• Title/Summary/Keyword: Polyvinyl Chloride

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Reactive modification of PVC membranes for the improved performance

  • Jhaveri, Jainesh H.;Patel, Chetan M.;Murthy, Z.V.P.
    • Membrane and Water Treatment
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    • v.9 no.6
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    • pp.385-392
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    • 2018
  • Poly vinyl chloride (PVC) was chemically modified, and used for ultrafiltration to analyze the performance. Non-solvent induced phase separation (NIPS) method was used to prepare membranes. The neat PVC membrane was casted and used as a control membrane. Modified membrane was prepared by reacting PVC with ethanolamine (EA) in the casting solution (labeled as CM-PVC). Pure water permeability (PWP) was evaluated by measuring pure water flux. Humic acid was used as model foulant solute to analyze flux and rejection ability of membranes. Flux and rejection data of neat and modified membranes were compared to prove the improvement in the filtration performance. The experimental results showed that for PVC and CM-PVC, PWP was calculated to be ~64 and ${\sim}143L/m^2{\cdot}h$, respectively, and the rejection of humic acid was found to be 98% and 100%, respectively. TGA was carried out to analyze the effect of chemical modification on the thermal stability of polymer. FT-IR analysis was another characterization technique used for the comparative study.

A Yew Technique for Infrared Spectroscopy using Polyethylene Film Cell (Polyethylene Film을 利用한 赤外線分光分析用 Cell)

  • Sung, Chwa-Kyung;Noh, Ick-Sam
    • Journal of the Korean Chemical Society
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    • v.7 no.1
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    • pp.58-64
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    • 1963
  • Authors propose a new technique using polyethylene film instead of sodium chloride window as a cell material. Nujol mulls, liquids and aqueous solutions are sandwitched between two pieces of polyethylene film which are held between cardboards. Ordinary lead or stainless steel spacers could be used if exact cell thickness is desired. A more elaborate cell can be assembled by injecting samples between two pieces of polyethylene film which are placed between sodium chloride windows of ordinary demountable liquid cell. The absorption bands due to polyethylene and Nujol are compensated by placing the polyethylene film of suitable thickness in the reference beam. The absorption bands due to solvents such as water can also be compensated by the polyethylene film cell sandwitched solvent of suitable thickness in the reference beam. This method would be a simple new technique. Especially this technique may offer a new helpful way for the investigation of the state of substances in aqueous system. Using this technique, authors have observed the appearance of an absorption bands at 3.2 micron, in the spectrum of phenol in aqueous solution, that is absent in the spectrum of phenol in benzene solution. The same absorption band also has been observed in the spectra of aqueous formaldehyde solution and aqueous polyvinyl alcohol solution, where the absorption bands due to polyethylene and water are compensated. Although it may be regarded that this absorption band is related to the intermolecular interaction between water and the solute having OH group, that is hydrogen bonding. The exact assignment of this absorption band is out of this work.

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Plasticized Poly(Vinyl Chloride)-Acetyl Tributyl Citrate Gels Based Triboelectric Nanogenerator (아세틸 트라이뷰틸 구연산 가소제를 이용한 PVC 겔 기반 마찰전기 나노발전기 개발 )

  • Dohye Park;Hyosik Park;Ju-Hyuck Lee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.1
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    • pp.93-97
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    • 2023
  • A triboelectric nanogenerator (TENG) is a device that converts mechanical energy into electrical energy, and has been considered as a substitute for continuous power supply due to its high performance, simple structure and eco-friendliness. Recently, it is important to develop a TENG using a non-toxic material in order to use it as a power source for wearable, attachable, and body-embeddable electronics. Here, we developed a human friendly TENG using polyvinyl chloride (PVC) gel containing acetyl tributyl citrate (ATBC), a non-toxic plasticizer. PVC gels were fabricated using various ratios of PVC and ATBC, and optimized by investigating dielectric properties, surface potential, output performance, and durability. The PVC gel based TENG generates output signals of 73 V and 4.3 μA, i.e., a 5-fold enhancement in the output power compared to pristine PVC-based TENG. In addition, the PVC gel can be stretched over 500% of strain. This study is expected to be helpful in the future development of non-toxic wearable TENG.

Study on the Synchronous Recycling of EAF Dust and Waste PVC (폐PVC와 전기로 제강분진의 동시재활용을 위한 기초연구)

  • Lee GyeSeung;Song YuungJun
    • Resources Recycling
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    • v.12 no.6
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    • pp.47-56
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    • 2003
  • PVC(polyvinyl chloride) powder were mixed with EAF(Electric Arc Furnace) dust and made as pellets. In order to recover the hydrochloride emitted from pyrolysis of PVC and the valuable metals in dust through making chlorides, pellets were roasted at $300 ^{\circ}C$ and investigated about the generation of chlorides. Two dust samples were collected at I steel making Co. and P Co. (called I dust and P dust respectively), which were mainly composed of zincite and franklinite. It was confirmed that about 50% of Zn in I dust and 48% of Zn in P dust compose zincite. The emission of HCl gas was completed in 15 min at 30$0^{\circ}C$ and the HCl mostly reacted with dust and made chlorides under 20% PVC mixed ratio. Because the reaction of HCl with zincite was faster than with franklinit, when generation and volatilization of ferric chloride is not allowed, the equivalent PVC powder mixed ratio in pellet depended on the amount of zincite in dust.

