• Title/Summary/Keyword: Pore distributions

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A Taxonomic Revision of the Subfamily Gobiinae(Pisces, Gobiidae) from Korea (한국산 망둑어아과 어류의 분류학적 재검토)

  • KIM Ik-Soo;LEE Yong-Joo;KIM Yong-Uk
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.20 no.6
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    • pp.529-542
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    • 1987
  • Thirty three species belonging to twenty genera in the subfamily Gobiinae of Korea were reviewed and key to species and genera were provided. Among them twenty seven species captured during 1985-1987 were examined on the cephalic sensory canal systems for the taxonomic review, and classified into 4 groups based on the presence or absence of the canal and their canal pore patterns. It was confirmed that the pore patterns of preopercular and anterior ocular-scapular canal were important in the diagnosis of gobiid genera or species and in the discussion of the specialized species group. It was considered that the genus of Acentrogobius masago should be transferred to Pseudogobius from Acentrogobius, because A. masago was more similar to P. jausnicus than to A. pflaumi and its congeneric species in their cephalicc sensory canal systems. Some populations of Chaenogobius annularis and Acanthogobius lactipes showed the geographical variations in cephalic pit organs and the number of predorsal scales. The endemic gobiid species was not found the Korean waters, but some species showed a disjunct distributions between the west and the east coast waters in Korea. The south coast was inhabited by the abundant species including twenty seven species of seventeen genera. The genera of Acanthogobius, Chaenogobius, and Chasmichthys were considered to be the common genera in Korean waters.

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Study on Major Mineral Distribution Characteristics in Groundwater in South Korea (국내 지하수의 주요 미네랄 분포 특성에 관한 연구)

  • Kim, Jeonghee;Ryoo, Rina;Lee, Jongsu;Song, Daesung;Lee, Young-Joo;Jun, Hang-Bae
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.10
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    • pp.566-573
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    • 2016
  • In order to support effective usage of groundwater as an alternative water resource in future, we investigated distribution characteristics of minerals related with human health. While recent studies tended to focus on small scale, this study broadened research area up to nationwide scale to understand groundwater hydrology and regional, geological distributions of minerals in wide area; we investigated mineral distributions of national groundwater monitoring networks, developed GIS-based mineral maps, and reviewed correlation with geological features. As a result, calcium showed the highest concentration among 5 minerals (Ca, Mg, Na, K, Si) and potassium showed the lowest. Calcium concentration in limestone and sedimentary zone was the highest, and that in pore-volcanic-rock zone was the lowest. While calcium, magnesium and sodium showed differences in concentrations in intrusive-igneous-rock and sedimentary zone, potassium was not within geological features. When we studied regional differences, there were no tendency, but Jeju and Gangwon area showed differences in concentrations of calcium and silica.

Effects of Pressure-shift Freezing on the Structural and Physical Properties of Gelatin Hydrogel Matrices

  • Kim, Byeongsoo;Gil, Hyung Bae;Min, Sang-Gi;Lee, Si-Kyung;Choi, Mi-Jung
    • Food Science of Animal Resources
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    • v.34 no.1
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    • pp.33-39
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    • 2014
  • This study investigates the effects of the gelatin concentration (10-40%, w/v), freezing temperatures (from $-20^{\circ}C$ to $-50^{\circ}C$) and freezing methods on the structural and physical properties of gelatin matrices. To freeze gelatin, the pressure-shift freezing (PSF) is being applied at 0.1 (under atmospheric control), 50 and 100 MPa, respectively. The freezing point of gelatin solutions decrease with increasing gelatin concentrations, from $-0.2^{\circ}C$ (10% gelatin) to $-6.7^{\circ}C$ (40% gelatin), while the extent of supercooling did not show any specific trends. The rheological properties of the gelatin indicate that both the storage (G') and loss (G") moduli were steady in the strain amplitude range of 0.1-10%. To characterize gelatin matrices formed by the various freezing methods, the ice crystal sizes which were being determined by the scanning electron microscopy (SEM) are affected by the gelatin concentrations. The ice crystal sizes are affected by gelatin concentrations and freezing temperature, while the size distributions of ice crystals depend on the freezing methods. Smaller ice crystals are being formed with PSF rather than under the atmospheric control where the freezing temperature is above $-40^{\circ}C$. Thus, the results of this study indicate that the PSF processing at a very low freezing temperature ($-50^{\circ}C$) offers a potential advantage over commercial atmospheric freezing points for the formation of small ice crystals.

