• Elastomers and Composites
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• 제50권3호
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• pp.189-195
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• 2015

In this study, we prepared epoxidized poly ethylene-ter-1-decene-ter-divinylbenzene (Epo-PEHV) as a reactive compatibilizer to prevent phase separation phenomenon which occurs upon blending polypropylene (PP) and ethylene-vinyl alcohol copolymer (EVOH). Firstly, PEHV was prepared under high catalyst activity according to content of catalyst and cocatalyst. After then, we modified vinyl group of the terpolymer with epoxy group. We observed that the terpolymer was successfully epoxidized by 1H-NMR and FT-IR analysis. The Epo-PEHV was added by 2, 5, 10% in PP/EVOH blends. The morphologies and mechanical properties of PP/Epo-PEHV/EVOH blends were analyzed by SEM and UTM, respectively. Epo-PEHV enhanced the interfacial adhesion of PP and EVOH blends.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2009년도 춘계 학술논문 발표대회 학계
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• pp.61-64
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• 2009

This study is reviewed fire resistance characteristics of high strength concrete according to changes in PP fiber mixing ratio and type of fine aggregate, and the results can be summarized as follows. As fire resistance characteristics, all plain crushed sands prevented spalling regardless of increase in mixing ratio of PP fiber. Mixtures other than the plain showed satisfactory spalling prevention when 0.05 % or more of PP fiber was mixed. After the fire resistance experiment, the plain showed 5.5 % of mass loss rate when fiber was not mixed and others could not be measured. According to increase in mixing ratio of fiber, river sand with fineness modulus of 2.2 showed most satisfactory result of 34 %${\sim}$42 %. Mass loss rate after fire resistance experiment was most satisfactory at about 10 % in the plain crushed sand without mixing of fiber, and all other mixes with 0.05 % PP fiber or more showed 5${\sim}$10 % loss rate.

• Elastomers and Composites
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• 제38권1호
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• pp.27-37
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• 2003

This work presents a comparative study of the morphology and structure related properties of thermoplastic elastomer blends based on SEBS/PP/Oil and dynamically vulcanized EPDM/PP/Oil. A combination of ruthenium oxide staining and low voltage scanning electron microscopy (LVSEM) was found to be suitable for the study of morphology of these highly oil extended blends. h close analogy was found in the mechanical, thermal and rheological properties of the two systems made in an internal Brabender mixer and co-rotating turin screw extruder. The morphology of the blends, as made by the two techniques, was found to be significantly different. In the case of TPVs, the blonds made in the extruder had smaller EPDM domains and better tensile properties. In the case of SEBS, the blends made in the Brabender had more co-continuous phases and showed better tensile properties. Crystallization behavior of the isotactic polypropylene in the blends was found to be influenced by the type of rubber. Blends of SEBS/PP crystallized at a lower temperature than the TPVs. These differences were probably caused by differences in the nucleating ability of the two rubbers.

• Journal of the Optical Society of Korea
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• 제12권1호
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• pp.38-41
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• 2008

Precise micropatterning of polypropylene film, which is highly transparent in the wavelength range over 250 nm has been demonstrated by 355 nm nano/picosecond laser and 785 nm femtosecond laser. Increments of both the pulse energy and the shot number of pulses lead to cooccurrence of photochemical and thermal effects, demonstrated by the spatial expansion of rim on the surface of PP. The shapes of the laser-ablated polypropylene films were imaged by optical microscope and measured by a 3D optical measurement system. And, the ablation depth and width of polypropylene film ablated by femtosecond laser at various pulse energy and pulse number were characterized. Our results demonstrate that a femtosecond pulsed laser is an efficient tool for fabricating micropatterns of polypropylene films, where the micropatterns are specifically tailored in size, location and number easily controlled by laser processing conditions.

• 폴리머
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• 제29권3호
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• pp.248-252
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• 2005

다양한 조성을 갖는 폴리프로필렌(PP)/몬모릴로나이트(MMT) 나노복합체를 이축압출기를 이용하여 용융혼합 법으로 제조하였다. 본 연구에서는 MMT의 박리를 위하여 MAH-g-PP를 상용화제로 사용하였고, 제조된 나노복합체를 X-ray 회절(X-ray diffraction, XRD)과 투과전자현미경(Transmission Electron Microscope, TEM)을 통해 MMT가 박리된 것을 확인하였다. PP/MMT 나노복합체의 제조에 사용한 MMT는 난연제와 상승효과를 발휘하여 난연제의 양을 절반가까이 줄였을 경우에도 우수한 난연효과를 나타내었다. PP/MMT 나노복합체는 순수 PP보다 기계적 물성과 열적 물성이 증가하였고, 난연성은 UL 94 V-0로 매우 우수하였다.

