• Title/Summary/Keyword: Polystyrene Foam

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Morphology and Electrical Conductivity of Polystyrene/Carbon Nanotube Microcellular Foams Polymerized by High Internal Phase Emulsions (고내상 에멀젼 중합법으로 제조한 폴리스티렌/탄소나노튜브 미세기공 발포체의 모폴로지 및 전기 전도도)

  • Noh, Won-Jin;Kang, Myung-Hwan;Lee, Seong-Jae
    • Polymer(Korea)
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    • v.36 no.5
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    • pp.579-585
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    • 2012
  • Polystyrene/carbon nanotube (CNT) microcellular foams were prepared to have electrically conductive properties via high internal phase emulsion polymerization. In this study, we have investigated the effects of surface modification of CNT, surfactant content and dispersion time to improve the stability of emulsion and the electrical conductivity of foam. Acid treatment and a surfactant were used to effectively disperse CNTs in the aqueous phase. In the organic phase, CNTs were used after a surface modification with organic functional groups. The degree of dispersion of CNTs was estimated by the electrical conductivity of resultant microcellular foams. With raw CNTs dispersed with the surfactant in the aqueous phase, substantial conductivity increase was observed but the foams were slightly shrunk. The foams prepared with organically modified CNTs dispersed in the organic phase showed stable cell morphology without shrinkage, but displayed limitation to improve the conductivity.

Evaluation on the Vibration Performance for Void-deck Slab Combined with Deck Plate and Polystyrene Void Foam (데크플레이트와 경량성형재가 결합된 중공슬래브의 진동성능에 대한 실물실험 평가)

  • Cho, Seung-Ho;Roh, Young-Sook
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.3
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    • pp.86-92
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    • 2017
  • The possibility to development of floor vibration problem is larger in case of long span structure under service loads. Therefore, to improve the vibration performance of the floor, increasing of its thickness is a common method. But, increasing of thickness can lead to increase of slab self weight and reduce the effectiveness of the building. For this reason, attention for voided slab which reduces the self-weight is increasing. Hence, voided deck slab combined with deck plate and polystyrene void foam which has buoyancy prevention capacity and much developed construct ability has bee developed. By using the developed voided slab, vibration performance of a mock-up building structure has been investigated in the current study. The results according to analysis showed that they can be implemented in living and bedroom which are considered as 1st grade on the basis of "Residential Evaluation Guidelines for Vibration of Buildings" by the Architectural Institute of Japan.

Reinforced Polymer/Clay Nanocomposite Foams with Open Cell Prepared via High Internal Phase Emulsion Polymerization (고내상 에멀션 중합에 의해 제조된 열린 기공을 갖는 고장도 고분자/점토 나노복합 발포체)

  • Song, In-Hee;Kim, Byung-Chul;Lee, Seong-Jae
    • Polymer(Korea)
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    • v.32 no.2
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    • pp.183-188
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    • 2008
  • Reinforced open cell micro structured foams were prepared by the polymerization of high internal phase emulsions incorporating inorganic thickeners. Organoclays were used as oil phase thickener, and sodium montmorillonite was used as aqueous phase thickener. Rheological properties of emulsions increased as oil phase thickener concentration and agitation speed increased, due to the reduced drop size reflecting both competition between continuous and dispersed phase viscosities and increase of shear force. Drop size variation with thickener concentration could be explained by a dimensional analysis between capillary number and viscosity ratio. Upon the foams polymerized by the emulsions, compression properties, such as crush strength and Young's modulus were measured and compared. Among the microcellular foams, the foam incorporated with an organoclay having reactive group showed outstanding properties. It is speculated that the exfoliated silicate layers inside polystyrene matrix, resulting in nanocomposite foam, are the main reason why this foam has enhanced properties.

