• Title/Summary/Keyword: Polymethylmethacrylate(PMMA)

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Long Bone Fractures in Raptors: 28 cases (2004-2007)

  • Yoon, Hun-Young;Fox, Derek B.;Jeong, Soon-Wuk
    • Journal of Veterinary Clinics
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    • v.25 no.3
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    • pp.215-217
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    • 2008
  • Medical records from the Veterinary Medical Teaching Hospital of the University of Missouri-Columbia from 2004 to 2007 were available for 28 raptors that underwent long bone fracture repair. There were 14 owls, 10 hawks, 2 vultures, 1 eagle, and 1 falcon. Mean body weight was 780 g (ranged from 150 to 1400 g) for 14 owls; 650 g (ranged from 150 to 1270 g) for 10 hawks; 1760 g (ranged from 1520 to 2000 g) for 2 vultures; 5000 g for 1 eagle; and 130 g for 1 falcon. Of all 28 fracture cases, 11 cases (39%) and 1 case (3%) were related to hit-by-car and shooting respectively. Physical examination revealed dehydration in 18 raptors (64%) and lethargy in 12 raptors (42%). Forty one long bone fractures were included in 28 cases. The radiographs revealed 13 ulnar fractures (32%), 12 humeral fractures (30%), 10 radial fractures (25%), 4 tibiotarsal fractures (9%), 1 femoral fracture (2%), and 1 fibular fracture (2%). External skeletal fixation using polymethylmethacrylate (PMMA) combined with intramedullary fixation was used in 19 long bone fractures (46%). Intramedullary fixation using intramedullary Kirschner pin was used in 16 long bone fractures (39%). No surgical treatment was performed in 6 long bone fractures (15%). This study reported that many of raptors presented dehydration and lethargy when admitted for treatment. Therefore, proper hydration and nutrition are critical pre-surgical requirements. In addition, combination of internal fixation and external skeletal fixation using PMMA might be better option to treat raptors with comminuted fracture that results from mostly trauma of hit-by-car.

The Analysis of Patterns and Risk Factors of Newly Developed Vertebral Compression Fractures after Percutaneous Vertebroplasty

  • Yoo, Chai Min;Park, Kyung Bum;Hwang, Soo Hyun;Kang, Dong Ho;Jung, Jin Myung;Park, In Sung
    • Journal of Korean Neurosurgical Society
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    • v.52 no.4
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    • pp.339-345
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    • 2012
  • Objective : The purpose of this study was to investigate the patterns and the risk factors of newly developed vertebral compression fractures (VCFs) after percutaneous vertebroplasty (PVP). Methods : We performed a retrospective review of the 244 patients treated with PVP from September 2006 to February 2011. Among these patients, we selected 49 patients with newly developed VCFs following PVP as the new VCFs group, and the remaining 195 patients as the no VCFs group. The new VCFs group was further divided into 2 groups : an adjacent fractures group and a nonadjacent fractures group. The following data were collected from the groups : age, gender, body weight/height, body mass index (BMI), bone mineral density (BMD) score of the spine and femur, level of initial fracture, restoration rate of anterior/middle vertebral height, and intradiscal cement leakage, volume of polymethylmethacrylate (PMMA). Results : Age, gender, mean body height/weight, mean BMI and volume of PMMA of each of the group are not statistically significantly associated with fractures. In comparison between the new VCFs group and the no VCFs group, lower BMD, intradiscal cement leakage and anterior vertebral height restoration were the significant predictive factors of the fracture. In addition, new VCFs occurrence at the adjacent spines was statistically significant, when the initial fracture levels were confined to the thoracolumbar junction, among the subgroups of new VCFs. Conclusion : Lower spinal BMD, the greater anterior vertebral height restoration rate and intradiscal cement leakage were confirmed as risk factors for newly formed VCFs after PVP.