• Composites Research
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• 제33권6호
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• pp.346-352
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• 2020

열가소성 복합재료는 수송용 기기의 구조용 소재로써 적용 분야가 확대되고 있다. 따라서 본 연구에서는 유리섬유(GF) 함량 차이에 따른 연속섬유 강화 GF/폴리프로필렌(PP)의 기계적 물성 및 함침성에 대한 평가를 진행하였다. GF 함량이 다른 GF/PP 복합원사를 제조하고 이를 이용하여 연속가압공정법으로 연속섬유 강화 GF/PP 중간재를 제조하였다. GF 함량에 따른 연속섬유 강화 GF/PP 복합재료의 인장강도, 굴곡강도 및 충격강도를 평가하였다. 전계방사형 주사전자현미경을 이용하여 인장파괴 된 GF/PP의 형태를 분석하여 GF 함량에 따른 파괴거동을 확인하였고, 동적기계분석 및 층간전단강도 측정 결과를 바탕으로 GF 함량에 따른 함침성 차이를 확인하였다. 궁극적으로 GF/PP 50 wt.% 복합재료 조건에서 기계적 강도와 함침성이 가장 안정화됨을 확인하였다.

• 한국응용곤충학회지
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• 제54권4호
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• pp.369-374
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• 2015

복숭아순나방(Grapholita molesta)은 핵과류과실에 일차 피해를 주는 해충이다. 이를 해결하기 위해 종합적병해충관리 [IPM]의 일환으로써 전세계적으로 교미교란제가 농가에 적용되고 있다. 왁스, 폴리에틸렌 튜브, 에어로졸 형태의 다양한 교미교란제가 상업화되었다. 이 연구에서는 복숭아순나방 성페로몬 방출기로써 에스테르왁스와 폴리프로필렌(PP)필름백을 구성하는 방출기를 기존의 파라핀 왁스와 폴리에틸렌(PE) 재질의 필름과 비교하여 페로몬의 방출거동을 분석했다. PE재질의 필름백은 성페로몬의 방출이 불규칙한 반면, PP필름백에서 성페로몬은 시간에 따라 일정하게 방출하는 패턴을 얻었다. 이러한 결과를 토대로 Japan 왁스_PP 필름 방출기(Japan_PP)를 제작하였고, 약 5개월 동안 복숭아과수원에 적용한 결과 98% 이상의 교미교란 효과가 검증되었다.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.280-280
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• 2006

Na-bentonite (local clay mineral) and Na-montmorillonite were treated with quaternary alkylammonium cations. The effect of the molecular structure and functional groups of the surfactants on the organoclays was investigated by X-ray diffraction (XRD). For the preparation of nanocomposites, organoclays were melt-blended with polypropylene in a twin screw extruder and $Surlyn^{(R)$. ionomer was used as a reactive compatibilizer. The clay dispersions in the composites were investigated by X-ray diffraction (XRD). XRD spectra showed no peak at low angle indicated that the silicate clay layer has a nearly exfoliated dispersion in the polymer matrix. Thermal and mechanical properties of nanocomposites were higher than those of PP.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 하계학술대회 논문집 D
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• pp.1428-1431
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• 1998

The polypropylene has been known to have higher melting temperature than polyethylene, and good mechanical properties. This paper introduces the experement result of dielectric breakdown properties to a polypropylene with a crystal structure. According to the experement, breakdown voltage is incresed when a thickness of thin film thinned. Spherulites of PP film prepared by annealing is larger than that of PE.

• 한국의류산업학회지
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• 제6권3호
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• pp.384-392
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• 2004

The purpose of this study is in development of effective filter-type polymer adsorbent for removal of pollutants from wastewater by UV irradiation graft polymerization. Photografting of acrylic acid (AA) on polypropylene (PP) nonwoven fabric using benzophenone (BP) as a photosensitizer was investigated. Inhibition of homopolymerization was achieved by adding various concentrations of $FeSO_4{\cdot}7H_2O$, $CuSO_4{\cdot}5H_2O$ and Mohr's salt. As AA concentration was increased, the degree of grafting was increased as to a specific value and then decreased, and the effect of BP concentration showed the same tendency. It was also found that the degree of grafting increased with reaction time and reaction temperature. Addition of the polyfunctional monomers and $H_2SO_4$ to the grafting system accelerated the photografting. The melting temperature, molecular weight and breaking stress and breaking strain were decreased with the increase in the degree of grafting.