• Macromolecular Research
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• 제16권2호
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• pp.163-168
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• 2008

Polystyrene/gold nanoparticle (PS/AuNP) composite fibers were fabricated using an electrospinning technique. Transmission electron microscopy (TEM) showed that the diameters of the naphthalenethiol-capped gold nanoparticles (prior to incorporation into the PS fibers) ranged from 2 to 5 nm. UV-vis spectroscopy revealed the surface plasmon peaks of the gold nanoparticles centered at approximately 512 nm, indicating that nano-sized Au particles are well-dispersed in solution. This was consistent with the TEM observations. The electrospun nanofibers of PS/AuNP composites were approximately 60-3,000 nm in diameter. The surface morphology of the PS/AuNP composite and the dispersability of the Au nanoparticles inside of PS after electrospinning process were investigated by SEM and TEM. The thermal behavior of the pure PS and PS/AuNP nanocomposites and fibers were examined by DSC.

• Bulletin of the Korean Chemical Society
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• 제30권11호
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• pp.2830-2832
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• 2009

• Bulletin of the Korean Chemical Society
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• 제35권9호
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• pp.2689-2693
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• 2014

The control over microstructure in block copolymer thin films using external electric fields has become an interesting research topic. In this article, the effect of nanoparticle on the microdomain alignments in block copolymer (polystyrene-b-poly(2-vinylpyridine)/nanoparticle (Au) thin films under electric fields has been examined with transmission electron microscopy. The homogeneous dispersion of Au nanoparticles into the block copolymer matrix was achieved by surface modification of nanoparticles with compatible ligands. Compared with the phenomenon seen in the pristine block copolymer thin films, a peculiar alignment behavior was observed in the block copolymer/nanoparticle hybrid thin films under electric fields. In addition, the different pathways observed in the pristine and nanoparticle incorporated block copolymer thin films were also monitored as a function of exposure time. This work can provide the fundamental information for understanding microdomain alignment in block copolymer/nanoparticle thin films under external electric fields.

• 반도체디스플레이기술학회지
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• 제17권3호
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• pp.36-40
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• 2018

We have developed a nonlithographic patterning technique using polystyrene nanoparticles to form nanonet channel structures which is promising for high-performance TFT applications. Nanoparticles assisted patterning (NAP) is a technique to form uniform nano-patterns by applying lift-off and dry etch process. Oxygen plasma treatment was used to control the diameters of nanonet hole size to realize a branch width down to 100 nm. NAP technology can be very promising to fabricate nanonet structure with advantages of lower manufacturing cost and large-area patterning capability.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회A
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• pp.1723-1726
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• 2008

In recent years, there has been a remarkable progress in the development of the fiber optic sensors for the detection of various chemicals. Fiber optic sensors have the advantages of very small size, flexibility and low cost. The fiber optic sensors employing different optical or spectroscopic phenomena have been reported such as bulk absorption, optical reflectance, fluoresces and energy transfer. In this study, the effect of nanoparticle concentration in liquid upon light absorption and scattering was studied using extrinsic fiber optic method. For the evaluation, we used Red (650 nm) and Blue (430 nm) light sources which are coupled through the standard cuvette using optical fiber to detector. The experiments are carried out with Polystyrene latex (400 - 800 nm), and Silicon (35 - 110 nm) nanoparticles suspended in Isopropanol. Differences in light absorption and scattering depending on nanoparticle concentration and type are discussed. This method may be useful to study nanoparticles properties for various application and research.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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• pp.1573-1574
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• 2009

Fullerene/polystyrene nanoparticles having the average size of 300 nm ~ 1 ${\mu}m$ were prepared by emulsion polymerization in aqueous medium. Poly(vinyl pyrrolidone) and potassium persulfate were used as a dispersant and an initiator, respectively. The contents of fullerene in the nanoparticle were controlled to be from 10 to 57 wt% by varying the feed ratio, which was confirmed by IR-spectroscopy, thermogravimetric analyses, and elemental analyses. Dynamic light scattering experiments revealed the particles have a broad size distribution. Further characterizations of the nanoparticles were performed by using SEM and TEM observation. The high content of fullerene in the particles will find applications in photovoltaic and organic semiconducting area.