Hydrophilic surface formation of polumer treated by ion assisted reaction and its applications (이온빔보조 반응법을 이용한 고분자 표면의 친수성처리와 그 응용)

  • Cho, J.;Choi, S. C.;Yun, K.H.;Koh, S. K.
    • Journal of the Korean Vacuum Society
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    • v.8 no.3B
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    • pp.262-268
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    • 1999
  • Polycarbonate (PC) and Polymethylmethacrylate (PMMA) surface was modified by ion assisted reaction (IAR) technique to obtain the hydrophilic functional groups and improve the wettability. In conditions of ion assisted reaction, ion beam energy was changed from 500 to 1500eV, and ion dose and oxygen gas blown rate were fixed $1\times10^{16}$ ions/$\textrm{cm}^2$ and 4ml/min, respectively. Wetting angle of water on PC and PMMA surface modified by $Ar^+$ ion without blowing oxygen at 4ml/mon showed $5^{\circ}$ and $10^{\circ}$. Changes of wetting angle with oxygen gas and $Ar^+$ ion irradiation were explained by considering formation of hydrophilic group due to a reaction between irradiated polymer chain by energetic ion irradiation and blown oxygen gas. X-ray photoelectron spectroscopy analysis shows that hydrophilic groups such as -C-O, -(C=O)- and -(C=O)-O- are formed on the surface of polymer by chemical interaction. The polymer surface modification using ion assisted reaction only changed the surface physical properties and sept the bulk properties. In comparison with other modification methods, the surface modification by IAR treatment was chemically stable and enhanced the adhesion between metal and polymer surface. The applications of various kinds of polymer surface modification methods, metal and polymer surface. The applications of various kinds of polymer surface modification could be appled to the new materials about hydrophilic surface properties by IAR treatment. The adhesion between metal film and polymer measured by Scotch tape test whether the hydrophilic surfaces could improve the adhesion strength or not.

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Stress Analysis of Total Knee System Depending on Implant Materials and Fixation Methods (인공무릎관절에 있어서 임플란트의 재료 및 고정방법에 따른 응력분석)

  • Cho, C.H.;Cho, Y.K.;Choi, J.B.;Choi, K.
    • Proceedings of the KOSOMBE Conference
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    • v.1997 no.11
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    • pp.484-488
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    • 1997
  • Three-dimensional finite element analyses were used to compare the stress distribution and the stability of the fixation among seven different tibial components and to investigate the effect due to implant materials in total knee arthroplasty. The components included an intact tibia(Type I), Cemented Cobalt-Chromium tibial tray implanted with a PMMA cemented Co-Cr stem(Type II), Cemented Co-Cr tibial tray with a uncemented Co-Cr stem(Type III), Cemented Ultra High Molecular Weight Polyethylene (UHMWPE) tibial tray with a cemented UHMWPE stem (Type IV), Cemented UHMWPE tray with a uncemented UHMWPE stem(Type V), Cemented Co-Cr tray without a stem(Type VI), and Cemented UHMWPE tray without a stem(Type VII). Uncemented components were assumed to have complete bony in growth and a rigid state of fixation between component and bone. The interface between bone/cement/component of cemented components was also assumed to be fully bonded. Bi-condylar forces were applied. The results indicated that Uncemented stem components provided lower bone stress shielding and stress concentration. The UHMWPE tray and stem component showed better agreement with the intact tibia than the Co-Cr Alloy tray and stem components. If the implant tray can be fixed firmed without a stem, Cemented PE tray without a stem(Type VII) may be recommended to give the best characteristics in the sense of stress distribution and stability.

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Effects of four novel root-end filling materials on the viability of periodontal ligament fibroblasts

  • Akbulut, Makbule Bilge;Arpaci, Pembegul Uyar;Eldeniz, Ayce Unverdi
    • Restorative Dentistry and Endodontics
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    • v.43 no.3
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    • pp.24.1-24.12
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    • 2018
  • Objectives: The aim of this in vitro study was to evaluate the biocompatibility of newly proposed root-end filling materials, Biodentine, Micro-Mega mineral trioxide aggregate (MM-MTA), polymethylmethacrylate (PMMA) bone cement, and Smart Dentin Replacement (SDR), in comparison with contemporary root-end filling materials, intermediate restorative material (IRM), Dyract compomer, ProRoot MTA (PMTA), and Vitrebond, using human periodontal ligament (hPDL) fibroblasts. Materials and Methods: Ten discs from each material were fabricated in sterile Teflon molds and 24-hour eluates were obtained from each root-end filling material in cell culture media after 1- or 3-day setting. hPDL fibroblasts were plated at a density of $5{\times}10^3/well$, and were incubated for 24 hours with 1:1, 1:2, 1:4, and 1:8 dilutions of eluates. Cell viability was evaluated by XTT assay. Data was statistically analysed. Apoptotic/necrotic activity of PDL cells exposed to material eluates was established by flow cytometry. Results: The Vitrebond and IRM were significantly more cytotoxic than the other root-end filling materials (p < 0.05). Those cells exposed to the Biodentine and Dyract compomer eluates showed the highest survival rates (p < 0.05), while the PMTA, MM-MTA, SDR, and PMMA groups exhibited similar cell viabilities. Three-day samples were more cytotoxic than 1-day samples (p < 0.05). Eluates from the cements at 1:1 dilution were significantly more cytotoxic (p < 0.05). Vitrebond induced cell necrosis as indicated by flow cytometry. Conclusions: This in vitro study demonstrated that Biodentine and Compomer were more biocompatible than the other root-end filling materials. Vitrebond eluate caused necrotic cell death.