Determination of Consolidation Characteristics of Clayey Soils from the Self-boring Pressuremeter Test (자가굴착식 프레셔미터 시험을 이용한 점성토의 압밀특성 산정)

  • 장인성;정충기;김명모;조성민
    • Journal of the Korean Geotechnical Society
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    • v.18 no.2
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    • pp.87-96
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    • 2002
  • The strain holding test(SHT) or the sell-boring pressuremeter test(SBPT) has been effectively utilized to determine the horizontal coefficient of consolidation$(c_h)$ of clayey soils. However, a commonly used procedure proposed by Clarke et al.(1979) can lead to an erroneous estimation of $(c_h)$ because of its simplified assumptions. This paper deals with numerical analyses based on realistic test conditions of the generally accepted testing procedure, and .using the most commonly used type of pressuremeter. The effects of pressuremeter geometry, partial drainage during cavity expansion, and the cavity strain level for the holding test are investigated with the radial distributions of the initial excess pore pressure and their dissipation rate. Based on the results of the numerical analyses, the curve of the time factor for the 50% degree of consolidation($T_{50}$) needed to estimate $(c_h)$ is proposed. Comparisons are made between $(c_h)$ values estimated from the SHT or the SBPT and those obtained from other in situ and laboratory tests performed at two sites in Korea. These results suggest the improved capability of the $T_{50}$ curve proposed herein.

Preparation of Mesoporous Molecular Sieve by the Reaction of Na2SiO3 and H2SiF6 in the Presence of an Aqueous Nonionic Surfactant Solution (비이온성 계면활성제 수용액에서 Na2SiO3와 H2SiF6의 반응을 통한 메조포러스 실리카의 제조)

  • Kim, Jin-Yeong;Kwon, Oh-Yun
    • Applied Chemistry for Engineering
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    • v.29 no.1
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    • pp.122-126
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    • 2018
  • Mesoporous molecular sieves were prepared by the reaction of $Na_2SiO_3$ and $H_2SiF_6$ using nonionic micelle templates in an aqueous solution. Well-crystalline mesoporous molecular sieves were obtained after several seconds at atmospheric conditions. Powder samples exhibited d-spacing of 3.8-5.1 nm with the sharpness of the d00l peak, showing well-crystalline mesoporous molecular sieves, pore size distributions of 2.5-3.1 nm and large specific surface areas of $290-1,018m^2/g$, depending on types of surfactants. SEM images of samples showed well-divided spherical particles with an uniform size of ${\sim}0.5{\mu}m$ and TEM images demonstrated uniform pores with a worm hole shape.

Electrochemical Behavior of Pt-Ru Catalysts on Zeolite-templated Carbon Supports for Direct Methanol Fuel Cells

  • Lim, Tae-Jin;Lee, Seul-Yi;Yoo, Yoon-Jong;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.35 no.12
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    • pp.3576-3582
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    • 2014
  • Zeolite-templated carbons (ZTCs), which have high specific surface area, were prepared by a conventional templating method using microporous zeolite-Y for catalyst supports in direct methanol fuel cells. The ZTCs were synthesized at different temperatures to investigate the characteristics of the surface produced and their electrochemical properties. Thereafter, Pt-Ru was deposited at different carbonization temperatures by a chemical reduction method. The crystalline and structural features were investigated using X-ray diffraction and scanning electron microscopy. The textural properties of the ZTCs were investigated by analyzing $N_2$/77 K adsorption isotherms using the Brunauer-Emmett-Teller equation, while the micro- and meso-pore size distributions were analyzed using the Barrett-Joyner-Halenda and Harvarth-Kawazoe methods, respectively. The surface morphology was characterized using transmission electron microscopy and inductively coupled plasma-mass spectrometry. The electrochemical properties of the Pt-Ru/ZTCs catalysts were also analyzed by cyclic voltammetry measurements. From the results, the ZTCs carbonized at $900^{\circ}C$ show the highest specific surface areas. In addition, ZTC900-PR led to uniform dispersion of Pt-Ru on the ZTCs, which enhanced the electro-catalytic activity of the Pt-Ru catalysts. The particle size of ZTC900-PR catalyst is about 3.4 nm, also peak current density from the CV plot is $12.5mA/cm^2$. Therefore, electro-catalytic activity of the ZTC900-PR catalyst is higher than those of ZTC1000-PR catalyst.

Thermal Phenomena of an N2O Catalyst Bed for Hybrid Rockets Using a Porous Medium Approach (다공성 매질 접근법을 적용한 하이브리드 로켓 N2O 촉매 점화기의 열적 현상)

  • 유우준;김수종;김진곤;장석필
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.9
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    • pp.89-96
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    • 2006
  • In this study, fluid flow and thermal characteristics in a catalyst bed for nitrous oxide catalytic decomposition which is introduced as a hybrid rocket ignition system for small satellites were theoretically considered. To analyze the thermal phenomena of the catalyst bed, a so-called porous medium approach has been opted for modeling the honeycomb geometry of the catalyst bed. Using a Brinkman-extended Darcy model for fluid flow and the one-equation model for heat transfer, the analytical solutions for both velocity and temperature distributions in the catalyst bed are obtained and compared with experimental data to validate the porous medium approach. Based on the analytical solutions, parameters of engineering importance are identified to be the porosity of the catalyst bed, effective volumetric ratio, the ratio of the radius of the catalyst bed to the radius of a pore, heat flux generated by a heater, and pumping power. Their effects on thermal phenomena of the catalyst bed are studied.

