• Title/Summary/Keyword: Polypropylene(PP)

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A Study on the Three Phase Glass Fiber/Nylon 6/Polyproylene Composites (나일론 6과 폴리프로필렌 수지에 유리섬유가 보강된삼상 복합재료에 관한 연구)

  • 서문호
    • The Korean Journal of Rheology
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    • v.10 no.2
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    • pp.57-64
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    • 1998
  • A pultrusion resin impregnation (PRI) die, which has been developed recently in our laboratory, was used to pre-pare various composite system. The continuous fiber reinforced composites of glass fiber/polypropylene(GFPP) and glass fiber/polyamide 6 (GFPA) were first manufactured by means of the PRI die and then cut into chopped pellets of predet-ermined length. These pellets and either virgin or modified thermoplastic resin were melt-mixed by a twin screw extruder to prepare GF/PA/PP and GF/PA/PPMA system. The mechanical properties of these blends were investigated and discussed in terms of their morphological observations. These preliminary results revealed that this new impregnation die could be suc-cessfully applied to produce prepregs suitavle for the final shaping process.

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Spalling Properties of High Strength Concrete Mixed with Various Mineral Admixtures Subjected to Fire

  • Han, Cheon-Goo;Han, Min-Cheol;Heo, Young-Sun
    • International Journal of Concrete Structures and Materials
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    • v.2 no.1
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    • pp.41-48
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    • 2008
  • This study investigates the spalling properties of high strength concrete designed with various types of mineral admixture and diverse content ratios of polypropylene (PP) fiber. Experimental factors considered in series I are four pozzolan types of mineral admixture and series II consists of three shrinkage reducing types of mineral admixture. PP fiber was added 0.05, 0.10 and 0.15vol. % in each mixture of series I and series II, so that totally 27 specimens including control concretes in each series were prepared. Test results showed that the increase of fiber content decreased the slump flow of fresh concrete and increased or decreased the air content depending on the declining ratio of slump flow. For the properties of compressive strength, all specimens were indicated at around 50 MPa, which is high strength range; especially all specimens in series II were 60 MPa. Fire test was conducted in standard heating curve of ISO 834 with ${\phi}100{\times}200\;mm$ size of cylinder moulds for 1 hour. The specimens incorporating silica fume exhibited severe spalling and most specimens without the silica fume could be protected from the spalling occurrence in only 0.05vol % of PP fiber content. This fire test results demonstrated that the spalling occurrence in high strength concrete was not only affected by concrete strength related to the porosity of microstructure but also, even more influenced by micro pore structure induced by the mineral admixtures.

A Study On the Structure and Mechanical Properties of PP filament at Different Spinning speed and Draw ratio (방사속도 및 연신비 변화에 따른 Polypropylene filament의 구조와 물성에 관한 연구)

  • Lee, Eun-Woo;Cho, Kyu-Min;Cho, In-Sul
    • Journal of the Korean Society of Industry Convergence
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    • v.2 no.1
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    • pp.27-33
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    • 1999
  • Effects of spinning speed and draw ratio on structure and mechanical properties of PP filament. A The crystalline structure and mechanical properties of uniaxially deformed polypropylene filament has been examined by XRD, birefringence, UTM and density method. Uniaxially deformed PP filament was prepared of various spinning speeds (300, 600, 900m/min.) and draw ratio(x2, x3, x4). From the results of these studies, it found the following facts. Firstly, it was found that the crystallinity and crystallite size (110plane) of the samples were increased with increasing of spinning speed and draw ratio, especially, it was rapidly increased between as spun yarn and 2 times draw ratio. Secondly, birefringence value was increased with increasing of spinning speed and draw ratio. The mechanical properties of initial modulus, tensile strength were increased with increasing of spinning speed and draw ratio also, but the degree of elongation decreased as spinning speed and draw ratio.

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A Study on the Residual Mechanical Properties of Fiber Mixed Concrete with High Temperature and Load (고온 및 하중에 따른 섬유혼입 콘크리트의 잔존역학적 특성에 관한 연구)

  • Yoon, Dae-Ki;Kim, Gyu-Yong;Choe, Gyeong-Choel;Lee, Tae-Gyu;Koo, Kyung-Mo;Kim, Hong-Seop
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.119-120
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    • 2011
  • Recently, the effects of high temperature and fiber content on the residual mechnical properties of high-strength concrete were experimentally investigated. In this paper, residual mechanical properties of concrete with water to cement (w/c) ratios of 55%, 42% and 32% exposed to high temperature are compared with those obtained in fiber reinforced concretes of similar characteristics with the ranging of 0,05% to 0,20% polypropylene (PP) fibers by volume of concrete, and considered factors include pre-load levels (20% and 40% of the maximum load at room temperature). Outbreak time and water contents were tested and were determined the compressive strength. In the result, it is showed that to prevent the explosive spalling of 50MPa grade concretes exposed to high temperature need more than 0.05Vol.% PP fibers. Also, the cross-sectional area of PP fiber can influence on the residual mechanical properties and the spalling tendency of fiber reinforced concrete exposed to high temperature. Especially, the external loading increases not only the residual mechanical properties of concrete but also the risk of spalling and the brittle tendency.

