• 제목/요약/키워드: Polymethyl Methacrylate(PMMA)

검색결과 159건 처리시간 0.026초

Submicron-scale Polymeric Patterns for Tribological Application in MEMS/NEMS

  • Singh R. Arvind;Yoon Eui-Sung;Kim Hong Joon;Kong Hosung;Jeong Hoon Eui;Suh Kahp Y.
    • KSTLE International Journal
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    • 제6권2호
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    • pp.33-38
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    • 2005
  • Submicron-scale patterns made of polymethyl methacrylate (PMMA) were fabricated on silicon-wafer using a capillarity-directed soft lithographic technique. Polyurethane acrylate (PUA) stamps (Master molds) were used to fabricate the patterns. Patterns with three different aspect ratios were fabricated by varying the holding time. The patterns fabricated were the negative replica of the master mold. The patterns so obtained were investigated for their adhesion and friction properties at nano-scale using AFM. Friction tests were conducted in the range of 0-80 nN. Glass (Borosilicate) balls of diameter 1.25 mm mounted on cantilever (Contact Mode type NPS) were used as tips. Further, micro-friction tests were performed using a ball-on-flat type micro-tribe tester, under reciprocating motion, using a soda lime ball (1 mm diameter) under a normal load of 3,000 mN. All experiments were conducted at ambient temperature ($24{\pm}1^{\circ}C$) and relative humidity ($45{\pm}5\%$). Results showed that the patterned samples exhibited superior tribological properties when compared to the silicon wafer and non-patterned sample (PMMA thin film) both at the nano and micro-scales, owing to their increased hydrophobicity and reduced real area of contact. In the case of patterns it was observed that their morphology (shape factor and size factor) was decisive in defining the real area of contact.

Hybrid LED용 유기 형광체로서의 Swallow-Tail Perylene Bisimide 제조 및 특성 연구 (Synthesis and Characterization of Swallow-Tail Perylene Bisimide as Organic Phosphor for Hybrid LED)

  • 정성봉;정연태
    • 한국전기전자재료학회논문지
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    • 제32권1호
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    • pp.86-92
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    • 2019
  • Although perylene bisimide derivatives have advantages such as excellent thermal stability and high luminance efficiency, they have poor solubility characteristics in organic solvents. In this research, in order to improve the solubility characteristics, we prepared perylene bisimide derivatives (1C) and (2C) with swallow-tail substituted imide, which is known to lead to excellent solubility. The structures and properties of swallow-tail perylene bisimide (1C) and (2C) were analyzed by $^1H-NMR$, FT-IR, UV/Vis spectroscopy, and thermogravimetric analysis (TGA). The maximum absorption wavelengths of (1C) and (2C) in the UV/Vis spectrum were 558 nm and 556 nm, respectively, and the maximum emission wavelengths were 602 nm and 600 nm, respectively. In the TGA, (1C) demonstrated good thermal stability with less than 5 wt% weight loss up to $242^{\circ}C$. In the solubility test, (1C) and (2C) exhibited solubilities of more than 5 wt% in chloroform, ethyl acetate, and dimethylformamide, but not in methanol. When the compounds (1C) and (2C) were mixed with PMMA (polymethyl methacrylate), thin films showed peaks at 679 nm and 677 nm, respectively, in the photoluminescence spectra. (1C) was found to be a possible candidate as red organic phosphor for hybrid LEDs.

Correlation analysis between radiation exposure and the image quality of cone-beam computed tomography in the dental clinical environment

