• Title/Summary/Keyword: Pore Development

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Thaw consolidation behavior of frozen soft clay with calcium chloride

  • Wang, Songhe;Wang, Qinze;Xu, Jian;Ding, Jiulong;Qi, Jilin;Yang, Yugui;Liu, Fengyin
    • Geomechanics and Engineering
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    • v.18 no.2
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    • pp.189-203
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    • 2019
  • Brine leakage is a common phenomenon during construction facilitated by artificial freezing technique, threatening the stability of frozen wall due to the continual thawing of already frozen domain. This paper takes the frequently encountered soft clay in Wujiang District as the study object, and remolded specimens were prepared by mixing calcium chloride solutions at five levels of concentration. Both the deformation and pore water pressure of frozen specimens during thawing were investigated by two-stage loading tests. Three sections were noted from the changes in the strain rate of specimens during thawing at the first-stage load, i.e., instantaneous, attenuated, and quasi-stable sections. During the second-stage loading, the deformation of post-thawed soils is closely correlated with the dissipation of pore water pressure. Two characteristic indexes were obtained including thaw-settlement coefficient and critical water content. The critical water content increases positively with salt content. The higher water content of soil leads to a larger thaw-settlement coefficient, especially at higher salt contents, based on which an empirical equation was proposed and verified. The normalized pore water pressure during thawing was found to dissipate slower at higher salt contents, with a longer duration to stabilize. Three physical indexes were experimentally determined such as freezing point, heat conductivity and water permeability. The freezing point decreases at higher salt contents, especially as more water is involved, like the changes in heat conductivity. The water permeability maintains within the same order at the considered range of salt contents, like the development of the coefficient of consolidation. The variation of the pore volume distribution also accounts for this.

Performance of a Chimney Drain in Reinforced Earth Wall for Reduction of Pore Water Pressure During Rainfall - a Numerical Investigation (보강토 옹벽에 적용되는 연직 배수시스템의 강우시 수압 저감 효과 - 수치해석 연구)

  • Yoo, Chung-Sik;Kim, Sun-Bin;Jung, Hyuk-Sang
    • Journal of the Korean Geotechnical Society
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    • v.24 no.5
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    • pp.99-106
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    • 2008
  • This study is concernsed with the effect of a chimney drainage system installed at the back of reinforced soil block on preventing the pore water pressure development. A series of finite-element analyses based on transient seepage analysis were performed for a number of cases with different patterns of the chimney drainage system. The results were thoroughly analyzed to get insight into the mechanism of pore water pressure reduction effect of the chimney drainage system. It is shown that a vertical drainage system installed at the back of reinforced zone can be an effective means of maintaining the wall stability during rainfall by preventing pore pressure increase in the reinforced as well as the backfill zones. Also shown is that the optimum height of the chimney drain is 50% of the wall height. Practical implications of the findings were discussed.

The development of encoded porous silicon nanoparticles and application to forensic purpose (코드화 다공성 실리콘 나노입자의 개발 및 법과학적 응용)

  • Shin, Yeo-Ool;Kang, Sanghyuk;Lee, Joonbae;Paeng, Ki-Jung
    • Analytical Science and Technology
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    • v.22 no.3
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    • pp.247-253
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    • 2009
  • Porous silicon films are electrochemically etched from crystalline silicon wafers in an aqueous solution of hydrofluoric acid(HF). Careful control of etching conditions (current density, etch time, HF concentration) provides films with precise, reproducible physical parameters (morphology, porosity and thickness). The etched pattern could be varied due to (1) current density controls pore size (2) etching time determines depth and (3) complex layered structures can be made using different current profiles (square wave, triangle, sinusoidal etc.). The optical interference spectrum from Fabry-Perot layer has been used for forensic applications, where changes in the optical reflectivity spectrum confirm the identity. We will explore a method of identifying the specific pattern code and can be used for identities of individual code with porous silicon based encoded nanosized smart particles.

