• 제목/요약/키워드: Pore Development

검색결과 514건 처리시간 0.031초

Pulse도금법에 의한 Ag주입 양극산화 알루미늄 합금의 항균특성에 관한 기초연구 (A Study on the Antibacterial Properties of Ag Electropulsed Anodized Aluminium Alloy)

  • 임기영;기준서;장용석;이우민;윤정모
    • 한국재료학회지
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    • 제16권10호
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    • pp.639-646
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    • 2006
  • Over the last two decades, microbiologically influenced corrosion (MIC) of metallic materials has received considerable attention due to its serious effects on industrial field. In this context, it is important to devise control methods which inhibit biofilm formation on various metallic compounds and are compatible with environment. It was change of various conditions (duty cycle, current density, $AgNO_3$ concentration and pH) for injection of Ag particles in anodized Aluminum alloy pore using pulsed current. Optimal condition was obtained by means of FE-SEM, ICP analysis etc. The antibacterial metal's specimen were manufactured under optimal condition and this specimen were tested the antibacterial characterization and anticorrosion characterization. In result of test, we can confirmed that the antibacterial characterization and anticorrosion characterization of the specimens of injected Ag particles in anodized Aluminum alloy pore using pulsed current were better than the anodized Aluminum alloy specimens.

Resistance of Cementitious Binders to Chloride Induced Corrosion of Embedded Steel by Electrochemical and Microstructural Studies

  • Song, Ha-Won;Ann, Ki-Yong;Kim, Tae-Sang
    • Corrosion Science and Technology
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    • 제8권2호
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    • pp.74-80
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    • 2009
  • The high alkaline property in the concrete pore solution protects the embedded steel in concrete from corrosion due to aggressive ions attack. However, a continuous supply of those ions, in particular, chlorides altogether with a pH fall in electrochemical reaction on the steel surface eventually depassivate the steel to corrode. To mitigate chloride-induced corrosion in concrete structures, finely grained mineral admixtures, for example, pulverized fuel ash (PFA), ground granulated blast furnace slag (GGBS) and silica fume (SF) have been often advised to replace ordinary Portland cement (OPC) partially as binder. A consistent assessment of those partial replacements has been rarely performed with respect to the resistance of each binder to corrosion, although the studies for each binder were extensively looked into in a way of measuring the corrosion rate, influence of microstructure or chemistry of chlorides ions with cement hydrations. The paper studies the behavior of steel corrosion, chloride transport, pore structure and buffering capacity of those cementitious binders. The corrosion rate of steel in mortars of OPC, 30% PFA, 60% GGBS and 10% SF respectively, with chloride in cast ranging from 0.0 to 3.0% by weight of binder was measured at 7, 28 and 150 days to determine the chloride threshold level and the rate of corrosion propagation, using the anodic polarization technique. Mercury intrusion porosimetry was also applied to cement pastes of each binder at 7 and 28 days to ensure the development of pore structure. Finally, the release rate of bound chlorides (i.e. buffering capacity) was measured at 150 days. The chloride threshold level was determined assuming that the corrosion rate is beyond 1-2 mA/$m^3$ at corrosion and the order of the level was OPC > 10% SF > 60% GGBS > 30% PFA. Mercury intrusion porosimetry showed that 10% SF paste produced the most dense pore structure, followed by 60% GGBS, 30% PFA and OPC pastes, respectively. It was found that OPC itself is beneficial in resisting to corrosion initiation, but use of pozzolanic materials as binders shows more resistance to chloride transport into concrete, thus delay the onset of corrosion.

포화 및 부분 포화 사질토의 Vp와 Vs 속도 및 과잉간극수압 측정을 위한 비틂전단 시험기의 개발 (Development of Torsional Shear Testing System to Measure P-wave Velocity, S-wave Velocity and Pore Water Pressure Buildup on Fully and Partially Saturated Sands)

  • 김동수;이세현;추연욱
    • 한국지반환경공학회 논문집
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    • 제7권1호
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    • pp.55-66
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    • 2006
  • 사질토의 액상화에 대한 저항 강도는 포화도에 상당히 의존한다. 압축파 속도는 현장에서 쉽게 측정이 가능하고 포화도의 영향을 크게 받기 때문에 현장 지반의 포화도를 예측하고자 할 때 효율적으로 사용될 수 있다. 본 논문에서는 시료의 포화가 가능하고 전단파, 압축파 속도 측정 및 비배수 상태에서 비틂전단 시험을 수행시 유발되는 과잉간극수압을 측정할 수 있는 비틂전단 시험기를 개발하였다. 토요라 모래에 대해 전단파, 압축파 속도 측정이 수행되고, 비배수 비틂전단 시험을 실시하였다. 포화도(B값)에 따른 시료의 전단파 속도 및 압축파 속도를 이론식과 비교하여 개발된 시험기를 검증하였으며, 여러 B값에서 비배수 TS 시험동안 유발되는 과잉 간극수압의 변화를 측정 분석하였다.

