• Title/Summary/Keyword: Polymeric effect

Search Result 399, Processing Time 0.024 seconds

Evaluation on Fatigue Characteristics of Tire Sidewall Rubber according to Aging Temperature

  • Jun, Namgyu;Moon, Byungwoo;Kim, Yongseok;Koo, Jae-Mean;Seok, Chang-Sung;Hong, Ui Seok;Oh, Min Kyeong;Kim, Seong Rae
    • Elastomers and Composites
    • /
    • v.52 no.3
    • /
    • pp.167-172
    • /
    • 2017
  • Ultra-high performance (UHP) tires, for which demand has recently surged, are subject to severe strain conditions due to the low aspect ratio of their sidewalls. It is important to ensure sidewall material durability, since a sudden tire sidewall breakage during vehicle operation is likely to cause a major accident. In the automotive application of rubber parts, cracking is defined as a failure because when cracks occur, the mechanical properties of rubber change. According to Mars, Andre et al., strain and strain energy density (SED) are mainly used as a failure parameters and the SED is generally used as a fatigue damage parameter. In this study, the fatigue life curves of sidewall rubber of tires were determined by using the SED as fatigue damage parameter while the effect of aging on fatigue life was evaluated after obtaining the SED-Nf curves according to aging condition.

PTC/NTC Behaviors of Nanostructured Carbon Black-filled HDPE Polymer Composites

  • Park, Soo-Jin;Seo, Min-Kang;Lee, Jae-Rock
    • Carbon letters
    • /
    • v.2 no.3_4
    • /
    • pp.159-164
    • /
    • 2001
  • In this study, the effects of carbon black (CB) content and anodic oxidation treatment with $AgNO_3$ on positive temperature coefficient (PTC) behavior of CB/HDPE nanocomposites were investigated. Also, the addition of elastomer as a toughing agent was studied. The 20~50 wt% of CB, 0~5 wtt% of elastomer, and 1 wt% of $AgNO_3$-filled HDPE nanocomposites were prepared using the internal mixer in 60 rpm at $160{\circ}C$ and the compression-molded at $180{\circ}C$ for 10 min. As a result, the room temperature resistivity and PTC intensity of the composites were dependent, to a large extent, on the content of CB, addition of elastomer, and surface chemical properties that were controlled in the relative arrangements of the carbon black aggregates in a polymeric matrix. Moreover, the composites with relatively low room temperature resistivity and suitable PTC intensity could be achieved by treatment of $AgNO_3$. Consequently, it was noted that PTC effect was due to the deagglomeration or the breakage of the conductive networks caused by thermal expansion or crystalline melting of the polymeric matrix.

  • PDF

Cadmium Detoxification Mechanism in Klebsiella aerogenes ATCC 10031 (Klebsiella aerogenes ATCC 10031의 카드뮴 해독기작)

  • 이기성;유순애;곽인영;박영식;최영길
    • Korean Journal of Microbiology
    • /
    • v.28 no.2
    • /
    • pp.134-144
    • /
    • 1990
  • In order to examine that what kind of system correlated with cadmium detoxification mechanism in Klebsiella aerogenes ATCC 10031, we tried to investigate the effect of phosphate upon the detoxification and also elucidate whether the cadmium phosphate and/or polymeric Cd-Pi complex is formed actually in cell or not. As the results, it was shown that growing pattern had long lag adaptive phase of 12 hr to 24 hr, at the concentrations of 0.02 mM and 0.08 mM cadmium, respectively. Cadmium was accumulated more highly in the fraction of cell wall and membrane than in those of cytoplasm. In case of phosphate starving cells added cadmium, inorganic polyphosphate system was primarily correlated with Cd-detoxification during the lag phase for the accommodation to cadmium, on the other hand, Cd:Sulfide complex system secondarily correlated it during the stationary phase. These results implied that polyphosphate system and Cd:sulfide complex system, these two systems were operated compensatively each other. Considering the results obsdrved with EM and examined tha changes of sulfide and polyphosphate amount, it was reflected that Cd:S complex was located at the cell surface. In the results of $in-vivo^{31}$P NMR spectra in the cells with cadmium pressure, several phosphate signals arose newly from the polyphosphate region with moving chemical shift of it. This phinomenon strongly implied the actual existence of Dd:Pi comples and /or Cd:poly-P complex in the cell and also the cellular compartmentalization of cadmium detoxifying mechanism.