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Preparation and Characterization of Polypropylene/Waste Ground Rubber Tire Powder Microcellular Composites by Supercritical Carbon Dioxide

  • Zhang, Zhen Xiu;Lee, Sung-Hyo;Kim, Jin-Kuk;Zhang, Shu Ling;Xin, Zhen Xiang
    • Macromolecular Research
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    • v.16 no.5
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    • pp.404-410
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    • 2008
  • In order to obtain 'value added products' from polypropylene (PP)/waste ground rubber tire powder (WGRT) composites, PP/WGRT microcellular foams were prepared via supercritical carbon dioxide. The effects of blend composition and processing condition on the cell size, cell density and relative density of PP/WGRT micro-cellular composites were studied. The results indicated that the microcellular structure was dependent on blend composition and processing condition. An increased content of waste ground rubber tire powder (WGRT) and maleic anhydride-grafted styrene-ethylene-butylene-styrene (SEBS-g-MA) reduced the cell size, and raised the cell density and relative density, whereas a higher saturation pressure increased the cell size, and reduced the cell density and relative density. With increasing saturation temperature, the cell size increased and the relative density decreased, whereas the cell density initially increased and then decreased.

A study of size and frictional effect on the evolution of melting PartII: Twin screw extruder

  • Kim, D.S.;Lee, B.K.;Kim, H.S.;Lee, J.W.;C.G. Gogos
    • Korea-Australia Rheology Journal
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    • v.13 no.2
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    • pp.89-95
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    • 2001
  • Effects of particulate size and frictional characteristics were examined on the melting behavior of PP(polypropylene) in a twin screw extruder. Powder and pellet types of PP were used and each component was blended with PE(polyethylene) wax and clay, respectively. It was observed that small size particulates, 1.e. powder systems exhibit accelerated melting behavior; and it was also found that the abrasive auditive acts as an effective agent for fast melting of PP powder. Retardation of melting due to the reduced friction was observed in both types of PP, contrary to the result found in a batch mixer. The tendency observed in variation of torque and exit temperature was explained in terms of frictional effect and length of compacted region formed during evolution of melting.

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Injection Molding Characteristics of COC and PP in Micro Rib Structure (미세 리브 구조에서 COC 및 PP의 사출성형 특성)

  • Jung, W.C.;Heo, Y.M.;Shin, K.H.;Yoon, G.S.;Chang, S.H.
    • Transactions of Materials Processing
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    • v.15 no.2 s.83
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    • pp.158-163
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    • 2006
  • The demand for the miniaturization and high-precision of machine part has recently increased in new technology like biotechnology(BT) and nanotechnology(NT). The purpose of this study is to analyze the molding characteristics according to injection conditions by measuring the filling height in micro injection molding of the polypropylene(PP) and cyclic olefin copolymer(COC). The result shows that the filling effect of COC is better than that of PP in micro rib structure with injection molding process.

The effect of carboxymenthyl cellulose in PP fibers for dye absorption ability

  • Panutumrong, Praripatsaya;Metanawin, Tanapak;Metanawin, Siripan
    • International Journal of Advanced Culture Technology
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    • v.3 no.1
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    • pp.52-60
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    • 2015
  • The present study aims to the use of carboxymenthyl cellulose (CMC) improving the ability of fiber in the dyeing process. Cellulose was extracted from banana leaves by NaOH and then modified by reacting with chloroacetic acid to obtain the carboxymenthyl cellulose. The effect of carboxymenthyl cellulose contents on the mechanical properties and dye absorption were also investigated. Then, CMC were blend with polypropylene (grade 561R) at 1%, 3% and 5% by weight ratio. The fibers were obtained from single screw extruder. The results show that the mechanical properties of the product decreased when increased the amount of CMC in the fiber product. After dyeing, the dye however were absorbed by the CMC-PP fibers more than the original PP fibers. The absorption of dye on the CMC-PP fibers increased significantly with the CMC ratio.

Rheology and Tensile Properties of EPDM/Polyolefin Blends (EPDM과 폴리올레핀 블렌드의 레올로지와 인장물성(引張物性))

  • Ha, Chang-Sik;Ryou, Jin-Ho;Kang, Dong-Il;Cho, Won-Jei
    • Elastomers and Composites
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    • v.25 no.3
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    • pp.203-210
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    • 1990
  • The structure and properties of blends of ethylene-propylene-diene terpolymer(EPDM) and polyolefin blends have been investigated. The rheology and tensile properties of the EPDM/HDPE(high density polyethylene), EPDM/PP(polypropylene) binary and EPDM/PP/HDPE ternary blends were studied along with morphological analyses. Those properties were affected by preferential interaction of EPDM on HDPE, compared to that of EPDM on PP, for the binary blends. The preferetial interaction may stem from the molecular characteristics of EPDM to possess more ethylene units than propylene units in the elastomer. The EPDM played a role as compatibilizer for HDPE and PP in the EPDM/PP/HDPE ternary blends.

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Study on the Functionalization of Waste EPDM and PP Blend

  • Chung, Kyungho;Kim, Jinhee
    • Elastomers and Composites
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    • v.50 no.4
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    • pp.245-250
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    • 2015
  • Recycling of ethylene-propylene-diene terpolymer (EPDM) scrap was tried by blending with polypropylene (PP). EPDM scrap powder was prepared by shear pulverization process at high temperature, which may lead to selective chain scission induced by difference in the critical elastic coefficient. On the other hand, EPDM scrap powder was prepared by adding a selected reclaiming agent during shear pulverization process at high temperature. Terpene as a bonding agent was then introduced to improve adhesion property. PP, used as a matrix for manufacturing thermoplastic elastomer, was modified by the incorporation of dicumyl peroxide and maleic anhydride. The functionalized EPDM and modified PP were blended and cured dynamically at $190^{\circ}C$. The blend materials prepared in this study showed the comparable results to those of conventional TPE in terms of tensile and flow properties. Also, the odor component of recycled EPDM was analyzed using GC-MS.