• Title/Summary/Keyword: Polyvinyl alcohol

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Research about Chemical-Biological Protection Capability of Selectively Permeable Membrane Materials Based on Polyvinyl Alcohol (폴리비닐알코올 기반 선택투과막 재료의 화생방호성능 연구)

  • Kang, Jae-Sung;Seo, Hyeon-Kwan;Kwon, Tae-Geun;Park, Hyen-Bae;Lee, Hae-Wan
    • Membrane Journal
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    • v.23 no.3
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    • pp.237-244
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    • 2013
  • We fabricated several composite membranes with selectively permeable performance designed to facilitate water vapor transport and resist DMMP vapor permeation. Materials for selective permeable membrane were based on polyvinyl alcohol and functional polymer containing basic functional group. With these materials, we characterized selectively permeable performance to identify next-generation material with chemical-biological protective capability. Results showed that polyvinyl alcohol (PVA)/polyethyleneimine (PEI) materials possessed performance with superior water vapor permeation ($2,200{\sim}2,900g/m^2/day$) and protective capability against DMMP vapor ($47g/m^2/day$).

Preparation and Characterization of Cellulose Nanofibril/Polyvinyl Alcohol Composite Nanofibers by Electrospinning

  • Park, Byung-Dae;Um, In Chul;Lee, Sun-Young;Dufresne, Alain
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.2
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    • pp.119-129
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    • 2014
  • This work undertook to prepare nanofibers of cellulose nanofibrils (CNF)/polyvinyl alcohol (PVA) composite by electrospinning, and characterize the electrospun composite nanofibers. Different contents of CNFs isolated from hardwood bleached kraft pulp (HW-BKP) by 2,2,6,6-tetramethylpiperidine-1-oxy radical (TEMPO)-mediated oxidation were suspended in aqueous polyvinyl alcohol (PVA) solution, and then electrospun into CNF/PVA composite nanofibers. The morphology and dimension of CNFs were characterized by transmission electron microscopy (TEM), which revealed that CNFs were fibrillated form with the diameter of about $7.07{\pm}0.99$ nm. Morphology of the electrospun nanofiber observed by field-emission scanning electron microscopy (FE-SEM) showed that uniform CNF/PVA composite nanofibers were manufactured at 1~3% CNF contents while many beads were observed at 5% CNF level. Both the viscosity of CNF/PVA solution and diameter of the electrospun nanofiber decreased with an increase in CNF content. The diameter and its distribution of the electrospun nanofibers helped explain the differences observed in their morphology. These results show that the electrospinning method was successful in preparing uniform CNF/PVA nanofibers, indicating a great potential for manufacturing consistent and reliable cellulose-based nanofibrils for scaffolds in future applications.

Immobilization of Alchidine on Polyvinyl Alcohol Gels

  • Soh, Dea-wha
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.1
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    • pp.11-14
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    • 2003
  • The regularities of immobilization of natural medicinal substances - alchidine on gels of poly(vinyl alcohol) - are investigated. It is shown that the polymer components of alchidine interact with nonionic polymer with formation of interpolymer complexes. The influence of the different factors on the properties of complexes is considered and the constants of alchidine distribution in the system gel - water are calculated.

Removal of NH(sub)3-N by Using Immobilized Nitrifier Consortium in PVA[Polyvinyl Alcohol]-I. Effect of Packing Fraction and Aeration Rate on Ammonia Nitrogen Removal (PVA에 고정화된 질화세균군에 의한 암모니아성 질소 제거 I. 충진율 및 공기 유입량이 암모니아성 질소제거에 미치는 영향)

  • 서근학;김병진;오창섭
    • KSBB Journal
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    • v.16 no.3
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    • pp.314-319
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    • 2001
  • A nitrifier consortium immobilized in polyvinyl alcohol was used to remove ammonia nitrogen from synthetic wastewater in an airlift bioreactor. The minimum aeration rates were 0.4, 0.6, 0.8 and 1.0 vvm for 5, 10, 15 and 20% immobilized bead packing volume fraction, respectively. The efficient packing fraction and the aeration rate for ammonia nitrogen removal were 15% and 2.4 vvm, respectively. With a hydraulic retention time of 0.5hr, the removal rate and the efficiency of ammonia nitrogen removal were 1685 g/㎥$.$day and 48% at an influent ammonia nitrogen concentration of 75 g/㎥.

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Removal of #NH_3-N$ by using Immobilized Nitrifier Consortium in Polyvinyl Alcohol (PVA에 고정화된 질화세균에 의한 암모니아성 질소제거)

  • 서근학;김용하;조진구;김병진;서재관;박은주;김성구
    • Journal of Environmental Science International
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    • v.8 no.4
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    • pp.479-483
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    • 1999
  • Nitrifier consortium immobilized in polyvinyl alcohol was used for the removal of ammonia nitrogen from synthetic aquaculture water in the airlift bioreactor. At the aeration rate fo 0.15 vvm and bead packing volume fraction of 20%, airlift bioreactor was operated effectively for a removal of ammonia nitrogen and for a stability of operation. Ammonia nitrogen removal rate by airlift bioreactor was continuously increased with decreasing hydraulic residence time. At the HRT(hydraulic residence time) of 0.3 hour, ammonia nitrogen removal rate was 84.3 g/$m^3$.d and the highest ammonia nitrogen removal rate was 130.8 g/$m^3$.d when HRT was 0.1 hour.