Suppression of brown blotch disease by tolaasin inhibitory factors (톨라신 저해 물질을 이용한 갈반병의 억제)

  • Yun, Yeong-Bae;Kim, Min-Hee;Han, Ji-Hye;Kim, Young-Kee
    • Journal of Applied Biological Chemistry
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    • v.60 no.2
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    • pp.179-184
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    • 2017
  • Tolaasin, a 1.9 kDa peptide toxin, is produced by Pseudomonas tolaasii and causes the brown blotch disease of cultivated oyster mushroom. It forms pores on the membrane and thus destroys cellular membrane structure, seriously reducing the productivity of mushroom cultivation. The mechanism of tolaasin-induced cytotoxicity is not known in detail. However, it has been reported to form a pore structure in the cytoplasmic membrane through the molecular multimerization. Therefore, food additives which can interact with tolaasin molecules may inhibit the pore formation by hydrophobic interactions with tolaasin molecules. In this study, various food additive materials have been identified as inhibitors of the tolaasin activity and named tolaasin-inhibitory factors (TIF). Most of TIFs are emulsifying agents for food processing procedures. Among various TIFs, polyglycerol and sucrose esters of fatty acids blocked effectively the cytotoxicity of tolaasins at the concentrations $10^{-4}-10^{-5}M$. These TIFs also successfully suppressed the blotch disease development in the shelf cultivation of oyster mushroom.

Rainfall induced instability of mechanically stabilized earth embankments

  • Roy, Debasis;Chiranjeevi, K.;Singh, Raghvendra;Baidya, Dilip K.
    • Geomechanics and Engineering
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    • v.1 no.3
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    • pp.193-204
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    • 2009
  • A 10.4-m high highway embankment retained behind mechanically stabilized earth (MSE) walls is under construction in the northeastern part of the Indian state of Bihar. The structure is constructed with compacted, micaceous, grey, silty sand, reinforced with polyester (PET) geogrids, and faced with reinforced cement concrete fascia panels. The connections between the fascia panels and the geogrids failed on several occasions during the monsoon seasons of 2007 and 2008 following episodes of heavy rainfall, when the embankment was still under construction. However, during these incidents the MSE embankment itself remained by and large stable and the collateral damages were minimal. The observational data during these incidents presented an opportunity to develop and calibrate a simple procedure for estimating rainfall induced pore water pressure development within MSE embankments constructed with backfill materials that do not allow unimpeded seepage. A simple analytical finite element model was developed for the purpose. The modeling results were found to agree with the observational and meteorological records from the site. These results also indicated that the threshold rainwater infiltration flux needed for the development of pore water pressure within an MSE embankment is a monotonically increasing function of the hydraulic conductivity of backfill. Specifically for the MSE embankment upon which this study is based, the analytical results indicated that the instabilities could have been avoided by having in place a chimney drain immediately behind the fascia panels.

3D porous ceramic scaffolds prepared by the combination of bone cement reaction and rapid prototyping system

  • Yun, Hui-Suk;Park, Ui-Gyun;Im, Ji-Won
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.56.2-56.2
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    • 2012
  • Clinically-favored materials for bone regeneration are mainly based on bioceramics due to their chemical similarity to the mineral phase of bone. A successful scaffold in bone regeneration should have a 3D interconnected pore structure with the proper biodegradability, biocompatibility, bioactivity, and mechanical property. The pore architecture and mechanical properties mainly dependent on the fabrication process. Bioceramics scaffolds are fabricated by polymer sponge method, freeze drying, and melt molding process in general. However, these typical processes have some shortcomings in both the structure and interconnectivity of pores and in controlling the mechanical stability. To overcome this limitation, the rapid prototyping (RP) technique have newly proposed. Researchers have suggested RP system in fabricating bioceramics scaffolds for bone tissue regeneration using selective laser sintering, powder printing with an organic binder to form green bodies prior to sintering. Meanwhile, sintering process in high temperature leads to bad cost performance, unexpected crystallization, unstable mechanical property, and low bio-functional performance. The development of RP process without high thermal treatment is especially important to enhance biofunctional performance of scaffold. The purpose of this study is development of new process to fabricate ceramic scaffold at room temperature. The structural properties of the scaffolds were analyzed by XRD, FE-SEM and TEM studies. The biological performance of the scaffolds was also evaluated by monitoring the cellular activity.