Recovery of Rare Earth Elements from Nd Magnet Scrap Using PVC (PVC에 의한 네오디뮴 자석 스크랩으로부터 희토류 회수)

  • Lee, So-Yeong;Park, Sung-Hun;Son, Injoon;Sohn, Ho-Sang
    • Resources Recycling
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    • v.27 no.1
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    • pp.38-44
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    • 2018
  • A large amount of Nd-Fe-B magnet scraps are generated during magnet manufacture process. In this study, selective chlorination of the rare earth elements by hydrogen chloride gas which obtained from the pyrolysis of polyvinyl chloride (PVC) was investigated. In thermogravimetric analysis, drastic weight loss was occurred at about 500 K and 710 K. At the isothermal experiments, the weight loss reaches about 30% above 673 K. XRD patterns characterized that after each experiments, ${\alpha}$-Fe, Nd oxychloride, Nd chloride, and Fe chlorides were formed, and the leaching residues remain only ${\alpha}$-Fe. The yields of Nd, Dy, and Fe for the isothermal experiment were increased with temperature and peaked at 873 K. As PVC ratio increased, the yields of Nd, Dy and Fe were also increased.

Discriminant Analysis of Marketed Liquor by a Multi-channel Taste Evaluation System

  • Kim, Nam-Soo
    • Food Science and Biotechnology
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    • v.14 no.4
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    • pp.554-557
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    • 2005
  • As a device for taste sensation, an 8-channel taste evaluation system was prepared and applied for discriminant analysis of marketed liquor. The biomimetic polymer membranes for the system were prepared through a casting procedure by employing polyvinyl chloride, bis (2-ethylhexyl)sebacate as plasticizer and electroactive materials such as valinomycin in the ratio of 33:66:1, and were separately attached over the sensitive area of ion-selective electrodes to construct the corresponding taste sensor array. The sensor array in conjunction with a double junction reference electrode was connected to a high-input impedance amplifier and the amplified sensor signals were interfaced to a personal computer via an A/D converter. When the signal data from the sensor array for 3 groups of marketed liquor like Maesilju, Soju and beer were analyzed by principal component analysis after normalization, it was observed that the 1st, 2nd and 3rd principal component were responsible for most of the total data variance, and the analyzed liquor samples were discriminated well in 2 dimensional principal component planes composed of the 1st-2nd and the 1st-3rd principal component.

Development of new materials for Point of Purchase Banner (신소재 고객유도 상품 개발)

  • Ha, Yan;Kim, Eun-Hee
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2012.05a
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    • pp.905-906
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    • 2012
  • In this paper, we develope new goods for helping of increasing income that tube arched POP by using PVC papers to PET plating films. General market is supported with high quality POP by using specified goods and increased value of goods. Also, it is easily developed with new material with re-combination of existing materials. The purpose of this paper is that good design and materials of POP spreads widely not only big markets but also small shops.

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Study on the laser transmission-welding of thermoplastics (열가소성 플라스틱의 레이저 투과 접합에 환한 연구)

  • Seo Myung-hee;Ryu Kwang-hyun;Nam Gi-jung
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.9 s.174
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    • pp.34-40
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    • 2005
  • Laser welding of thermoplastics is a new jointing technique with a host of advantages. It is not only another extremely useful welding method but also a cost-effective alternative to traditional techniques involving screws or adhesives. Transmission laser-welding of thermoplastics such as polycarbonate(PC), polypropylene(PP), polyvinyl chloride(PVC), low density polyethylene(LDPE) and acrylic using a high power diode laser has been studied experimentally. The optical transmission of each plastic has been measured at laser wavelength of 808nm. The weld process has been characterized by the specific energy and weld time required for each plastic. The characteristics of laser welding between same plastics have also been analyzed.

Study on the Characteristics Analysis of Series Arcing at the PVC Insulation Wire for Low Voltage (저압용 비닐절연전선에서의 직렬 아크 특성 분석)

  • Kim, Hyang-Kon;Kim, Dong-Ook;Kim, Dong-Woo;Lee, Ki-Yeon;Choi, Chung-Seog
    • Proceedings of the KIEE Conference
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    • 2006.05a
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    • pp.57-59
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    • 2006
  • In this study, we experimented a deterioration characteristics by series arcing with 600V polyvinyl chloride insulation wire and analyzed the glowing/growing process of copper oxide, waveforms of contact voltage, current, power dissipation and carbonized patterns of insulation. We know that how glowing contacts and surface arcing can decompose PVC insulation and that it is possible for the subsequent series arc to ignite, and burn insulation. We expect that these results are useful for advancing the state-of-the-art in fire protection by Providing a better understanding of how electrical fires can initiate.

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Isolation and Characterization of Biofouling Bacteria in Ultra-high Purity Water Used in the Semiconductor Manufacturing Process

  • Kim, In-Seop;Lee, Kye-Joon
    • Journal of Microbiology and Biotechnology
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    • v.10 no.4
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    • pp.554-558
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    • 2000
  • Bacteria were isolated and identified from an advanced high-purity water system that supplies ultra-high purity water (UHPW) for 16-megabyte DRAM semiconductor manufacturing. Scanning electron microscopic and microbiological observations revealed that the primary source of the bacteria isolated from the UHPW was detached cells from biofilms developed on the pipe wall through which the UHPW, a man-made and extremely nutrient poor environment, was passing. About 63-65% of the bacteria isolated from the UHPW and the pipe wall were Gram-positive, whereas only 10% of the bacteria isolated from the feed water were Gram-positive. The of Gram-positive bacteria and seven genera of Gram-negative bacteria. Strains of the UHPW bacteria effectively adhered to and formed a biofilm on the surface of polyvinyl chloride (PVC) pipe.

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