Manufacturing and Characterization of Organic-Inorganic Hybrid Coating Film Using Sol-Gel Method (Sol-Gel법을 이용한 유무기 하이브리드 코팅막 제조 및 특성평가)

  • Seungwon Cho;Dabin Kim;Ji-Sun Lee;Dongwook Shin;Jinho Kim
    • Korean Journal of Materials Research
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    • v.34 no.9
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    • pp.439-447
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    • 2024
  • Organic-inorganic hybrid coating films have been used to increase the transmittance and enhance the physical properties of plastic substrates. Sol-gel organic-inorganic thin films were fabricated on polymethylmethacrylate (PMMA) substrates using a dip coater. Metal alkoxide precursor tetraethylsilicate (TEOS) and alkoxy silanes including decyltrimethoxysilane (DTMS), 3-glycidoxypropyltrimethoxysilane (GPTMS), phenyltrimethoxysilane (PTMS), 3-(trimethoxysilyl)propyl methacrylate (TMSPM) and vinyltrimethoxysilane (VTMS) were used to synthesize sol-gel hybrid coating solutions. Sol-gel synthesis was confirmed by the results of FT-IR. Cross-linking of the Si-O-Si network during synthesis of the sol-gel reaction was confirmed. The effects of each alkoxy silane on the coating film properties were investigated. All of the organic-inorganic hybrid coatings showed improved transmittance of over 90 %. The surface hardness of all coating films on the PMMA substrate was measured to be 4H or higher and the average thickness of the coating films was measured to be about 500 nm. Notably, the TEOS/DTMS coating film showed excellent hydrophobic properties, of about 97°.

A Proposal of Round Specimen for the Determination of Crack Arrest Toughness (균열정지 인성치결정을 위한 원형시편의 제안)

  • 이억섭;김상철;송정일;이규철
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.5
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    • pp.1472-1478
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    • 1991
  • 본 연구에서는 Rectangular Computer Tension(CT) 시편을 수정하여 만든 표준 시편인 MRL-CLWL시편(material research laboratorycrack line wedge loaded specimen )으로 균열정지 인성치를 결정하였다. 그리고 CT시편과 같은 효과를 갖는 Newman등 이 제안한 round compact tension(RCT)시편을 수정한 Round-CLWL 시편으로 균열정지인 성치를 결정하여 상호 비교평가하였다. Round-CLWL 시편은 시편제작시 round-bar를 절단하여 시편으로 가공할 수 있으므로 가공성이 좋으며 따라서 가공비가 적게 든다. 특히 균열 위치 및 방향을 임의로 선택하여 가공하기가 용이하므로 방향성이 있는 소 재의 균열정지 인성치를 결정하는 데 매우 편리한 시편이라 생각된다. 본 논문에서 는 Round-CLWL 시편으로 $K_{1a}$ 값을 계산하는데 필요한 형상계수를 결정하였으며, Polymethylmethacrylate(PMMA)를 사용하여 Round-CLWL 시편 채택의 타당성 확인을 위 한 MRL-CLWL과 Round-CLWL 시편 채택의 타당성 확인을 위한 MRL-CLWL과 Round-CLWL시 편의 $K_{1a}$결정 실험을 하였다.하였다.