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온도 조절을 통한 다공성 폴리우레탄 동정맥 누관의 개발 (Development of Porous polyurethane Arterial-Venous Shunt by Thermal Control)

  • 정재승;유규하;김종원;민병구
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1997년도 추계학술대회
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    • pp.478-481
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    • 1997
  • A technique or the preparation of porous polyurethane vascular prostheses was investigated. Small-diameter vessels are not in general clinical use due to their limited long-term biocompatibility and low patency rates in experimental trial. These limits are mainly due to the failure of mechanical unction of the vascular grafts. This failure has been suggested to result partially from compliance mismatch. The long-term patency is considered to depend critically on the properties of the material and the fabrication process of the graft. So the control of pores is very important and main points to develop a available vascular grafts. Two-kind polymer sheets was compared. One was the porous PU-sheet made at room temperature by the solvent/non-solvent exchange. And the other was the porous PU-sheet which was fabricated by thermal phase transition and solvent-/non-solvent exchange using the thermal controller. The polymer sheets had a uniform pore size and pore occupation. According to the result of the above experiments, polyurethane solution was injected into a mold designed or U-type tube. The average pore size and pore occupation were easily changed by changing polyurethane concentration, freezing temperature, and methods. This technique can give a proper pore size ($10{\sim}45\;{\mu}m$) or tissue in growth, and suitable compliances or matching with arteries and veins. Besides, the fabrication of more complicated shaped vessels such as the U-type vascular grafts is easily controlled by using the fixed mold. this method might give a desired compliant graft or artificial implantation with the presently valid medical polymers.

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Microstructure of Non-Sintered Inorganic Binder using Phosphogypsum and Waste Lime as Activator

  • Kim, Ji-Hoon;An, Yang-Jin;Mun, Kyung-Ju;Hyung, Won-Gil
    • 한국건축시공학회지
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    • 제18권3호
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    • pp.305-312
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    • 2018
  • This study is about the development of a non-sintered binder (NSB) which does not require a sintering process by using the industrial by-products Phosphogypsum (PG), Waste Lime (WL) and Granulated Blast Furnace Slag (GBFS). In this report, through SEM analysis of the NSB paste hardening body, micropore analysis of paste using the mercury press-in method and microstructure observation were executed to consider the influence of the formation of the pore structure and the distribution of pore volume on strength, and the following conclusions were reached. 1) Pore structure of NSB paste of early age is influenced by hydrate generation amount by GBFS and activator. 2) Through observing the internal microstructure of NSB binder paste, it was found that the strength expression at early age due to hydration reaction was achieved with a large amount of ettringite serving as the frame with C-S-H gel generated at the same time. It was confirmed that C-S-H gel wrapped around ettringite, and as time passed, the amount generated continually increased, and C-S-H gel tightly filled the pores of hardened paste, forming a dense network-type web structure. 3) For NSB-type cement, the degree of formation of gel pores below $10{\mu}m$ had a greater influence on strength improvement than simple pore reduction by charging capillary pores, and the pore size that had the greatest effect on strength was micropores with diameter below $10{\mu}m$.

액상화 해석을 위한 수정교란상태개념 모델 개발 (Development of Modified Disturbed State Concept Model for Liquefaction Analysis)

  • 박근보;최재순;박인준;김기풍;김수일
    • 한국지반공학회논문집
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    • 제24권3호
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    • pp.35-51
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    • 2008
  • 본 논문에서는 액상화 해석에 관한 DSC 모델을 실험 및 해석적 관점에서 그 적용성을 평가하였다. 포화 사질토의 동적거동을 보다 정확히 예측하기 위해 DSC 모델을 유효응력 경로와 과잉간극수압 발현에 기초하여 수정하였다. 액상화에 대한 동적거동 및 DSC 모델에 대한 매개변수 산정을 위해 정적배수삼축시험과 반복 비배수삼축시험을 상대밀도와 구속응력에 따라 수행하였다. 유효응력 경로와 과잉간극수압의 항으로 액상화 상태를 분류하고 수정된 DSC 모델을 적용시켜 액상화 해석을 수행하였다. 제안된 방법을 토대로 DSC 모델과 제안된 DSC 모델에 대한 액상화 해석을 상대밀도와 구속응력에 따라 비교하였다. 비교 결과 수정 모델은 액상화 시작점 및 동적 거동을 보다 정밀하게 평가하였고, 입력변수의 수가 감소하고 산정방법이 간편해졌다.

