• Structural Engineering and Mechanics
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• 제72권6호
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• pp.713-722
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• 2019

Micromechanics is a technique for the analysis of composites or heterogeneous materials which focuses on the components of the intended structure. Each one of the components can exhibit isotropic behavior, but the microstructure characteristics of the heterogeneous material result in the anisotropic behavior of the structure. In this research, the general mechanical properties of a 3D anisotropic and heterogeneous Representative Volume Element (RVE), have been determined by applying periodic boundary conditions (PBCs), using the Asymptotic Homogenization Theory (AHT) and strain energy. In order to use the homogenization theory and apply the periodic boundary conditions, the ABAQUS scripting interface (ASI) has been used along with the Python programming language. The results have been compared with those of the Homogeneous Boundary Conditions method, which leads to an overestimation of the effective mechanical properties. According to the results, applying homogenous boundary conditions results in a 33% and 13% increase in the shear moduli G₂₃ and G₁₂, respectively. In polymeric composites, the fibers have linear and brittle behavior, while the resin exhibits a non-linear behavior. Therefore, the nonlinear effects of resin on the mechanical properties of the composite material is studied using a user-defined subroutine in Fortran (USDFLD). The non-linear shear stress-strain behavior of unidirectional composite laminates has been obtained. Results indicate that at arbitrary constant stress as 80 MPa in-plane shear modulus, G₁₂, experienced a 47%, 41% and 31% reduction at the fiber volume fraction of 30%, 50% and 70%, compared to the linear assumption. The results of this study are in good agreement with the analytical and experimental results available in the literature.

• 대한치과보철학회지
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• 제38권6호
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• pp.782-790
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• 2000

The mainly used polymeric material for the denture is PMMA because of its cost and easiness to handle. So it was widely used material among dentists for past decades. But the acrylic-based denture materials have several common weak points such as shrinkage after curing and lack of strength. In order to solve these problems, we adapted one of hybrid system using acrylic polymer and vinyloligosilsesquioxane(POSS). POSS, which is a well known expandable monomer during polymerization process, may eventually suppress volumetric shrinkage. And the hybrid system makes it possible for the polymer to be stable in various severe conditions. Eight different kinds of samples were designed and synthesized. Each samples were characterized with dynamic mechanical analyser(DMA) to confirm their thermodynamic properties, fractured to analyze the cross-sectional morphology of the samples. And elongation, flexural and impact tests were also executed to evaluate the mechanical properties of the samples. From the results, hybrid composites had well defined crosslinked network structure compared to the widely used denture materials, and the mechanical strength improved without changing any surface condition as increment with POSS ratio in hybrid system. Fractured morphology showed homogeneous surfaces in spite of mutli component system, therefore we can conclude that the adoption of the POSS brought the reinforcement of the denture resin.

• Tribology and Lubricants
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• 제30권6호
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• pp.343-349
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• 2014

Currently, in order to resist the scratching of the fuel rod surface while fabricating the fuel assembly of the light-water nuclear reactor, we use a solution of nitrocellulose, an explosive material, as a dry lubricant along with its solvent. However, the demand for developing safe and harmless aqueous alternative materials for environment-conservation and field-worker safety has increased. In this study, we demonstrate the preparation of a novel aqueous resin composite using a formulation of aqueous polymeric resin, alcoholic solvent, and water. Subsequently, we characterize this composite on the basis of hardness, adhesive property, and water solubility using plates similar to the fuel rod material. The insertion test of a fuel rod coated with the YS-3 composite shows load values of $18.8-20.5kg/cm^2$, which is comparable with $18.8-20.5kg/cm^2$ of the nitrocellulose coating agent. In addition, the depth and width of longitudinal scratches caused by the YS-3 composite test are 50% higher than those of the standard. We can develop a harmless and safe aqueous dry lubricant to replace the existing NC products through field testing of 264 pieces of fuel rods, after producing 350 kg of the YS-3 prototype. The scratch test for the rod surface showed that weight of chip of YS-3 prototype was smaller than that of NC before and after solvent treatment, indicating the properties of YS-3 prototype was comparable to the counterpart.

• Elastomers and Composites
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• 제47권1호
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• pp.2-8
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• 2012

본 연구에서는 식물성 오일로부터 여러 가지 기능기를 가진 soybean resin(AESO, MAESO)을 제조하였으며, nanoclay를 사용하여 새로운 고기능성 바이오-나노 복합 재료를 개발하였다. 또한 제조된 soybean resin을 바인더로 이용하여 $TiO_2$ 광전극을 제조하고 친환경 염료감응형 태양전지를 개발하다. 제조된 나노복합재료의 형태는 고분자의 삽입에 의해 층간 간격이 증가된 형태와 박리된 형태를 조절하였으며 나노 클레이 함량이 증가됨에 따라 물리적 성질이 증가하였다. 또한 COOH기가 첨가된 MAESO에서 분산도가 향상되었고 초음파 처리에 의해 분산도가 더욱 향상되어 물리적 특성이 현저히 향상되었다. 또한 $TiO_2$를 질산처리 한 후 soybean resin을 바인더로 이용하여 나노 다공성 $TiO_2$ 광전극을 제조하였으며 염료를 흡착시킨 후 염료감응형 태양전지를 제조하였다. AESO와 MAESO를 바인더로 제조한 $TiO_2$ 광전극에서는 향상된 분산성과 표면적 증가로 인해 염료 흡착량이 증가하였다. 이로 인해 높은 전류밀도를 나타내었으며, 첨가된 기능기의 영향으로 $TiO_2$ 계면의 저항이 낮아져 매우 좋은 광전기화학적 특성과 높은 효율을 나타내었다.