CdSe/ZnS 양자점과 무기 형광체를 색변환층으로 이용한 백색 유기발광 소자의 특성 연구

  • Kim, Gi-Hyeon;Jeon, Yeong-Pyo;Kim, Tae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.302.2-302.2
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    • 2014
  • 유기발광소자는 고휘도, 넓은 시야각, 빠른 응답속도, 높은 색재현성, 좋은 유연성의 소자 특성 때문에 디스플레이 제품에 많이 응용되고 연구가 활발하게 진행되고 있다. 최근에 저소비전력, 고휘도, 소형화 및 장수명의 장점을 가진 유기발광소자의 상용화가 진행되면서 차세대 디스플레이소자로서 관심을 끌게 되었다. 최근에는 고효율의 장점을 가지는 무기 형광체와 양자점을 이용한 백색 유기발광 소자에 대한 연구가 활발하게 진행되고 있으나 색 안정성이 좋지 않은 문제점이 있다. 본 연구에서는 적색 빛을 방출하는 CdSe/ZnS 양자점과 녹색 빛을 방출하는 YAG:Ce3+ 무기 형광체를 포함하는 polymethylmethacrylate (PMMA)를 색변환층으로 이용하여 청색 유기발광소자에 결합한 백색 유기발광소자를 제작하였다. CdSe/ZnS 양자점과 YAG:Ce3+ 무기 형광체의 광흡수대역은 250 nm에서 500 nm이므로 470 nm의 청색 발광소자의 청색 빛을 흡수하여 색변환층에서 재 발광할 때 색 변환 결과를 무기 형광체와 양자점의 여러 가지 혼합 비율에 따라 전계발광 스펙트럼을 통해 관측하였다. 또한, 전압을 12 V 에서 16 V까지 변화하였을 때 색좌표가 (0.32, 0.34)에서 (0.30, 0.33)으로 적은 변화를 보여 높은 색안정성을 확인 할 수 있었다. 이 연구 결과는 양자점과 무기 형광체를 혼합한 색변환층을 이용한 백색 유기발광소자의 색 변환 효율 증가와 색안정성에 대한 기초자료로 활용할 수 있다.

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A Study on Plasma Sprayed Porous Super Austenitic Stainless Steel Coating for Improvement of Bone Ingrowth (Bone ingrowth 향상을 위해 플라즈마 용사된 초내식성 오스테나이트 스테인리스강의 다공성 코팅층에 대한 연구)

  • 오근택;박용수
    • Journal of Surface Science and Engineering
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    • v.29 no.2
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    • pp.81-92
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    • 1996
  • The cementless fixation of bone ingrowth by porous coatings on artificial hip joint prostheses are replacing polymethylmethacrylate(PMMA) bone cement fixations. However, the major interests in the field of porous metal coating are environmental corrosivity accelerated by metal ion release, deterioration in the mechanical property of the coating, and the mechanical failure of the coatings as well as the substrate. Therefore, the selection of right materials for coatings and the development of porous coating techniques must be accomplished. Because of the existing problems in Ti and Ti alloys which are used extensively, this study is focused on the plasma spraying technique for coating on super stainless steel substrate. In order to determine the optimum conditions which satisfy the requirement for the porous coatings, under the plasma spraying, we selected the experimental parameters which extensively influenced on the characteristics of the coating through the pre-examination. Spray distance has been selected among 120, 160, and 200mm and primary gas flow rate among 70, 100, and 130 SCFH. Current and secondary gas($H_2$) flow rate was fixed at 400A, and 15 SCFH respectively. To understand the characteristics of the coatings, surface morphology, cross-sectional micro-structure, surface roughness, residual stress, and corrosion resistance were elucidated and the best conditions for the bone ingrowth improvement on artificial hip joint prostheses were found.

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Investigating the effects of a range shifter on skin dose in proton therapy

  • Ming Wang;Lei Zhang;Jinxing Zheng;Guodong Li;Wei Dai;Lang Dong
    • Nuclear Engineering and Technology
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    • v.55 no.1
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    • pp.215-221
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    • 2023
  • Proton treatment may deliver a larger dose to a patient's skin than traditional photon therapy, especially when a range shifter (RS) is inserted in the beam path. This study investigated the effects of an RS on skin dose while considering RS with different thicknesses, airgaps and materials. First, the physical model of the scanning nozzle with RS was established in the TOol for PArticle Simulation (TOPAS) code, and the effects of the RS on the skin dose were studied. Second, the variations in the skin dose and isocenter beam size were examined by reducing the air gap. Finally, the effects of different RS materials, such as polymethylmethacrylate (PMMA), Lexan, polyethylene and polystyrene, on the skin dose were analysed. The results demonstrated that the current RS design had a negligible effect on the skin dose, whereas the RS significantly impacted the isocenter beam size. The skin dose was increased considerably when the RS was placed close to the phantom. Moreover, the magnitude of the increase was related to the thickness of the inserted RS. Meanwhile, the results also revealed that the secondary proton primarily contributed to the increased skin dose.