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Silastic Molding Method for Pectus Excavatum Correction Using a Polyvinyl Alcohol (Ivalon) Sponge

  • Lee, Jun-Ho;Kim, Sung-Jin;Kang, Jeong-Ho;Chung, Won-Sang;Kim, Hyuck;Chon, Soon-Ho
    • Journal of Chest Surgery
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    • v.45 no.6
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    • pp.418-420
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    • 2012
  • Pectus excavatum is rare, but it is the most common type of sternal congenital disorder. There are many surgical methods to correct pectus excavatum such as the Ravitch method, Wada method, Silastic mold method, and the Nuss operation. We report a case of minimal invasive surgery for pectus excavatum using a polyvinyl alcohol sponge.

Preparation of Nitrifier Immobilized PVA(Polyvinyl Alcohol) Bead and Removal of Ammonia Nitrogen (질화세균군이 고정화된 PVP(Polyvinyl Alcohol) bead 제조 및 암모니아성 질소 제거)

  • 서근학;조진구
    • Journal of Environmental Science International
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    • v.10 no.3
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    • pp.233-237
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    • 2001
  • Immobilized nitrifier bead in airlift bioreactor were used to remove high levels of ammonia nitrogen from synthetic wastewater. Polyvinylalcohol(PVA) bead for immmobilization of nitrifier consortium were prepared by PVA-boric acid method by varying concentration of PVA and nitrifier consortium. By determining viscosity, sphercity and tailing, the characteristics of prepared beads were investigated and the continous immobilization process was developed. Synthetic wastewater containg 25g/$\textrm{m}^3$ of ammonia nitrogen could be treated within 0.5 hour and the highest removal rate of ammonia nitrogen was 934.2g/$\textrm{m}^3{\cdot}$ day.

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Dyeing of Polyvinyl Alcohol Fibers in Filament Yarn Form with Reactive and Vat Dyes

  • Rashad, Mahmood;Kim, Sam-Soo;Huh, Man-Woo;Yoon, Nam-Sik
    • Textile Coloration and Finishing
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    • v.19 no.5
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    • pp.17-23
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    • 2007
  • As polyvinyl alcohol(PVA) filament yarn is commercially used in many fields due to its high strength and modulus properties. This research was carried out to study the dyeing behavior of PVA and to find out appropriate dye for better dyeing. As the dyeing behavior of PVA fiber is similar to cellulose due to the same functional group, reactive and vat dyes were selected for the dyeing. Color strength of PVA fibers treated with vat dyes was found to be better than those with reactive dyes, because of the low fixation of reactive dye on fibers. Most of the reactive dye may became hydrolyzed, and flushed away with water in washing. Colorfastness to laundering was shown to be very high for both of the reactive-dyed and vat-dyed PVA fibers.

A Study on the Thermal Stability of Polymer Mixtures using Air Bags (에어백용 고분자 혼합물의 열안정성에 관한 연구)

  • Oh, Yang-Hwan;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.4
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    • pp.353-357
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    • 2003
  • Sodium azide (SA) is commonly used as propellant for inflating automatic safety bags and other chemical manufacturing purposes. The investigation of potentially thermal hazard of sodium azide and its mixture with polymers are very important because it can occur an expected traffic accident so we took a experiment s using different scanning calorimeter (DSC) in nitrogen atmosphere. The decomposition temperature were about $350{\sim}450^{\circ}C$. We could find not only exothermic reaction was remarkably decreased in mixture s of acrylonitrile-butadiene-styrene (ABS) and polyvinyl chloride (PVC), but also increasing mixed rate of ABS, polyvinyl alcohol (PVA) and polymethyl methacrylate (PMMA) decreased thermal decomposition heat.

Evaluation Physical Characteristics of Coating Materials for Forage Seed Coating by Coating Index (피복지수에 의한 목초종자 피복제의 물리적 특성 평가)

  • 이성운;허삼남;김택림
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.24 no.2
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    • pp.155-162
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    • 2004
  • Different adhesives(CF-clear, arabic gum, cethylmethyl cellulose, polyvinyl alcohol, polyvinyl pyrrolidone, hydroxy propyl cellulose, methyl cellulose) and particulate matters(bentonite, kaolin, calcium carbonate, peatmoss, talcum, vermiculite, zeolite, calcium hydroxide, plaster, calcium phosphate, vermiculite + calcium carbonate, vermiculite + kaolin, vermiculite + talcum) were evaluated by coating index method. According to the weight of single coated seeds, CF-clear and polyvinyl alcohol appeared to be the best coating adhesives for red clover and tall fescue seeds. Both vermiculite and vermiculite + talc(l : 1) for red clover, and vermiculite + talc(l : 1) for tall fescue appeared to be the best particulate matter(P < 0.01). Percent friability showed excellent results for the arabic gum, CF-clear, and polyvinyl alcohol when compared to others(p < 0.01). The coating index showed high with vermiculite and vermiculite + talc(l : 1) in coating red clover seed, and talc, vermiculite, and vermiculite + talc showed good coating index in coating tall fescue seed.