treatment method by delivering ginsenoside components that have a therapeutic effect on respiratory diseases directly to the lungs. Methods: We fabricated the AAO vibrating mesh by using the micromachining process. The starting substrate of an AAO wafer has a 350nm pore diameter with 50㎛ thickness. A photomask having several 5㎛ opening holes with a 100㎛ pitch was used to separate each nanopore nozzle. The photoresist structure was optimized to pattern the nozzle area during the lift-off process precisely. The commercial vibrating mesh was removed from OMRON's NE-U100 product, and the fabricated AAO vibrating mesh was installed. A diluted sample of 20mL with 30% red ginseng concentrate was prepared to atomize from the device. Results: As a result of liquid chromatography analysis before spraying the ginsenoside solution, ginsenoside components such as 20S-Rg3, 20R-Rg3, and Rg5 were detected. After spraying through the AAO vibrating mesh, ginsenosides of the same component could be detected. Conclusion: A nutrient solution containing ginsenosides was successfully sprayed through the AAO vibrating mesh with 350 nm selective pores. In particular, during the atomizing experiment of ginsenoside drug solution having excellent efficacy in respiratory diseases, it was confirmed that atomizing through the AAO vibrating mesh while maintaining most of the active ingredients was carried out.

굵은 골재의 종류와 초음파 속도의 관계성을 고려한 콘크리트 수직 거푸집 해체 시점 분석에 관한 연구 (A Study on the Analysis of Concrete Vertical form Demolding Timing Considering the Relationship between the Type of Coarse Aggregate and Ultrasonic Pulse Velocity)

  • 남영진;김원창;최형길;이태규
    • 한국건축시공학회지
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    • 제23권6호
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    • pp.683-692
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    • 2023
  • 본 연구에서는 보통 및 경량 굵은 골재를 사용한 콘크리트의 역학적 특성을 평가하기 위해 압축강도와 초음파 속도를 측정하였다. 압축강도에서는 재령 초기에서 보통골재 콘크리트가 높은 경향을 나타냈으나 시간 경과에 따라 경량골재 콘크리트가 높아지는 것을 알 수 있으며, 경량골재의 특징 중 높은 흡수율의 영향이라고 판단된다. 초음파 속도에서는 일정 시간을 제외하고 대부분 보통골재가 높은 경향을 나타냈으며, 골재의 내부 공극의 차이라고 판단된다. 압축강도와 초음파 속도의 상관관계를 통한 예측식의 상관계수(R2)가 0.95를 상회하며, 본 실험을 통한 예측식으로 강도 예측의 신뢰성이 높다고 판단된다.