  • PDF

Dynamic load concentration caused by a break in a Lamina with viscoelastic matrix

  • Reza, Arash;Sedighi, Hamid M.;Soleimani, Mahdi
    • Steel and Composite Structures
    • /
    • v.18 no.6
    • /
    • pp.1465-1478
    • /
    • 2015
  • The effect of cutting off fibers on transient load in a polymeric matrix composite lamina was studied in this paper. The behavior of fibers was considered to be linear elastic and the matrix behavior was considered to be linear viscoelastic. To model the viscoelastic behavior of matrix, a three parameter solid model was employed. To conduct this research, finite difference method was used. The governing equations were obtained using Shear-lag theory and were solved using boundary and initial conditions before and after the development of break. Using finite difference method, the governing integro-differential equations were developed and normal stress in the fibers is obtained. Particular attention is paid the dynamic overshoot resulting when the fibers are suddenly broken. Results show that considering viscoelastic properties of matrix causes a decrease in dynamic load concentration factor and an increase in static load concentration factor. Also with increases the number of broken fibers, trend of increasing load concentration factor decreases gradually. Furthermore, the overshoot of load in fibers adjacent to the break in a polymeric matrix with high transient time is lower than a matrix with lower transient time, but the load concentration factor in the matrix with high transient time is lower.

Effects of Fabrication Variables and Microstructures on the Compressive Strength of Open Cell Ceramics (개방셀 세라믹스의 압축강도에 대한 제조공정변수 및 미세구조의 영향)

  • 정한남;현상훈
    • Journal of the Korean Ceramic Society
    • /
    • v.36 no.9
    • /
    • pp.954-964
    • /
    • 1999
  • The effect of fabrication variables and microstructures on the compressive strength of open cell alumina zirconia and silicon nitride ceramics fabricated by polymeric sponge method was investigated. Bulk density and compressive strength of open cell ceramics were mainly affected by coating characteristics of ceramic slurry on polymeric sponge that controlled a shape thickness and defect of the struts. Sintering temperature was optimized for enhancement of strut strength and compressive strength of open cell ceramics. Relative density and compressive strength behaviors were relatively well matched with the predicted values. Open cell ceramics of lower relative density below 0.1 prepared by first relatively well matched with the predicted values. Open cell ceramics of lower relative density below 0.1 prepared by first coating of ceramic slurry had thin triangular prismatic struts that were often broken or longitudinally cracked. With an application of second coating of slurry shape of struts was transformed into thickner cylindrical one and defects in struts were healed but the relative density increased over 0.2 Open cell zirconia had both the highest bulk density and compressive strength and alumina had the lowest compressive strength while silicon nitrides showed relatively high compressive strength and the lowest density. Based upon the analysis open cell silicon nitride was expected to be one of potential structural ceramics with light weight.

  • PDF

Feasibility Study of the Damage Monitoring for Composite Materials by the Piezoelectric Method (압전기법을 이용한 복합재료 손상모니터링의 가능성에 관한 연구)

  • Hwang, Hui-Yun
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.32 no.11
    • /
    • pp.918-923
    • /
    • 2008
  • Since crack detection for laminated composites in-service is effective to improve the structural reliability of laminated composites, it have been tried to detect cracks of laminated composites by various nondestructive methods. An electric potential method is one of the widely used approaches for detection of cracks for carbon fiber composites, since the electric potential method adopts the electric conductive carbon fibers as reinforcements and sensors and the adoption of carbon fibers as sensors does not bring strength reduction induced by embedding sensors into the structures such as optical fibers. However, the application of the electric method is limited only to electrically conductive composite materials. Recently, a piezoelectric method using piezoelectric characteristics of epoxy adhesives has been successfully developed for the adhesive joints because it can monitor continuously the damage of adhesively bonded structures without producing any defects. Polymeric materials for the matrix of composite materials have piezoelectric characteristics similarly to adhesive materials, and the fracture of composite materials should lead to the fracture of polymeric matrix. Therefore, it seems to be valid that the piezoelectric method can be applied to monitoring the damage of composite materials. In this research, therefore, the feasibility study of the damage monitoring for composite materials by piezoelectric method was conducted. Using carbon fiber epoxy composite and glass fiber composite, charge output signals were measured and analyzed during the static and fatigue tests, and the effect of fiber materials on the damage monitoring of composite materials by the piezoelectric method was investigated.