세탁 중 세탁물 중량과 여과 기공 크기에 따른 미세플라스틱 분석 (Analysis of microplastics released from textiles according to filter pore size and fabric weight during washing)

  • 최솔아;권미연;박명자;김주혜
    • 한국의상디자인학회지
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    • 제23권1호
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    • pp.37-45
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    • 2021
  • This study observed the release of microplastics according to washing weights and filtering conditions, measured microplastic generation rates, fiber lengths, and fiber diameters. This study attempted to present data for the development of filters that decrease microplastic generation. For test samples, polyester piled knit fabric (cut-pile) was selected, which currently has the highest amount of consumption in the clothing industry, but can easily cause marine pollution because of its low biodegradability. For test equipment, a drum washer was used and microplastics were collected using two filter pore sizes, 5 ㎛ and 20-25 ㎛. Microplastic fibers weights and lengths were measured. The results of the experiment showed the following: 1) The release of microplastics differed according to the fabric weights and washing process; 2) washing fabric weights showed a differences in the collection amount according to the filter pore size (5 ㎛, 20-25 ㎛); 3) observations of differences in the lengths of the microplastics that occur during the washing process by filter pore size were made. Fibers with shorter lengths appeared with filter pore sizes of 5㎛ in comparison to filter pore sizes of 20-25㎛. The results from this study on microplastic generation by fabric during washing, demonstrated the following conclusions that can be used to reduce the release of microplastics. First, the release of microplastics according to fabric weights and washing courses are affected by physical force. Therefore, it is necessary to reduce the amount of physical force due to water flow, increase the fabric weight, or wash the material in low temperatures. Second, in the manufacturing of washing machines, microplastic filtration can be promoted or legislatation supporting microplastic filtration can be introduced.

반복재하에 의한 미액상화 재성형 풍화토의 변형 특성 (Deformation Characteristics of Non-liquefied, Reconstituted, Weathered Residual Soils due to the Cyclic Loading)

  • 최연수;윤찬영;장의룡;정충기
    • 한국지반공학회논문집
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    • 제22권6호
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    • pp.41-49
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    • 2006
  • 이 논문에서는 반복적인 하중에 의해 발생한 동적 과잉간극수압의 발생과 소산을 실내시험을 통하여 연구하였다. 이를 위해 국내 건설 현장에서 건설재료로 널리 사용되고 있는 풍화토를 재성형하여 실내에서 반복삼축시험을 수행하였다. 그 결과 비배수 반복 재하 과정에서 발생하는 과잉간극수압은 반복재하하중과 구속압이 증가할수록 크게 나타남을 확인하였다. 여기서 이 두 가지 영향요소가 반영된 수정과잉간극수압비(MEPPR)를 제안하여, 과잉간극수압 거동을 반복재하횟수만으로 나타낼 수 있었다. 또한 과잉간극수압을 구속압으로 정규화한 과잉간극수압비(EPPR)를 이용하여, 구속압의 증가에 따라 감소하는 과잉간극수압 소산 시 부피변형률을 간편히 나타낼 수 있었다. 결론적으로 재성형 풍화토에 대하여 얻어진 실내 시험 결과를 토대로 지진 하중과 같은 동적 반복 재하 시 미액상화 조건에서 발생하는 침하량을 적은 수의 실험 결과로 간편하게 예측할 수 있는 방법 및 개념을 도출하였다.

나노급 도금공정을 위한 미세패턴 제어기술의 개발 (Development of control technique of nano-sized pattern for electroplating)

  • 이재홍;이병욱;이경호;김창교
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 하계학술대회 논문집 C
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    • pp.1576-1578
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    • 2004
  • The alumina membrane with nano sized pore was prepared from aluminum by anodic oxidation to apply for storage equipment, gas sensor and stamper. The pore size and cell size of the pores are controlled by anodic oxidation voltage. The alumina thickness was controlled by etching process using 0.2M $H_3PO_4$. The thickness of alumina on Si wafer was very accurately controlled by anodic oxidation time. Nickel with nano-sized grain was electroplated on the Au layer on silicon wafer. The fabricated pores on alumina membrane was the thickness of $7{\sim}10{\mu}m$ with straight nano-sized pore of 307${\sim}$120nm. The alumina by the etching process shows smooth surface. The size of Ni grain was 130nm and 250nm for 10mA/$cm^2$and 20mA/$cm^2$of electroplating currents, respectively.

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