• 제목/요약/키워드: Pore Development

검색결과 514건 처리시간 0.03초

Microstructural Evolution and Dielectric Response Characteristics During Crystallization of Amorphous Pb(Fe2/3W1/3)O3

  • Kim, Nam-Kyung;David A. Payne
    • The Korean Journal of Ceramics
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    • 제1권2호
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    • pp.75-80
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    • 1995
  • Development of phases, evolution of microstructures, and dielectric response characteristics of amorphous lead iron tungstates during crystabllization were investiageted. A series of mircographs showing the evolution sequence of microstructures is presented. Crystallization was observed to initiate from inside of the amorphous material. A cubic perovskite phase developed fully at $760^{\circ}C$ from amorphous state via intermediate metastable crystalline structures. Dielectric constant of amorphous PFM was totally insensitive to the temperature change around the Curie temperature of crystalline material. Sintered pellet, with relative density of 96% and an almost pore-free dense internal microstructure, could be prepared from amorphous powder.

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강우로 인한 사면 불안정 (Slope Instability Due to Rainfall)

  • 김상규;김영묵
    • 한국지반공학회지:지반
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    • 제7권1호
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    • pp.53-68
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    • 1991
  • 이 논문은 강우가 시작된 후 시간의 경과에 따른 불구화 지반에서의 여러가지 침투거동을 밝혀서, 서면 불안정의 구체적인 머케니즘을 이해하려는데 목적이 있다. 이를 위해 강우장치를 만들어 권쬐요면에 대해 여러가지 강도의 강우를 재현하고 침투거동을 측정하는 한편, 실험에서 사용한 동일한 수치권을 가지고 수치 해석을 하였다. 두가지 모델시 험 의 결과로부터 만윤전선이 진행되는 과정,지반으로 침투되는 한계강우량의 존재,지표류출의 영향,시간의 경과에 따른 간극수압의 변화 등을 밝혀서 이들 인자들이 사면 불안정에 어떻게 영향을 끼치는가를 자세히 언급하였다.

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부산점토의 변형률 속도 의존적인 압밀특성 (Strain-rate-dependent consolidation characteristics of Busan clay)

  • 김윤태;조상찬;조기영
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2005년도 춘계 학술발표회 논문집
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    • pp.240-247
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    • 2005
  • In order to analyze effects of strain rate on consolidation characteristics on Busan clay, a series of constant rate of strain(CRS) consolidation tests with different strain rate and incremental loading test(ILT) were performed. From experimental test results, it was found that the preconsolidation pressure was dependent on the corresponding strain rate occurred during consolidation process. Also, consolidation curves normalized with respect to preconsolidation pressure gave a unique stress-strain curve. Coefficient of consolidation and permeability estimated from CRS test had a tendancy to converge to a certain value at normally consolidated range regardless of strain rate. An increase in excess pore pressure without change of total stress was noted on the incremental loading test after the end of loading.

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고온석탄가스에서 황화물을 제거하기 위한 다공성 흡착제의 개발 -II. 산화아연의 황화반응에 관한 연구- (Development of Porous Sorbents for Removal of Hydrogen Sulfide from Hot Coal Gas -II. Kinetics of Suffidation on Zinc Oxide -)

  • 서인식;이재복;류경옥
    • 한국환경보건학회지
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    • 제14권1호
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    • pp.11-22
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    • 1988
  • Calcium oxide, lithium oxide and titanium oxide were investigated as additives of zinc oxide for the removal of hydrogen sulfide at high temperature. This experiment was performed in the range of 1.0-2.0 vol.% H$_2$S concentration at 623-873 K reaction temperature, using a thermogravimetric analyzer. A pore blocking model was found to fit the reaction rate and the kinetics data were sucessfully expressed by this model. The reactions between additive sorbents and hydrogen sulfide were first order with respect to hydrogen sulfide concentration in a gaseous mixture with nitrogen. Among the used sorbents, ZnO-CaO 0.5 at.% and ZnO-TiO$_2$ 2.0 at.% sorbents had the best additive effects on the sulfidation reaction between additive sorbents and hydrogen sulfide, whereas the ZnO-Li$_2$O sorbents were ineffective.

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Effects of carbonization temperature on pore development in polyacrylonitrile-based activated carbon nanofibers

  • Lee, Hye-Min;An, Kay-Hyeok;Kim, Byung-Joo
    • Carbon letters
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    • 제15권2호
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    • pp.146-150
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    • 2014
  • In this work, activated carbon nanofiber (ACNF) electrodes with high double-layer capacitance and good rate capability were prepared from polyacrylonitrile nanofibers by optimizing the carbonization temperature prior to $H_2O$ activation. The morphology of the ACNFs was observed by scanning electron microscopy. The elemental composition was determined by analysis of X-ray photoelectron spectroscopy. $N_2$-adsorption-isotherm characteristics at 77 K were confirmed by Brunauer-Emmett-Teller and Dubinin-Radushkevich equations. ACNFs processed at different carbonization temperatures were applied as electrodes for electrical double-layer capacitors. The experimental results showed that the surface morphology of the CNFs was not significantly changed after the carbonization process, although their diameters gradually decreased with increasing carbonization temperature. It was found that the carbon content in the CNFs could easily be tailored by controlling the carbonization temperature. The specific capacitance of the prepared ACNFs was enhanced by increasing the carbonization temperature.

