• Title/Summary/Keyword: Pore distributions

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Mapping Particle Size Distributions into Predictions of Properties for Powder Metal Compacts

  • German, Randall M.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.704-705
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    • 2006
  • Discrete element analysis is used to map various log-normal particle size distributions into measures of the in-sphere pore size distribution. Combinations evaluated range from monosized spheres to include bimodal mixtures and various log-normal distributions. The latter proves most useful in providing a mapping of one distribution into the other (knowing the particle size distribution we want to predict the pore size distribution). Such metrics show predictions where the presence of large pores is anticipated that need to be avoided to ensure high sintered properties.

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Preparation and Characteristics of Polyethersulfone Microfiltration Membranes (폴리에테르술폰 정밀여과막의 제조 및 특성 연구)

  • Kim, No-Won
    • Membrane Journal
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    • v.17 no.4
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    • pp.329-337
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    • 2007
  • This is the research about a new method to make the internal separation layer with smallest pore size in polyethersulfone (PES) membrane by adding p-toluenesulfonic acid (TSA) and polyvinylpyrolidone (PVP) to polymeric PES solution. The preparation and morphological characterization of PES sheet membranes containing PVP as a hydrophilic swelling material and TSA as a demixing material were performed. As a result by microflow porometery, the PVP and TSA added PES membranes showed good permeabilities and narrow pore size distributions, comparable to those of the commercial membranes. The concentration of PVP affected the PES characteristics on air permeability and surface structure. The concentration of TSA influenced on pore size distribution but do not affect air permeability. The surface images of FE-SEM shows similar pore size when TSA added or not. However, the cross-section images of FE-SEM show that the TSA added PES membranes have a increase of internal layer thickness with smallest pore size.

Effect of Processing and Reactive Dyeing on Swelling and Pore Structure of Lyocell Fibers

  • Sasaki, Hiroaki;Donkai, Nobuo;Kasahara, Katusji
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.33-34
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    • 2003
  • Lyocell yarns were treated with NaOH, liquid ammonia, high pressure steam and polycarboxylic acids, and dyed with five reactive dyes. The water content of the samples was also measured by the centrifugal and chromatographic techniques. The total pore volume w as substantially increased by NaOH treatment, while decreased by high pressure steaming. The pore size distributions for the dyed samples were affected by the dyes used.

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A model to characterize the effect of particle size of fly ash on the mechanical properties of concrete by the grey multiple linear regression

  • Cui, Yunpeng;Liu, Jun;Wang, Licheng;Liu, Runqing;Pang, Bo
    • Computers and Concrete
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    • v.26 no.2
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    • pp.175-183
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    • 2020
  • Fly ash has become an important component of concrete as supplementary cementitious material with the development of concrete technology. To make use of fly ash efficiently, four types of fly ash with particle size distributions that are in conformity with four functions, namely, S.Tsivilis, Andersen, Normal and F distribution, respectively, were prepared. The four particle size distributions as functions of the strength and pore structure of concrete were thereafter constructed and investigated. The results showed that the compressive and flexural strength of concrete with the fly ash that conforming to S.Tsivilis, Normal, F distribution increased by 5-10 MPa and 1-2 MPa, respectively, compared to the reference sample at 28 d. The pore structure of the concrete was improved, in which the total porosity of concrete decreased by 2-5% at 28 d. With regarding to the fly ash with Andersen distribution, it was however not conducive to the strength development of concrete. Regression model based on the grey multiple linear regression theory was proved to be efficient to predict the strength of concrete, according to the characteristic parameters of particle size and pore structure of the fly ash.

Resistance In Chloride ion Penetration and Pore Structure of Concrete Containing Pozzolanic Admixtures (포졸란재 함유 콘크리트의 세공구조와 염화물이온 침투 저항성)

  • 소양섭;소형석
    • Journal of the Korea Concrete Institute
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    • v.14 no.1
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    • pp.100-109
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    • 2002
  • Significant damage to concrete results from the intrusion of corrosive solutions, for example, dissolved chlorides corrode reinforcing steel and cause spatting. Effectively blocks the penetration of these solutions will eliminate or greatly reduce this damage and lead to increased durability. This study is to investigate the effects of pozzolanic admixtures, fly ash and silica fume, and a blast furnace slag on the chloride ion penetration of concretes. The main experimental variables wore the water-cementitious material ratios, the types and amount of admixtures, and the curing time. And it is tested for the porosity and pore size distributions of cement paste, chloride ion permeability based on electrical conductance, and 180-day ponding test for chloride intrusion. The results show that the resistance of concrete to the penetration of chloride ions increases as the w/c was decreased, and the increasing of curing time. Also, concrete with pozzolans exhibited higher resistance to chloride ion penetration than the plain concrete. The significant reduction in chloride ion permeability(charge passed) of concrete with pozzolans due to formation of a discontinuous macro-pore system which inhibits flow. It is shown that there is a relationship between chloride ion permeability and depth of chloride ion penetration of concrete, based on the pore structure (porosity and pore size distributions) of cement paste.