Adsorption Characteristics of Elemental Iodine and Methyl Iodide on Base and TEDA Impregnated Carbon (활성탄을 이용한 원소요오드 및 유기요오드 흡착특성)

  • Lee, Hoo-Kun;Park, Geun-Il
    • Nuclear Engineering and Technology
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    • v.28 no.1
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    • pp.44-55
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    • 1996
  • For the purpose of controlling the release of radioiodine to the environment in nuclear power plants, adsorption characteristics of elemental iodine and methyl iodide on the base carbon and 2%, 5% TEDA impregnated carbons were studied. The amounts of adsorption of elemental iodine and methyl iodide on the carbons were compared with Langmuir, Freundlich, Sips and Dubinin-Astakhov(DA) isotherm equations. Adsorption data were well correlated by the DA equation based on the potential theory. Adsorption energy distributions were obtained from the parameters of the DA equation derived from the condensation approach method. For the adsorption of methyl iodide and elemental iodine-carbon system, the DA equation can be well expressed by the degree of heterogeneity of the micropore system because the surface is nonuniform when its potential energy is unequal. The adsorption energy distribution wes investigated to find a surface heterogeneity on the carbon. The surface heterogeneity for iodine-carbon system is highly affected by the adsorbate-adsorbent interaction as well as the pore structure. The surface heterogeneity increases as a content of TEDA impregnated increases. The adsorption nature of methyl iodide on carbon turned out to be more heterogeneous than that of elemental iodine.

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Hydration and Carbonation Properties of Different Hydraulic Lime (수경성석회 종류에 따른 수황 및 탄산화 특성)

  • Moon, Ki-Yeon;Choi, Moon-Kwan;Cho, Kye-Hong;Cho, Jin-Sang;Ahn, Ji-Whan;Yeon, Kyu-Seok
    • Journal of the Korean Ceramic Society
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    • v.51 no.2
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    • pp.72-81
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    • 2014
  • The main mineral phases of natural hydraulic lime (NHL) as a hydraulic lime binderare $Ca(OH)_2$, $C_2S$, $C_3S$, $C_3A$, and $SiO_2$ residues. Also, NHL has the characteristic of setting and hardening by a hydration reaction with water and by carbonation reactions with carbon dioxide from the air. In this study, in an effort to investigate changes of the mineral phases by NHL hydration and carbonation reactions, transitions of mineral phases and the microstructures of hardened pastes were analyzed by XRD, DSC, SEM, and by pore size distributions using domestic and foreign-sourced NHL pastes after curing at 1, 3, 7, and 28 days. On the basis of the analysis results, it was confirmed that domestic low-grade limestone can be used for the manufacturing of NHL. The main hydration mineral phases were $Ca(OH)_2$, $CaCO_3$, $C_2S$, and $SiO_2$ residues, while in the case of foreign-sourced NHL, a small amount of an aluminium hydration phase formed. Also, the $CaCO_3$ content after the carbonation reaction increased with an increase in the curing time. After hydration for 28 days, NHL containing considerable amounts of $C_2S$ and $C_3S$ showed higher carbonation ratios than others types.

Acoustic Abosrption Characteristic and Fabrication process of Foamed Aluminum (발포알루미늄의 제조공정 및 흡음특성)

  • Hur, Bo-Young;Ahn, Hyo-Jun;Jeon, Sung-Hwan;Choi, Dae-Choul;Kim, Sang-Youl;Hur, Yoon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2000.11a
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    • pp.396-402
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    • 2000
  • Porous structures of aluminum foam have been studied. The apparent foam shape, foam hight, density, pore size, shape, and their distributions in various section areas of the experimental samples have been investigated. The sample have been cast into metallic mold, using aluminum foam prepared from a precursor based on pure Al ingot mixed with various amount of 1-2wt% increasing viscosity and foam agent materials. The process provides for flexibility in design of foam structures via relatively easy control over the amount of hydrogen evolution and the drainage processes which occur during foam formation. This is facilitated by manupulating parameters such as the foaming agent, thermal histories during solidification and mix melt viscosities. The acoustical performance of the panel made with the foamed aluminum is considerably improved; its absorption coefficient shows NRC 0.6-0.8. It has been found that the Al foam is very preferable for the compactness of the thermal system.

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