• Title/Summary/Keyword: Polymeric membrane

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Separators far Li-Ion Secondary Batteries (리튬이온 2차전지용 분리막)

  • Nam Sang Yong;Lee Young Moo;Lee Chang Hyun;Park Ho Bum;Rhim Ji Won;Ha Seong Yong;Kang Jong Seok
    • Membrane Journal
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    • v.14 no.4
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    • pp.263-274
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    • 2004
  • The polymeric membrane, a component of battery devices such as Li-ion battery (LIB) and Li-polymer battery (LPB), is a typical material in which the carrier mobility dominates the battery performance. In this paper, the state-of-the-art of membranes for secondary battery is described in terms of membrane properties. Several prerequisites, which are related to stability of battery devices, are discussed to design and prepare suitable polymeric membranes. In addition, physical requirements of membranes and their measurement methods are described to develop applicable polymeric membranes in membrane preparation processes.

REPONSE OF POLYMERIC MEMBRANES AS SENSING ELEMENTS FOR ELECTRONIC TOUGUE

  • Bae, Y.M.;Cho, S.I.
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2000.11b
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    • pp.219-226
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    • 2000
  • The study was executed for development of sensing elements of electronic tongue which could discriminate taste of liquid and semi-liquid foods. Five polymeric membranes which were composed of polymer, plasticizer, electro-active materials were prepared. After each polymeric membranes were mounted in an electrode body, membrane potentials due to electrochemical reaction with taste stimuli were measured. The experimental results were interpreted in view of the membrane's non-selective responses to stimuli.

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Polymeric Acetate-Selective Electrodes Based on meso-(α,α,α,α)-Tetrakis-[(2-arylphenylurea)phenyl]porphyrins: Electormic and pH Effects

  • Lee, Hyo-Kyoung;Song, Ki-ju;Seo, Hyung-Ran;Jeon, Seung-won
    • Bulletin of the Korean Chemical Society
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    • v.23 no.10
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    • pp.1409-1412
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    • 2002
  • Polymeric membrane electrodes for acetate anion based on meso-(${\alpha}$,${\alpha}$,${\alpha}$,${\alpha}$)-5,10,15,20-tetrakis[2-(penta-fluorophenylurea) phenyl]porphyrin I and similar urea-functionalized porphyrins Ⅱ-Ⅳ as neutral ionophores were prepared. The membrane based on porphyrin I exhibits the best potentiometric properties in pH 6.0 rather than pH 7.0: linear stable response over a wide concentration range (6.0 ${\times}$$10^{-5}$-1.0 ${\times}$$10^{-2}$) with a slope of -59.6 mV/decade and a detection limit of log[CH3CO$O^-$] = -5.32. Selectivity coefficients obtained from the matched potential method (MPM) in pH 6.0 indicate that interferences of hydrophobic anions are very small for the membranes of porphyrins I and II having the strong withdrawing group. The electronic effect of urea-functionalized porphyrins and pH effect of buffer solutions are discussed on the potentiometric response.

Improving hydrophilic and antimicrobial properties of membrane by adding nanoparticles of titanium dioxide and copper oxide

  • Khosroyar, Susan;Arastehnodeh, Ali
    • Membrane and Water Treatment
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    • v.9 no.6
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    • pp.481-487
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    • 2018
  • Membrane clogging or fouling of the membrane caused by organic, inorganic, and biological on the surface is one of the main obstacles to achieve high flux over a long period of the membrane filtration process. So researchers have been many attempts to reduce membrane fouling and found that there is a close relationship between membrane surface hydrophilicity and membrane fouling, such that the same conditions, a greater hydrophilicity were less prone to fouling. Nanotechnology in the past decade is provided numerous opportunities to examine the effects of metal nanoparticles on the both hydrophilic and antibacterial properties of the membrane. In the present study the improvement of hydrophilic and antimicrobial properties of the membrane was evaluated by adding nanoparticles of titanium dioxide and copper oxide. For this purpose, 4% copper oxide and titanium dioxide nanoparticles with a ratio of 0, 30, 50, and 70% of copper oxide added to the polymeric membrane and compare to the pure polymeric membrane. Comparison experiments were performed on E. coli PTCC1998 in two ways disc and tube and also to evaluate membrane hydrophilic by measuring the contact angle and diameter of pores and analysis point SEM has been made. The results show that the membrane-containing nanoparticle has antibacterial properties and its impact by increasing the percentage of copper oxide nanoparticles increases.

Ceramic based Nanofiltration Membrane for Wastewater Treatment: A Review (폐수처리를 위한 세라믹계 나노여과막: 리뷰)

  • Yeonsoo, Kwak;Rajkumar, Patel
    • Membrane Journal
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    • v.32 no.6
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    • pp.390-400
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    • 2022
  • Nanofiltration (NF) membranes are more popular than reverse osmosis (RO) membranes as they can be operated at much lower pressures for applications in treatment of wastewater from industries like food processing and pharmaceutical as well as municipal sewage water. The separation mechanism in case of NF membranes is based on solution diffusion as well as sieving, for which the crosslinking density of the thin film of the composite membrane is less then RO membrane. Unlike ceramic membranes, membrane fouling is one of the chronic problems that occur during the nanofiltration process in polymeric membranes. Membrane cleaning is done to get rid of reversible as well as irreversible fouling by treatment with sodium hypochlorite. Compared to polymeric membranes, ceramic membranes show higher stability against these agents. In this review different types of ceramic membrane applied wastewater treatment by NF process are discussed.

Membrane fouling and sludge characteristics in submerged membrane bioreactor under low temperature

  • Yuan, Yuan;Zhang, Jianqiao
    • Membrane and Water Treatment
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    • v.10 no.5
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    • pp.331-338
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    • 2019
  • This study aimed to investigate the membrane fouling and sludge characteristics in a pilot-scale submerged membrane bioreactor (MBR) operated under low temperature ($7^{\circ}C$). To elucidate the mechanisms of membrane fouling at low temperature, we studied the correlation between MBR performances and physicochemical properties of sludge including extracellular polymeric substance (EPS), relative hydrophobicity (RH) and floc size during long-term operation. The MBR was shown able to remove chemical oxygen demand (COD) stably and efficiently (>90 %) in the case of overgrowth of filamentous bacteria (bulking sludge) at low temperature. On the other hand, the occurrence of filamentous bulking greatly accelerated membrane fouling, as indicated by membrane filtration period of 14 days for filamentous bulking at $7^{\circ}C$, in comparison with that of 27 days for non-bulking sludge at $24^{\circ}C$ The overgrowth of filamentous bacteria resulting from low-temperature condition led to an increased release of EPS, higher RH, smaller floc size and lower fractal dimension of sludge. These factors accelerated the formation of compact cake layer on membrane surface in association with performance diminution in terms of increase in transmembrane pressure (TMP) of the membrane and thus the decrease in membrane permeability.