• Journal of the Korean Society of Safety
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• v.18 no.3
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• pp.81-87
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• 2003

Latex polymers are widely used for adhesive, binder, paint etc. Especially the PVAc(Polyvinyl acetate) latex which manufactured by vinyl acetate and vinyl alcohol as protective colloid is a useful environmentally friendly adhesive. To increase useful property of PVAc latex, this study was carried out for checking thermal characteristics and physical condition of PVAc latex by DSC, FT-IR, Pyrolyzer GC-MS. The activation energies of thermal decomposition for 40, 48, 56, 64% solid content of PVAc latex were found as 28.1-36.0kcal/mol by Kissinger's method and 17.2-22.0kcal/mol by DSC method. Actually, reasonable solid content could be consiered as 56% because of activation energy and adhesive characteristics. According to the effect of protective colloid for 4, 10, 15, 20wt%, the activation energy shows same tendency to both method and in case of l5wt% has been found as the highest activation energy. The mechanism of thermal decomposition was mainly estimated by main chain scission, not by side group on FT-IR analysis. Main component of Pyrolzer GC-MS result were consisted of $CH_3COOH$, $CH_3$, $H_2O$ and light gases(CO, $CO_2$, $CH_4$ etc).

• Geomechanics and Engineering
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• v.23 no.2
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• pp.179-187
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• 2020

Freezing-thawing cycles have significant effect on soils engineering behavior in frozen areas. This effect is more considerable in fine-graded than coarse-grained soils. The objective of this study is improving soil durability and strength in continues freezing-thawing cycles. For getting this purpose mixture of Polyvinyl Acetate (PVAc) and Ethylene Glycol Monobutyl Ether (EGBE) has been added to fine-grained soil and final prepared samples were tested at different freezing-thawing cycles. PVAc was mixed with 1%, 2% and 3% of soil weight. Half of PVAc weight was used as weight of EGBE. Freezing-Thawing cycles were exposed to samples and they were tested at different cycles. Results showed that adding mixture of PVAc+EGBE improved strength and durability of samples up to 10 freezing-thawing cycles. Unconfined compress strength tests were applied to samples and stress and strain of samples were tested on failure time. Behavior of samples was different at different percentages of mixture. Results showed that increasing amount of PVAc from 1% to 2% had more considerable effect on final stress than 2% to 3%. Using higher percentages of PVAc + EGBE mixture leaded to that samples carried more strain before collapsing. Another result gained from tests was that, freezing-thawing effect was more considerable after fourth cycles. It means differences between first and fourth cycles were more considerable than differences between fourth and tenth.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.32 no.5A
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• pp.299-305
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• 2012

The objective of this paper is to obtain the basic data in order to develop an eco-friendly concrete through evaluation on the properties of polymer cement mortar and concrete using PVAc (Polyvinyl Acetate), as a kind of water-soluble polymer. For this purpose, the physical properties of cement mortar and concrete which does not contain the PVAc as the control batch were compared and analyzed with those using the PVAc. And then, the replacement amount of the PVAc was 3%, 6%, 9% and 12% by binder, respectively. And also, the properties of concrete using the PVAc were evaluated, by adding an antifoaming agent in order to control the air contents increasing with an increase of amount of polymer usage. As a result, in the case of polymer cement mortar using the PVAc, it presented that the compressive strength reduced, while the performance of flexural strength and drying shrinkage increased. When the replacement of the PVAc was 6% within concrete, the compressive, tensile, flexural strength and elastic modulus were increased.

• Journal of the Korea institute for structural maintenance and inspection
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• v.16 no.4
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• pp.18-24
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• 2012

In this study, hybrid method using polyvinyl acetate (PVAc) which has a strong adhesion and flexibility in which acrylic copolymer chemical-reaction reacts with cement, and is eco-friendly, is to improve the watertightness. The hybrid method is applied applied primarily waterproof stuff comprising silicate system and secondary mortar mixed with PVAc on the concrete surface. And then, in order to evaluate the performance, the properties of bond strength and amount of water absorption were measured. Based on the above experiments, mock-up specimens for field application were fabricated, and then the properties were evaluated as laboratory experiments. As the results, specimens cast from hybrid method using PVAc showed the best results on watertightness and bond strength. And also, with respect to experiment of mock-up specimens, the properties were in agreement with laboratory results. Especially, it could know that PVAc has strengthening effect from the results of the compressive strength. Due to outstanding results of carbonation depth and resistance to chloride ion penetration, it may be applied in weak areas such as underground and marine structures.

• Journal of the Korea Furniture Society
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• v.16 no.1
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• pp.1-8
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• 2005

This experiment was carried out to investigate the gluing characteristics of poly vinyl acetate emulsion adhesive(PVAc) on the Cryptomeria japonica laminated boards. This sample trees are major planting species and have been planted in southern district for a long time. The optimum gluing conditions for laminated board were summarized as follows; the amount of spreading glue, assembly time, clamping pressure, and clamping time for PVAc resin were $200g/m^2$, 10min., $5kg/cm^2$, and 6hrs., respectively, and the relative formulae between extension ratio(x) and block shear strength(y) was $y=-9.6x+85.2(R^2=0.95)$.