Development of Shape refining process of VLM-ST Parts Using Noncontacting Hot Tool (비접촉식 열공구를 이용한 VLM-ST 제품의 미세 형상 가공 공정 개발에 관한 연구)

  • 김효찬;이상호;안동규;양동열
    • Journal of the Korean Society for Precision Engineering
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    • v.21 no.1
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    • pp.149-158
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    • 2004
  • In most RP processes, the inherent stair-stepped surfaces and shrinkage-induced warping of the parts require post processing such as surface finishing. To minimize such defects, VLH-ST, a newly developed RP process, employs a 3.9-mm thick expandable polystyrene (EPS) foam sheet and a hot wire to contour it to have slant linear-interpolated sides. The use of relatively thick sheets for layers, however, limits the process capability of constructing fine details, especially smaller than the layer thickness. This study is focused on the development of a post processing method fo fine details of VLM-ST parts. The post-processing tool was designed to meet all the requirements for the desirable post processing. It adopted a hot wire as a means of melting the EPS foam sheet. Various basic experiments on the post processing were carried out to obtain the optimal process conditions. The dominant process parameters such as the radiated heat input, the tool speed, and the gap between the tool tip and the foam sheet (tool height) were considered in the experiments. The effectiveness of the developed post-processing method fo forming or engraving fine details on the VLM-ST parts has been thus demonstrated. The experiments on engraving several sets of letters, such as CANESM, 인간, and 한국과학기술원, on the EPS foam sheet were carried out. In addition, a flowery shape was engraved on a three-dimensionally curved surface of a pottery-shape VLM-ST part.

The Production of Metal Matrix Composites by Using the EPC Process;Particle Behavior at Solid-Liquid Interface (소실모형주조법에 의한 금속기 복합재료의 제조;고액계면과 입자거동에 관하여)

  • Park, Jong-Ik;Kim, Young-Seob;Kim, Jeong-Min;Kim, Dong-Gyu
    • Journal of Korea Foundry Society
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    • v.17 no.1
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    • pp.93-99
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    • 1997
  • A possibility of production of aluminium matrix composites by using the lost foam process was investigated. Silicon carbide particles, graphite particles, and stainless steel wires were used as reinforcement materials. The reinforcement materials were introduced to the polystyrene to form patterns via injection molding process. The results obtained from this experiment can be summarized as follows. In Al/SiCp system, the particles with the radius of $100{\mu}m$ and over were entrapped in the matrix in the case of upward freezing of which solidification direction was opposite to floating direction of the particles. And few particles were entrapped in the matrix in downward freezing. In Al/graphite system, almost no particles were entrapped in the matrix except the area chill attatched. When the thickness of polystyrene slice was 4mm in Al/stainless steel wire system, the floating tendency of fibers was observed to increase as the distance from the ingate was increased.

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Studies on Recycling of Waste Polyurethane ( II ) (폐우레탄고무 재활용에 관한 연구 (II))

  • Lee, Hyung-Kyu;Hwang, Sung-Hyuk;Kim, Jin-Kuk
    • Elastomers and Composites
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    • v.35 no.3
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    • pp.227-235
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    • 2000
  • This study focused on the recycling technology and application of waste polyurethane scrap($5{\sim}7mm$) and waste urethane form from the footware scrap. Firstly we suggest the waste polyurethane can be used as a component of medium for hydroponic rose culture. Secondly, recycled thermoplastic polyurethane(RTPU) was produced and blended it with high impact polystyrene(HIPS). And also, in order to extend application of recycling field, the former was produced with adding the amine foaming agent to RTPU/HIPS alloy. The main purpose of this study is to diverse of the recycling of the waste polyurethane.