Ballistic impact analyses of triangular corrugated plates filled with foam core

  • Panigrahi, S.K.;Das, Kallola
    • Advances in Computational Design
    • /
    • v.1 no.2
    • /
    • pp.139-154
    • /
    • 2016
  • The usage of sandwich structure is extensively increasing in lightweight protective structures due to its low density and other useful properties. Sandwich panels made of metal sheets with unfilled cellular cores are found to exhibit lower deflections by comparing to an equivalent monolithic plate of same metal and similar mass per unit density. However, the process of localized impact on solid structures involving plastic deformation, high strain rates, temperature effect, material erosion, etc. does not hold effectively as that of monolithic plate. In present work, the applications of the sandwich plate with corrugated core have been extended to develop optimized lightweight armour using foam as medium of its core by explicit finite element analysis (FEA). The mechanisms of hardened steel projectile penetration of aluminum corrugated sandwich panels filled with foams have been numerically investigated by finite element analysis (FEA). A comparative study is done for the triangular corrugated sandwich plate filled with polymeric foam and metallic foam with different densities in order to achieve the optimum penetration resistance to ballistic impact. Corrugated sandwich plates filled with metallic foams are found to be superior when compared to the polymeric one. The optimized results are then compared with that of equivalent solid and unfilled cores structure to observe the effectiveness of foam-filled corrugated sandwich plate which provides an effective resistance to ballistic response. The novel structure can be the alternative to solid aluminum plate in the applications of light weight protection system.

Relation between sludge properties and filterability in MBR: Under infinite SRT

  • Zhang, Haifeng;Wang, Bing;Yu, Haihuan;Zhang, Lanhe;Song, Lianfa
    • Membrane and Water Treatment
    • /
    • v.6 no.6
    • /
    • pp.501-512
    • /
    • 2015
  • A laboratory-scale submerged membrane bioreactor (MBR) was continuously operated for 100 d at an infinite sludge retention time (SRT) with the aim of identifying possible relation between the filterability of mixed liquor and sludge properties, such as extracellular polymeric substances (EPS), soluble microbial products (SMP), viscosity of mixed liquor, zeta potential of flocs and particle size distributions (PSD). Research results confirmed that MBR can operate with a complete sludge retention ensuring good treatment performances for COD and $NH_3-N$. However, the long term operation (about 40 d) of MBR with no sludge discharge had a negative influence on sludge filterability, and an increase in membrane fouling rates with the time was observed. There as a strong correlation between the sludge filterability and the fouling rate. Among the different sludge properties parameters, the concentration SMP and EPS had a more closely correlation with the sludge filterability. The concentrations of SMP, especially SMP with MW above 10 kDa, had a strong direct correlation to the filterability of mixed sludge. The protein fractions in EPS were biodegradable and available for microorganism metabolism after about 60 days, and the carbohydrates in EPS had a significantly negative effect on sludge filterability in MBR at an infinite SRT.

Property Enhancement of SiR-EPDM Blend Using Electron Beam Irradiation

  • Deepalaxmi, R.;Rajini, V.
    • Journal of Electrical Engineering and Technology
    • /
    • v.9 no.3
    • /
    • pp.984-990
    • /
    • 2014
  • Polymers are the most commonly used di-electrics because of their reliability, availability, ease of fabrication and cost. The commercial and industrial demand for advanced polymeric materials which are capable of being used in harsh environment is need of the hour. The study of the effect of electron beam irradiation on polymeric materials is an area of rapidly increasing interest. This paper discusses the resultant beneficial effects of electron beam irradiation on the SiR-EPDM blend having 50:50 composition. The changes in mechanical and electrical properties of SiR-EPDM blend which are exposed to three different doses of electron beam radiation namely 5 Mrad, 15 Mrad and 25 Mrad are presented. The irradiated blends are analyzed for their electro-mechanical and physico chemical properties. The electrical changes induced by irradiation are investigated by arc resistance, surface resistivity and volume resistivity measurements as per ASTM standards. The mechanical changes are observed by the measurement of tensile strength and elongation at break. Physico chemical investigation has been done using the FTIR, in order to investigate the irradiation induced chemical changes.

Effects of Organic Passivation Layers by Vapor Deposition Polymerization(VDP) for Organic Thin-Film Transistors(OTFTs) (Vapor Deposition Polymerization(VDP)을 이용한 페시베이션이 유기박막트렌지스터에 주는 영향)

  • Park, Il-Houng;Hyung, Gun-Woo;Choi, Hak-Bum;Kim, Jae-Hyeuk;Kim, Woo-Young;Kim, Young-Kwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2007.06a
    • /
    • pp.114-115
    • /
    • 2007
  • In this paper, it was demonstrated that organic thin-film transistors (OTFTs) were fabricated with the organic passivation layer by vapor deposition polymerization (VDP) processing, In order to form polymeric film as an passivation layer, VDP process was also introduced instead of spin-coating process, where polymeric film was co-deposited by high-vacuum thermal evaporation from 6FDA and ODA followed by curing, Field effect mobility, threshold voltage, and on-off current ratio with 450-nm-thick organic passivation layer were about $0.21\;cm^2/Vs$, IV, and $1\;{\times}\;10^5$, respectively.

  • PDF