  • Song, Chang-Ho;Yeom, Han-Gyeol;Kim, Jo-Eun;Huh, Kyung-Hoe;Yi, Won-Jin;Heo, Min-Suk;Lee, Sam-Sun
    • Imaging Science in Dentistry
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    • 제52권3호
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    • pp.283-288
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    • 2022
  • Purpose: This study was conducted to measure the radiation exposure and image quality of various cone-beam computed tomography (CBCT) machines under common clinical conditions and to analyze the correlation between them. Materials and Methods: Seven CBCT machines used frequently in clinical practice were selected. Because each machine has various sizes of fields of view (FOVs), 1 large FOV and 1 small FOV were selected for each machine. Radiation exposure was measured using a dose-area product (DAP) meter. The quality of the CBCT images was analyzed using 8 image quality parameters obtained using a dental volume tomography phantom. For statistical analysis, regression analysis using a generalized linear model was used. Results: Polymethyl-methacrylate (PMMA) noise and modulation transfer function (MTF) 10% showed statistically significant correlations with DAP values, presenting positive and negative correlations, respectively (P<0.05). Image quality parameters other than PMMA noise and MTF 10% did not demonstrate statistically significant correlations with DAP values. Conclusion: As radiation exposure and image quality are not proportionally related in clinically used equipment, it is necessary to evaluate and monitor radiation exposure and image quality separately.

각막 후면 지형 측정을 위한 새로운 방법의 신뢰도 분석 및 평가 (Validating a New Approach to Quantify Posterior Corneal Curvature in Vivo)

  • 윤정호
    • 한국안광학회지
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    • 제17권2호
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    • pp.223-232
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    • 2012
  • 목적: 본 연구는 각막 전면의 지형과 각막의 두께를 이용하여 각막 후면 정점 곡률과 asphericity(Q)를 측정하기 위해 고안된 새로운 방법의 신뢰도 평가를 위해서 시행 되었다. 방법: 각막 후면의 정점 곡률 및 Q는 Medmont E300 corneal topographer로 측정한 각막 전면의 지형 data와 Holden-Payor optical pachometer로 측정한 각막 수평 경선의 두께 data를 이용하여 계산 되었다. 정확한 각막 두께를 계산 하기위하여 각막 전면 측정 위치의 곡률반경과 각막의 겉보기 두께로부터 각막의 실제 두께를 계산 할 때 정확한 방정식을 이용하였으며, 이는 선행 연구와 구별되는 점이다. 그리고 각막 전면과 후면의 지형은 각막 전면의 지형 data와 계산된 각막 후면의 좌표를 best fit 알고리즘을 이용하여 계산 되었다. 각막 후면의 지형 측정의 신뢰도는 10개의 polymethyl methacrylate(PMMA) lens와 성인 5명의 각막을 측정 하여 평가 하였다. 결과: 10개의 PMMA lens를 이용한 평가에서는 후면 정점 곡률과 후면 Q의 mean absolute accuracy(${\pm}SD$)는 각각 $0.053{\pm}0.044mm$(95% 신뢰구간(CI) -0.033~0.139)와 $0.10{\pm}0.10$(95% CI -0.10~0.31)이였다. 그리고 5명의 각막을 이용한 평가에서의 각막 후면 정점 곡률과 후면 Q의 mean absolute repeatability coefficient(${\pm}SD$)는 각각 $0.07{\pm}0.06mm$(95% CI -0.05~0.19)와 $0.09{\pm}0.07$(95% CI -0.05~0.23) 이였다. 결론: 새로운 방법을 이용하여 신뢰할 수 있는 각막 후면의 지형(정점 곡률과 Q)을 계산 할 수 있었다. 이러한 새로운 방법은 살아있는 인체 각막의 정확한 후면 지형 계산에 적용 될 수 있다.

악교정수술환자에서 폴리메틸메터크릴레이트(아테콜$^{(R)}$) 주입을 통한 융비술 (PMMA MICROSPHERES (ARTECOLL$^{(R)}$) INJECTION FOR NASAL RIDGE AUGMENTATION IN THE ORTHOGNATHIC SURGERY)