달걀 껍질을 재활용한 탈황제의 제조에 관한 연구 (Study on Manufacturing Desulfurization Sorbent using Eggshell)

  • 이병호;이봉헌;박흥재;김우성
    • 한국환경과학회지
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    • 제7권5호
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    • pp.693-696
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    • 1998
  • We tried to develope a desulfurization sorbent using eggshell for recycling, practicability, and economic development. The calcination character of the eggshell was examined by thermal gravimetric analysis and qualitative-quantitative character by X-ray diffractometer(XRD) and scanning electron microscope(SEM). The calcination was occurred easily in the case of eggshell and its form was changed from calcite($CaCO_3$) to lime(CaO). The grain and pore sizes of the calcined sample after base-treatment were larger and more crystallic. The adsorption ability of the eggshell was two- to six-times in the calcination temperature more than in the grain size. Therefore, the eggshell was thought to be usable as the desulfurization sorbent.

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Effects of nanomaterials on hydration reaction, microstructure and mechanical characteristics of cementitious nanocomposites: A review

  • Kim, Gwang Mok
    • 도시과학
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    • 제9권1호
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    • pp.7-16
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    • 2020
  • Application of nanomaterials to cementitious composites has been attempted with the rapid development of nanotechnology since the 1990s. Various nanomaterials such as carbon nanotube, graphene, nano-SiO2, nano-TiO2, nano-Al2O3, nano-Clay, and nano-Magnetite have been applied to cementitious composites to improve the mechanical properties and the durability, and to impart a variety of functionality. In-depth information on the effect of nanomaterials on the hydration reaction, the microstructure, and the mechanical properties of cementitious nanocomposites is provided in the present study. Specifically, this paper mostly deals with the previous studies on the heat evolution characteristics of cementitious nanomaterials at an early age of curing, and the pore and the compressive strength characteristics of cementitious nanocomposites. Furthermore, the effect of nanomaterials on the cementitious nanocomposites was systematically discussed with the reviews.

Comparison of behaviour of basal reinforced piled embankment with two layer of reinforcement

  • Balaban, Eren;Onur, Mehmet I.
    • Geomechanics and Engineering
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    • 제16권3호
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    • pp.233-245
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    • 2018
  • Interest to basal reinforced piled embankments is increasing recently due to their rapid construction and reliability. A comprehensive parametric study is conducted to determine effects of pile properties, reinforcement stiffness, embankment properties and soft soil properties into settlements, pressures and excess pore water pressure development and dissipations. Results which are obtained by using one-layer reinforcement during construction are compared with the results obtained by using two-layer reinforcement during construction. Finite element method is used during the parametric study. Second layer of reinforcement is placed in five different positions in order to reveal effects of reinforcement position into behaviour. Traffic load is also taken into consideration during the study. Differences between the results without presence of traffic loading and with presence of traffic loading is stated in this the study.

알칼리활성화 슬래그-레드머드 흙포장재의 레드머드 대체율에 따른 기공특성 (Porosity of Alkali-Activated Slag-Red Mud Soil Mixed Pavement of Red Mud Substitution Rate)

  • 강혜주;김병기;김재환;강석표
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2016년도 추계 학술논문 발표대회
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    • pp.91-92
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    • 2016
  • Red mud is an inorganic by-product produced from the mineral processing of alumina from Bauxite ores. the development of alkali-activated slag-red mud cement can be a representative study aimed at recycling the strong alkali of the red mud as a construction material. This study is to investigate the pore characteristics of alkali-activated slag-red mud soil pavement according to the red mud content. The results showed that the porosity of alkali-activated slag-red mud soil pavement increased but the compressive strength of that decreased as the red mud content increased.

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Development of Multi-Components Model of Cement Hydration

  • ;이한승;경제운;박기봉
    • 시멘트 심포지엄
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    • 통권34호
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    • pp.129-137
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    • 2007
  • This paper presents a numerical model which can predict degree of cement mineral component, such as $C_3S$, $C_2S$, $C_3A$, $C_4AF$ and microstructure of hydrating cement as a function of water to cement ratio, cement particle size distribution, cement mineral components and temperature. In this model cement particles are parked randomly in cell space and hydration process is described using a multi-component intergrated kinetic model. The simulation result of degree of hydration of cement mineral component agrees well with experiment result. The content of cement hydration product, such as CSH and CH can be obtained as an accompanied result during hydration process. By introducing of equal-area projection method, water withdrawl mechanism and contact area among cement particles can be considered in detail. By using proposed method, pore size distribution of hydrating cement is predicted.

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