Electrode properties of various carbon anodes containing different sizes and distributions of pores (다양한 기공 크기 및 분포를 갖는 양극 탄소의 전극 특성)

  • 안홍주;오한준;김인기;김세경;임창성;지충수;이재봉;박광규;고영신
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.1
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    • pp.42-49
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    • 2002
  • Differences in electrode properties and in fluorine electrolysis behaviors of various carbon anodes, which were the YBD-like grade carbon, the YBD grade carbon and the P2X grade carbon, containing different pore sizes and distributions were investigated. The evaluations were performed by measuring their mechanical properties, cyclic voltammograms and chronoamperometries in 0.5 M $K_2SO_4$ solution with 1 mM $[[Fe(CN)_6]^\;{3-}/Fe(CN)_6$] $^{4-}$ redox couple and electrochemical behaviours of fluorine electrolysis in molten KF . 2HF electrolyte at $85^{\circ}C$. It was found that the P2X grade carbon anode showed better electrode properties in the cyclic voltammogram and chronoamperometry than the other carbon anodes while the YBD-like grade carbon anode which contained the pore size of 200~300$\mu$m showed superior electrode properties for fluorine electrolysis to the others. These differences in the electrode properties of various carbon anodes seemed to be owing to different sizes and distributions of pores on their surfaces.

Pore Size and Distribution of Polyester Fabrics Determined by Liquid Extraction Method (액체유출법에 의한 폴리에스테르 직물의 기공 크기 및 분포 측정)

  • Lee, Dong-Hwa;Yeo, Suk-Yeong;Kim, Eun-Ae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.21 no.1
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    • pp.206-216
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    • 1997
  • The purpose of this study was to determine the pore size distributions (PSDs) of polyester woven fabrics by using liquid extraction method. Three types of PSDs-percent PSD, PSD per unit area of sample and PSD per unit weight of sample-were evaluated. Plain, twill and satin polyester fabrics with various fabric counts were used as specimens. Results showed that the interyarn PSDs reflected the fabric characteristics such as the fabric count and the weave type and the intrayarn PSDs reflected the thread characteristics such as the number of fibers, the fiber diameter, the thread diameter and the thread twist. Of three types of PSDs, the PSD per unit area of sample best reflect fabric and thread characteritics. As the fabric count decreased, rc increased and interyarn pore volume increased. The PSDs were skewed to the small pore sizes and the pore volumes decreased in the order of plain> twill> satin. As the number of fibers, the fiber diameter and the thread twist decreased, the intrayarn pore volumes were increased.

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Preparation of novolac-type phenol-based activated carbon with a hierarchical pore structure and its electric double-layer capacitor performance

  • Lee, Dayoung;Jung, Jin-Young;Park, Mi-Seon;Lee, Young-Seak
    • Carbon letters
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    • v.15 no.3
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    • pp.192-197
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    • 2014
  • A hierarchical pore structured novolac-type phenol based-activated carbon with micropores and mesopores was fabricated. Physical activation using a sacrificial silicon dioxide ($SiO_2$) template and chemical activation using potassium hydroxide (KOH) were employed to prepare these materials. The morphology of the well-developed pore structure was characterized using field-emission scanning electron microscopy. The novolac-type phenol-based activated carbon retained hierarchical pores (micropores and mesopores); it exhibited high Brunauer-Emmett-Teller specific surface areas and hierarchical pore size distributions. The hierarchical pore novolac-type phenol-based activated carbon was used as an electrode in electric double-layer capacitors, and the specific capacitance and the retained capacitance ratio were measured. The specific capacitances and the retained capacitance ratio were enhanced, depending on the $SiO_2$ concentration in the material. This result is attributed to the hierarchical pore structure of the novolac-type phenol-based activated carbon.

A Study on the Relationship between the Pore Volume Distributions of Some Adsorbents Including Charcoal and the Rates of Adsorption of a Number of Cigarette Aerosol Ingredients such as Tar, Nicotine and etc. (활성탄을 포함하는 몇 가지 흡착제의 동공부피 분포와 이들의 흡착제에 대한 타르, 유기산 등 연초 에어로솔 성분의 흡착률과의 관련성)

  • Ick Kyun Kang;Sang Hyun Han;Yong Kwon Kim;Eun Hee Cha
    • Journal of the Korean Chemical Society
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    • v.33 no.4
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    • pp.350-356
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    • 1989
  • The analysis of adsortion behaviors of some cigarett aerosol ingredients such as tar, nicotine, carbon monoxide and a number of organic acids has shown that the rates of adsorption of the adsorbates of lower boiling point had increased in accordance with increasing cumulative pore volume, while that of higher doiling point decreased with increasing pore volume of smaller radius. The adsorbents used here were charcoal, silica gel, alumina, and activated clay. The common principle that the adsorbents of greater specific surface area adsorb the larger amount of adsorbates appeared to be disturbed in the adsortion of higher boiling point adsorbates. This confirmation was made mainly by analyzing the adsorption behaviors with regard to the pore volume distributions evaluated on the bases of desorption isotherms.

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