  • 옥용주;김명진;팽준영;명훈;황순정;최진영;이종호;정필훈
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • 제31권4호
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    • pp.329-334
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    • 2005
  • Polymethyl-methacrylate(PMMA; Artecoll$^{(R)}$) microspheres suspended 1 : 3 in a 3.5% collagen solution has been used as an injectable implant for long lasting correction of wrinkles and minor skin defects. The patients with mandibular prognathism have increased necessity for nasal augmentation. Usually these patients usually get an additional rhinoplasty after orthognathic surgery. The purpose of this study is to evaluate the result of PMMA injection for nasal ridge augmentation simultaneously with the orthognathic surgery. PMMAs were injected to the nasal dorsum of 13 patients with mandibular prognathism to augment the nasal ridge at the end of the orthognathic surgery. The cephalometric X-ray and clinical facial photograph were taken at 2, 4 and 6 months after operation. Using S-N line, we calculated the change of soft tisuue on the nasal ridge and also investigated the degree of patients satisfaction at 6 months after operation. Most of the patients were satisfied with their nasal ridge height status from moderate to good degree. The average amount of nasal ridge augmentation was $1.4{\pm}0.5$ mm immediately after operation, $1.2{\pm}0.4$ mm at 2 months after operation. The postoperative nasal ridge height seemed to be remained stable after 2 months. Intraoperative PMMA injection is considered to be simple and effective technique which can be used for the minor augmentation of nasal ridge in the orthognathic patients.

Application of a newly developed software program for image quality assessment in cone-beam computed tomography

  • de Oliveira, Marcus Vinicius Linhares;Santos, Antonio Carvalho;Paulo, Graciano;Campos, Paulo Sergio Flores;Santos, Joana
    • Imaging Science in Dentistry
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    • 제47권2호
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    • pp.75-86
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    • 2017
  • Purpose: The purpose of this study was to apply a newly developed free software program, at low cost and with minimal time, to evaluate the quality of dental and maxillofacial cone-beam computed tomography (CBCT) images. Materials and Methods: A polymethyl methacrylate (PMMA) phantom, CQP-IFBA, was scanned in 3 CBCT units with 7 protocols. A macro program was developed, using the free software ImageJ, to automatically evaluate the image quality parameters. The image quality evaluation was based on 8 parameters: uniformity, the signal-to-noise ratio (SNR), noise, the contrast-to-noise ratio (CNR), spatial resolution, the artifact index, geometric accuracy, and low-contrast resolution. Results: The image uniformity and noise depended on the protocol that was applied. Regarding the CNR, high-density structures were more sensitive to the effect of scanning parameters. There were no significant differences between SNR and CNR in centered and peripheral objects. The geometric accuracy assessment showed that all the distance measurements were lower than the real values. Low-contrast resolution was influenced by the scanning parameters, and the 1-mm rod present in the phantom was not depicted in any of the 3 CBCT units. Smaller voxel sizes presented higher spatial resolution. There were no significant differences among the protocols regarding artifact presence. Conclusion: This software package provided a fast, low-cost, and feasible method for the evaluation of image quality parameters in CBCT.

APPLICATION OF A DUAL-ENERGY MONOCHROMATIC XRAY CT ALGORITHM TO POLYCHROMATIC X-RAY CT: A FEASIBILITY STUDY

  • Chang, S.;Lee, H.K.;Cho, G.
    • Nuclear Engineering and Technology
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    • 제44권1호
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    • pp.61-70
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    • 2012
  • In this study, a simple post-reconstruction dual-energy computed tomography (CT) method is proposed. A dual-energy CT algorithm for monochromatic x-rays was adopted and applied to the dual-energy CT of polychromatic x-rays by assigning a representative mono-energy. The accuracy of algorithm implementation was tested with mathematical phantoms. To test the sensitivity of this algorithm to the inaccuracy of representative energy value in energy values, a simulation study was performed with mathematical phantom. To represent a polychromatic x-ray energy spectrum with a single-energy, mean energy and equivalent energy were used, and the results were compared. The feasibility of the proposed method was experimentally tested with two different micro-CTs and a test phantom made of polymethyl methacrylate (PMMA), water, and graphite. The dual-energy calculations were carried out with CT images of all possible energy pairs among 40, 50, 60, 70, and 80 kVp. The effective atomic number and the electron density values obtained from the proposed method were compared with theoretical values. The results showed that, except the errors in the effective atomic number of graphite, most of the errors were less than 10 % for both CT scanners, and for the combination of 60 kVp and 70 kVp, errors less than 6.0 % could be achieved with a Polaris 90 CT. The proposed method shows simplicity of calibration, demonstrating its practicality and feasibility for use with a general polychromatic CT.