• 한국건설순환자원학회논문집
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• 제9권4호
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• pp.433-442
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• 2021

이 연구에서는 폴리머 결합재(불포화 폴리에스터 수지), 플라이 애시, 그리고 순환굵은골재(60%)와 부순굵은골재(40%)를 사용하여 폴리머 결합재 함량의 변화에 따른 무세골재 폴리머 콘크리트의 성질(9개항)에 대하여 연구하였다. 폴리머 결합재 함량(4.0-6.0wt.%)을 실험 변수로 한 이유는 비용측면에서 가장 큰 비중을 차지할 뿐만 아니라 각종 성능에 미치는 영향이 크기 때문이다. 연구결과 밀도, 압축강도, 휨강도, 동결융해 후 휨강도는 폴리머 결합재 함량이 증가함에 따라 증가하였고, 흡수율, 공극률, 연속공극률, 투수계수, 내산성(산에 의한 밀도 감소율)은 폴리머 결합재 함량이 증가함에 따라 감소하였다. 특히 폴리머 결합재 함량 6wt.%에서는 공극률이 18.4%, 투수계수가 7.3mm/sec 임에도 압축강도는 38.0MPa, 휨강도는 10.0MPa로서 기존의 연구결과들에 비해 월등히 높고, 흡수율, 내산성 등 다른 성질들도 우수한 것으로 나타났다. 이러한 결과는 가교제의 첨가에 의해 높아진 결합재의 부착력과 폴리머 결합재가 가진 표면 소수성에 기인하는 것이라고 하겠다.

• Tribology and Lubricants
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• 제14권4호
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• pp.72-78
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• 1998

In this work, the effects of binder materials on the tribological behavior were experimentally evaluated for air curable MoS$_2$bonded film lubricants. The binders tested were basically alkyd and acryl based resins, and also were modified by nitro-cellulose in various weight percentages. Effects on the binder ratio to solid lubricants and the molecular weight of binders were also investigated in all aspects of the tribological behavior. For the tests, LFW-1 and Falex tester were used to measure mainly the endurance life and load carrying capacity of bonded lubricants. Results showed that lubricants of methacrylic resin has the better performance than those of other resins, and also the properties of lubricants both of alkyd and acrylic resins could be improved by modification with nitro-cellulose. It was also shown that the optimum ratio of nitro-cellulose related closely to the binder material and the testing machine.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.129-129
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• 2006

Conventional solvent-based polyurethane (PU) is well established for wide applications, such as textile treatments, surface coating, adhesive and so on. Due to the demands of safety, economic, and environmental protection, the solvent-based PU is restricted and has been phasing out and aqueous-based PU is becoming the world market trend, which is an environmental friendly product. The chemical resistance, physical and mechanical properties of aqueous-based PU are still not competible with solvent-based PU. Because of aqueous-based PU is a linear thermoplastic polymer with lower average molecular weight. Their improvements are normally performed by a post-curing reaction or a polymer hybridization to enhance the polymer cross-linking density. Hybridization of PU with aqueous-based epoxy resin or acrylate emulsion and then cured by a curing agent for improving the performance properties and reducing the cost of aqueous-based PU.Furthermore, a special function is added to aqueous-based PU increasing the application value, for examples, flame retardation, polymeric dyes, hydrophilic and etc.

• 한국철도학회논문집
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• 제9권1호
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• pp.57-62
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• 2006

Composite thin-walled members for civil engineering application are mainly produced by pultrusion technique, and they are generally made of a polymeric resin system reinforced by E-glass fibers due to economical reason. This material combination results in low elastic moduli of the composite materials and makes the design of composite members to be governed by stability limit state. Therefore the buckling behavior of composite thin-walled members was experimentally investigated in the present study. Axial compression was applied on each specimens by a hydraulic ram and knife edge fixtures were placed at both ends to simulate simple boundary condition. Axial compression, lateral displacements and twisting at the mid-height of each specimen were measured by a set of transducers during buckling test. The experimental buckling loads were compared with analytical results obtained through isotropic formulas. In the calculation of analytical results, elastic properties such as Young's modulus(E) and shear modulus(G) were replaced with EL and GLT obtained from coupon tests, respectively.

• Carbon letters
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• 제8권2호
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• pp.134-136
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• 2007

In this work, activated carbons (ACs) were prepared from polystyrene-based cation-exchangeable resin (PSI) by a chemical activation with KOH as an activating agent. The surface morphologies were observed by using SEM, and the textural properties were investigated by using nitrogen adsorption at 77 K. From the experimental results, it was found that the well-developed micro- and mesopores were produced by a chemical activation, and the textural properties including specific surface areas and pore volumes were greatly enhanced. The electrochemical behaviors of the ACs showed similar phenomena with that of textural properties. These results indicated that KOH activation played an important role in the changes of surface, and pore structures, resulting in enhancing the electrochemical properties of the ACs prepared in present work.

• International Journal of Automotive Technology
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• 제6권5호
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• pp.507-511
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• 2005

Recently, many solution have been suggested to development of plastic products. Among many manufacturing technologies for plastic parts, the injection molding process is very attractive because of its low production cost and short cycle time. In this paper, the plastic ball seat of a ball joint, one of the essential components for automotive suspension or steering system, was studied to enhance its mechanical performance and durability by using PA66 that is reinforced polymeric plastic resin. But ball seat has some trouble in manufacture process. And strength of molded part is not enough to use. For the quality stabilization and reliability of injection molded parts, we designed the mold cavities through analytical simulation software and tested the mechanical performance for the injection molded ball-seat parts. After modification, tensile strength increases by about $13.5\%$. Strength and quality stabilization is improved.