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Development of High Performance MEA by Decal Method for PEM Fuel Cell (데칼 공정을 적용한 고성능 MEA 개발)

  • Lee, Ki-Sub;Lee, Jae-Seung;Kwon, Nak-Hyun;Hwang, In-Chul
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.5
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    • pp.585-591
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    • 2011
  • This study has focused on the development of high performance membrane-electrode assemblies (MEAs) fabricated by decal method for proton exchange membrane fuel cell (PEMFC). To study the effect of ionomer contents on performance, we fabricated MEAs with several electrodes which were prepared by varying the quantity of ionomer from 20 wt.% to 45 wt.% in catalyst layer. The MEA performance was obtained through single cell test. The MEA prepared from electrode with 25wt.% of ionomer showed the best performance. We evaluated the surface area and pore volume of electrode with BET. We found that the surface area and pore volume in electrode decreased rapidly at the electrode with 40wt.% of ionomer in catalyst layer. MEA was fabricated by roll laminator machine and the roll laminating conditions for the preparation of MEA, such as laminating press, temperature and speed, were optimized. The MEA performance is not affected by laminating temperature and speed, but roll laminating press have a great effect on MEA performance.

The Study on permeability enhancement in smear zone using electro-osmotic pressure (전기 삼투압을 이용한 교란영역의 투수성 개선에 관한 연구)

  • Ahn, Byung-Wook;Noh, Hee-Jeon;Kim, Hyun-Ki;Cho, Nam-Jun
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.435-441
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    • 2008
  • More time is required for consolidating soft clay when its hydraulic conductivity around the vertical drains is reduced by soil disturbance. One of the methods to be proposed to solve such problem is the electro-osmotic flow application. This study presents the experimental results of model tests using a modified oedometer and a large-scale cylinder with a sand drain. Results show that the development of negative excessive pore water pressure due to the DC electrical field in saturated clay can be transformed to additional loads causing more consolidation settlement.

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Strength Properties and Pore Structure of Epoxy-Modified Mortars under Steam and Steam/Heat Combined Curing (증기 및 가열 조합양생에 의한 에폭시수지 혼입 모르타르의 강도 및 세공구조)

  • Lee, Jae-Hwa;Kim, Wan-Ki
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.107-108
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    • 2011
  • The purpose of present study is to examine the application of effective curing to hardener-free epoxy-modified mortars. The epoxy-modified mortars are prepared with polymer-cement ratios, subjected to two types of curing conditions, and tested for compressive, flexural and tensile strengths. As a result, hardener-free epoxy-modified mortars with steam curing is markedly improved with increasing air-dry curing period. High strength development of the epoxy-modified mortars may be achieved by the dense microstructure by cement and the hardener of the epoxy resin in the mortars.

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Effect of Foulant Characteristics on Membrane Fouling Index (오염물질의 특성이 막오염 지수에 미치는 영향)

  • Park, Chanhyuk;Kim, Hana;Hong, Seungkwan
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.6
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    • pp.775-780
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    • 2005
  • This study was performed to investigate the effect of foulant characteristics on Membrane fouling index such as Silt Density Index (SDI) and Modified Fouling Index (MFI). A linear relationship was found relating the fouling index (both SDI and MFI) on particle concentration, but fouling index values were nonlinearly (exponentially) with increasing organic concentration. When organic matter was the primary cause of fouling, the MFI was not accurately predicted due to internal fouling such as pore adsorption. The fouling index was determined mainly by particle characteristics when both particle and organic coexisted in the feed water. This observation was attributed to lessening of organic pore adsorption by particle cake layer formed on the membrane surface. Bench-scale actual fouling experiments demonstrated that permeate flux declines much faster with feed water containing particles than organic matters although fouling potential predicted by SDI values were identical, indicating that the accurate prediction of fouling potential requires the development of fouling index reflecting different foulant characteristics.