• Bulletin of the Korean Chemical Society
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• 제24권5호
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• pp.684-686
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• 2003

• Bulletin of the Korean Chemical Society
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• 제33권9호
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• pp.2966-2970
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• 2012

Fullerene/polystyrene ($C_{60}$/PS) nano particle was prepared by using emulsion polymerization. Styrene and fullerene were emulsified in aqueous media in the presence of poly(N-vinyl pyridine) as an emulsion stabilizer, and polymerization was initiated by water soluble radical initiator, potassium persulfate. The obtained nano particles have an average diameter in the range of 400-500 nm. The fullerene contents in the nano particle can be controlled up to 15 wt % by varying the feed ratio, which was confirmed by themogravimetric analysis (TGA) and elemental analysis (EA). The structure and morphologies of the $C_{60}$/PS nano particles were examined by various analytical techniques such as dynamic light scattering (DLS), scanning electron microscope (SEM), transmission electron microscope (TEM), electron diffraction (ED) pattern, X-ray powder diffraction (XRD), and UV spectroscopy. Unlike conventional $C_{60}$/PS particles initiated by organic free radical initiators, in which the fullerene is copolymerized forming a covalent bond with styrene monomer, the prepared $C_{60}$/PS nano particles contain pristine fullerene as secondary particles homogeneously distributed in the polystyrene matrix.

• 공업화학
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• 제22권4호
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• pp.444-446
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• 2011

계면활성제(polyvinylpyrrolidone, PVP)와 개시제(benzoyl peroxide, BPO)를 95% 알코올을 용매 속에 첨가하여 styrene monomer로부터 나노 크기의 균일한 분포 영역을 갖는 polystyrene (PS)을 제조하였다. Emulsion polymerization방법을 사용하였으므로 중합과정에서 PS입도 크기에 많은 변수가 영향을 미칠 수 있다. 본 연구에서는 단량체, 계면활성제 및 개시제 등의 농도 영향은 배제하고 가장 큰 변수들로 고려되는 교반 속도와 초음파 조사시간의 영향을 주로 연구하였다. 초음파 조사시간을 조절한 결과 400 nm의 나노 크기를 갖는 PS 입자를 제조할 수 있었다.

• Macromolecular Research
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• 제15권4호
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• pp.285-290
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• 2007

Ag nanoparticles were distributed onto polystyrene nanoparticle (PS-Ag) beads using two synthetic methodologies. In the first methodology, polystyrene (PS) beads were prepared via emulsion polymerization, with Ag nanoparticles subsequently loaded onto the surface of the PS beads. The polymerization of styrene was radiolytically induced in an ethanol (EtOH)/water medium, generating PS beads. Subsequently, Ag nanoparticles were loaded onto the PS beads via the reduction of Ag ions. The results from the morphological studies, using field emission transmission electron microscopy (FE-TEM), reveal the PS particles were spherical and nanosized, and the average size of the PS spherical particles decreased with increasing volume % of water in the polymerization medium. The size of the PS spherical particles increases with increasing radiation dose for the polymerization. Also, the amount of Ag nanoparticle loading could be increased by increasing the irradiation dose for the reduction of the Ag ions. In the second methodology, the polymerization of styrene and reduction of Ag ions were simultaneously performed by irradiating a solution containing styrene and Ag ions in an EtOH/water medium. Interestingly, the Ag nanoparticles were preferentially homogeneously distributed within the PS particles (not on the surface of the PS particles). Thus, Ag nanoparticles were distributed onto the surface of the PS particles using the first approach, but into the PS clusters of the particles via the second. The antimicrobial efficiency of a cloth coated with the Ag-PS composite nanoparticles was tested against bacteria, such as Staphylococcus aureus and Klebsiella pneumoniase, for 100 water washing cycles.