• Journal of Conservation Science
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• v.32 no.2
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• pp.167-178
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• 2016

Despite the size layer is an important part for conserving the artworks in the configuration of oil painting, the conservation scientific approaches of that have not been made yet. Therefore, this study produced standard samples on the basis of the analysis results of oil painting works, and carried out the evaluation of functions of the size layer materials. As a result of literature material, traditionally, animal glue was used for the size layer, whereas synthetic resin have been used in combination with animal glue since the modern age, in particular, it was identified that Polyvinyl Acetate(PVAc) was in general use. As a result of analysis of oil painting works, size layer was detected on the support and it was identified as animal glue. As a result of analysis based on Funaoka canvas for ground, it showed that the lead oxide and the titanium dioxide were the main constituents. On the basis of these results, standard samples were produced. As a result of evaluation on the functions of the size layer materials, in the case of the animal glue, stable result was observed in the shrinkag expansion rate, whereas slight weakness was observed in moisture proofing, color, and tensile strength, and dense cracks were found on surface. As for PVAc(A), moisture proofing, color, and the tensile strength exhibited stable results. Higher shrinkage rate was observed and the cracks with wide gaps were found on surface. As for PVAc(B), tensile strength, shrinkage expansion rate, and surface observation showed stable results, whereas moisture proofing property showed poor results. Different aspects were observed in each experiment, and this phenomena were considered to be due to the density and the adhesion properties between the hydrophilic and hydrophobic molecules in the size layer materials. The results are expected to be used as materials for the oil painting work conservation henceforth.

• Journal of the Korean Applied Science and Technology
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• v.27 no.2
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• pp.216-221
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• 2010

Polyvinyl acetate (PVAc) prepared by emulsion polymerization has broad applications for additive such as paint binder, adhesive for wood and paper due to its low glass transition temperature which help to plasticize substrate resins. Since emulsion polymerization has a disadvantage that surfactant and ionic initiator degrade properties of the product polymer, poly (vinyl acetate-eo-ethyl acrylate) (VAc-EA) was synthesized using potassium persulfate as catalyst and polyvinylalcohol (PVA) as protective colloid to prevent the degradation. The copolymer latex product was internally plasticized and has enhanced adhesion, water resistance during VAc-EA emulsion polymerization. No coagulation and complete conversion occur with the reactant mixture of 10 mmol/L potassium persulfate, 10 mmol/L poly ( vinyl alcohol) (PVA 17). As the concentrations of PVA increase, the viscosity becomes increase.

• Journal of the Korea Furniture Society
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• v.17 no.2
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• pp.25-34
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• 2006

This experiment was carried out to investigate the high-frequency gluing characteristics of poly vinyl acetate emulsion adhesive(PVAc) on MDF edge-glued boards. The edge-glued boards were glued lengthwise with butt, scarf, or finger joint. The wastes of MDF boards were reused as board materials. The obtained results are summarized as follows; the bending strength of edge-glued MDF increased slightly with the HF heating time, but the economically desirable heating time was 6 minutes. The bending and tensile strength of edge-glued MDF were high with scarf, finger and butt joint, in order. The strength of finger jointed MDF showed 80% of scarf jointed MDF. The effects of location of finger joints on the bending strength of edge-glued MDF were larger than those of the numbers of finger joints. The bending strength of edge-glued MDF with one joint on the middle position showed 40% decrease in comparison with non-jointed MDF.

• Journal of the Korean Wood Science and Technology
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• v.32 no.6
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• pp.57-66
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• 2004

To study the efficient usage of small diameter logs and woods containing defects such as knots, slope of the grain and decay, six types of finger-jointed woods with various finger profiles were made of poplar, pine and oak with different density. We investigated the effect of finger profile on static bending strength performances of finger-jointed woods. The efficiency of bending MOE, MOR and deflection showed the highest value in poplar finger-jointed wood with the lowest density of three species, and the lowest value in oak finger-jointed wood with the highest density of three species. The values markedly decreased with increasing finger pitch for finger-jointed wood glued with polyvinyl acetate (PVAc) resin for all tested species, whereas for the finger-jointed wood glued with resorcinol-phenol formaldehyde (RPF) resin, the influence of finger pitch on the efficiency of MOE was not found in all tested species, and those on the efficiency of MOR and deflection indicated the same trend as finger-jointed wood glued with PVAc resin in the case of pine and oak finger-jointed wood with higher densities. It was found that the values tended to decrease with increasing density of species on the whole and the desirable finger pitches were L (6.8 mm) for poplar, M (4.4 mm) for pine and S (3.5 mm) for oak in a view of economy. For finger-jointed wood glued with PVAc resin, the fitness between a tip and a root width of a pair of fingers δ of 0.5 mm indicated the highest efficiency of MOE for all species. And, the influence of δ on MOR was only found in oak finger-jointed wood glued with RPF resin and the desirable δ value for oak was 0.1 mm. However, it was found that the influence of δ on the strength performance was very small.

• Geomechanics and Engineering
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• v.8 no.3
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• pp.361-375
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• 2015

Constructions over soft and loose soils are one of the most frequent problems in many parts of the world. Cement and cement-lime mixture have been widely used for decades to improve the strength of these soils with the deep soil mixing method. In this study, to investigate the freeze-thaw effect of sand improved by polymers (i.e., styrene-acrylic-copolymer-SACP, polyvinyl acetate-PVAc and xanthan gum) and fly ash, unconfined compression tests were performed on specimens which were exposed to freeze-thaw cycles and on specimens which were not exposed to freeze-thaw cycles. The laboratory test results concluded that the unconfined compressive strength increased with the increase of polymer ratio and curing time, whereas, the changes on unconfined compressive strength with increase of freeze-thaw cycles were insignificant. The overall evaluation of results has revealed that polymers containing fly ash is a good promise and potential as a candidate for deep soil mixing application.