백라이트 유닛용 V-그루브 도광판의 전산모사 및 DSF성형에 관한 비교연구 (A Study on the Simulation and DSF Molding of V-groove Type Light Guide for a Backlight Unit)

  • 조광환;윤경환
    • 소성∙가공
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    • 제14권3호
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    • pp.282-290
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    • 2005
  • Nowadays, TFT-LCD is widely used as display unit of many digital devices. And, the backlight unit(BLU) is used as a light source of TFT-LCD module. In the backlight unit, the most important component is a light guide, which guides the input light to the TFT-LCD module uniformly. Recently, many researchers have focused on improving the efficiency of BLU by changing the design and structure of a light guide. In the present paper, a series of simulation was performed to find the optimal luminance distribution of emanated light from the given geometry as the first step. From the results of simulations for the light guide with given V-groove pattern, the emanated light from it is mostly affected by the groove angle. In the case of acute angle, about 74 degrees was found as optimal angle to satisfy the restrictions of angular luminance distribution, FWHM, the maximum luminance, etc. However, as far as the average luminance value was concerned, the case of 120 degrees(abtuse angle) was found to be the best while prism films were added to the BLU. As a next step the light guide samples of 74 and 120 degrees were manufactured by DSF method, which was recently proposed by the authors. Of course, most of design parameters were chosen by the aid of simulation results. Finally, the results of average luminance values were compared between the simulation and DSF molded samples.

극청정 가스필터용 다공성 니켈 멤브레인의 제조 (Fabrication of porous nickel membrane for high precision gas filter)

  • 송한복;양재교;성기훈;서동문;강두홍;좌용호
    • 한국결정성장학회지
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    • 제17권5호
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    • pp.210-216
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    • 2007
  • 극청정 가스필터용 다공성 멤브레인을 제조하기 위해 금속산화물 분말의 in-situ한 환원/소결 공정을 이용하였다. 또한 기공도의 향상을 위해 solid pore forming agent로써 구형의 폴리머 입자를 첨가하여 금속 섬유를 사용한 멤브레인과 비슷한 52%의 기공도를 가지는 니켈 멤브레인을 제조하였다. 제조된 니켈 멤브레인은 폴리머의 첨가에 따라 평균기공크기와 기공도가 증가하였다. 한편 환원/소결 온도가 $800^{\circ}C$에서 $1000^{\circ}C$로 상승함에 따라 평균기공크기와 기공도는 감소하였다. 이는 환원/소결 온도가 상승함에 따라 격자확산 및 입계확산이 진행되어 멤브레인의 수축률 증가를 일으켰기 때문이다.

폴리머 콘크리트의 압축 및 휨강도 발현 특성 (Compressive and Flexural Strength Development Characteristics of Polymer Concrete)

  • 김남길;연규석
    • 한국농공학회논문집
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    • 제60권1호
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    • pp.101-110
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    • 2018
  • This study experimentally investigated the compressive and flexyral strength development characteristics of polymer concrete using four different type polymeric resins such as unsaturated polyester, vinyl ester, epoxy, and PMMA (polymethyl methacrylate) as binders. The test results show that the average compressive strength of those four different polymer concretes was 88.70 MPa, the average flexural strength was 20.30 MPa. Those test results show that compressive and flexural strengths of polymer concrete were much stronger than compressive and flexural strengths of ordinary Portland cement concrete. In addition, the relative gains of the compressive strength development at the age of 24 hrs compared to the age of 168 hrs were 68.6~88.3 %. Also, the relative gains of the flexural strength development at the age of 24 hrs compared to the age of 168 hrs were 73.8~93.4 %. These test results show that compressive and flexural strengths of each polymer concrete tested in this study were developed at the early age. Moreover, the prediction equations of compressive and flexural strength developments regarding the age were determined. The determined prediction equations could be applied to forecast the compressive and flexural strength developments of polymer concrete investigated in this study because those prediction equations have the high coefficients of correlation. Last, the relations between the compressive strength and the flexural strength of polymer concrete were determined and the flexural/compressive strength ratios were from 1/4 to 1/5. These results show that polymer concretes investigated in this study were appropriate as a flexural member of a concrete structure because the flexural/compressive strength ratios of polymer concrete were much higher than the flexural/compressive strength ratios of Portland cement concrete.