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Study on Rapid Manufacturing of 3D Functional Parts Combining VLM-ST Process and Its RT Technology (단속형 가변적층 쾌속조형공정과 쾌속툴링 기술을 이용한 쾌속 3차원 기능성 제품 개발에 관한 연구)

  • 안동규;이상호;김기돈;양동열
    • Transactions of Materials Processing
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    • v.11 no.4
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    • pp.323-331
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    • 2002
  • The combination of rapid prototyping(RP) and rapid tooling(RT) has a potential for rapid manufacturing of three-dimensional parts. In the present study, a new RP system transfer type Variable Lamination Manufacturing using Expandable Polystyrene Foam (VLM-ST), is proposed to fabricate net shapes of three-dimensional prototypes. Various three-dimensional parts, such as a knob shape and a human head shape, are manufactured by the VLM-ST apparatus. In addition, a new rapid tooling technology, which utilizes a room temperature vulcanizing (RTV) molding technique and a triple reverse process technique, is proposed to manufacture net shapes of three-dimensional plastic parts using the prototypes of VLM-ST. A plastic part of the knob shape is produced by the proposed RT technology. The combination of the proposed RP and RT enables the manufacture of a plastic knob within two days.

A Fundamental Study on the Effectiveness of Cold Weather Concreting Using Anti-freeze Agent and Insulating Form (Focused on the Slab) (내한제 및 단열거푸집에 의한 한중콘크리트 시공의 효율화에 관한 기초적 연구 (슬래브를 중심으로))

  • Kim, Kyoung-Min;Won, Cheol;Hong, Sang-Hee;Kim, Gi-Cheol;Oh, Sun-Kyo;Han, Cheon-Goo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.913-918
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    • 2001
  • This paper investigates insulating effects and strength properties of concrete under cold climate carrying out the experiment with insulating forms on the slab member. According to test results, under $-10^{\circ}C$ of outer temperature, the surface of concrete exposed to outer temperature goes below zero after 10hours since exposed. And, the surface of concrete covered with vinyl and blanket goes below zero after 42hours. However, the surface of concrete covered with insulating materials such as polystyrene foam does not drop below zero until 55hours. And, according to coring sample strength test, compressive strength cured with insulation shows much higher strength than no insulation curing condition and vinyl and blanket curing condition.

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A Description Method of Linear Hotwire Posture in Space for the Cutting System of VLM-S (가변적층 쾌속조형공정용 CAD 시스템 개발을 위한 3차원 공간상에서의 선형열선절단기 자세표현에 관한 연구)

  • 이상호;문영복;안동규;양동열;채희창
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2001.04a
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    • pp.11-14
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    • 2001
  • In all Rapid Prototyping(RP) processes, computer-aided design(CAD) solid model is sliced into thin layers of uniform, but not necessarily constant, thickness in the building direction. Each cross-sectional layer is successively deposited and, at the same time, bonded onto the previous layer, the stacked layers form a physical part of the model. The objective of this study is to develop a method for obtaining necessary coordinates$(x,\;y,\;\theta_x,\;\theta_y)$ to position linear hotwire of the cutting system in three-dimensional space for the Variable Lamination Manufacturing process (VLM-S), which utilizes expandable polystyrene foam sheet as part material. In order to examine the applicability of the developed method to VLM-S, various three-dimensional shapes, such as a spanner, a patterned columm, and a pyramid were made using data obtained from the method.

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Processing of Microcellular Nanocomposite Foams by Using a Supercritical Fluid

  • Wee, Dongho;Seong, Dong Gi;Youn, Jae Ryoun
    • Fibers and Polymers
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    • v.5 no.2
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    • pp.160-169
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    • 2004
  • Polystyrene/layered silicate nanocomposites were prepared by melt intercalation. To examine the distribution of the clay in polymer matrix, small angle X-ray scattering (SAXS) and transmission electron microscopy (TEM) were used. Intercalated nanocomposites were obtained and their rheological properties were investigated. Microcellular nanocomposite foams were produced by using a supercritical fluid. As clay contents increased, the cell size decreased and the cell density increased. It was found that layered silicates could operate as heterogeneous nucleation sites. As the saturation pressure increased and the saturation temperature decreased, the cell size decreased and the cell density increased. Microcellular foams have different morphology depending upon the dispersion state of nanoclays.