• Journal of Ocean Engineering and Technology
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• v.9 no.2
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• pp.133-140
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• 1995

This paper deals with the residual strength characteristics of composite materials under the environment of high temperature and humidity. Two types of GFRP, one with unidirection and randomly oriented, are used to investigate the features of moisture absorption and the residual strength. The results show that, when exposed longterms in high temperature and humidity, the randomly oriented composites is more stable than the unidirection one.

• Journal of Ocean Engineering and Technology
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• v.10 no.3
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• pp.34-43
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• 1996

In this study basic equations of fiber orientations is cimpared with experimental results. It is found that fiber orientations of short fiber reinforced polymeric composite under compression molding are governed by slope of flow speed in x-y direction. Fiber orientation angle of mold is also found to increase with closure speed and the compression ratio. At the middle of the mold, the slope of flow speed is larger in x-direction than in y-direction. At the wall of the mold, the shope of flow speed in y-direction occurs due to the effect of friction, hence affects the fiber orientation. The effect of partial flow, which incurs y-direction orientation causes to increase the fiber orientation angle at the fore part of the flow.

• Carbon letters
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• v.1 no.1
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• pp.1-5
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• 2000

The effect of surface free energy on the positive temperature coefficient (PTC) of carbon black/thermoplastic resin composites was investigated. The thermoplastic resins such as EVA, LDPE, LLDPE and HDPE were used with the addition of 30 wt.% of the carbon black. The surface free energy of the composites was studied in the context of two-liquid contact angle measurements, i.e., deionized water and diiodomethane. It was observed that the resistivity on PTC composites Was greatly increased near the crystalline melting temperature, due to the thermal expansion of polymeric matrix. From the experimental results, it was proposed that the decrease of surface free energy induced by interactions between carbon black surfaces and polymer chains is an important factor to the fabrication of a PTC composite made of carbon black and polymeric matrix.

• Proceedings of the Safety Management and Science Conference
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• 2004.05a
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• pp.219-231
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• 2004

The Charpy and Izod impact tests are the most prevalent techniques used to characterize the effects of high impulse loads on polymeric materials. An analysis method for rubber toughened PVC is suggested to evaluated critical dynamic strain energy release rates(G$_c$) from the Charpy impact tester was used to extract ancillary information concerning fracture parameters in additional to total fracture energies and maximum critical loads. The dynamic stress intensity factor KID was computed for varying amounts of rubber contents from the obtain maximum critical loads and also toughening effects were investigated as well. The fracture surfaces produced under low velocity impact for PVC/MBS composites were investigated by SEM. The results show that MBS rubber is very effective reinforcement material for toughening PVC.

• Computers and Concrete
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• v.19 no.6
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• pp.677-687
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• 2017

The nonlinear buckling response of nano composite anti-symmetric functionally graded polymeric microplate reinforced by single-walled carbon nanotubes (SWCNTs) rested on orthotropic elastomeric foundation with temperature dependent properties is investigated. For the carbon-nanotube reinforced composite (CNTRC) microplate, a uniform distribution (UD) and four types of functionally graded (FG) distribution are considered. Based on orthotropic Mindlin plate theory, von Karman geometric nonlinearity and Hamilton's principle, the governing equations are derived. Generalized differential quadrature method (GDQM) is employed to calculate the non-linear buckling response of the plate. Effects of FG distribution type, elastomeric foundation, aspect ratio (thickness to width ratio), boundary condition, orientation of foundation orthotropy and temperature are considered. The results are validated. It is found that the critical buckling load without elastic medium is significantly lower than considering Winkler and Pasternak medium.

• Steel and Composite Structures
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• v.19 no.5
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• pp.1259-1277
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• 2015

In this work, a trigonometric refined beam theory for the bending, buckling and free vibration analysis of carbon nanotube-reinforced composite (CNTRC) beams resting on elastic foundation is developed. The significant feature of this model is that, in addition to including the shear deformation effect, it deals with only 3 unknowns as the Timoshenko beam (TBM) without including a shear correction factor. The single-walled carbon nanotubes (SWCNTs) are aligned and distributed in polymeric matrix with different patterns of reinforcement. The material properties of the CNTRC beams are assessed by employing the rule of mixture. To examine accuracy of the present theory, several comparison studies are investigated. Furthermore, the effects of different parameters of the beam on the bending, buckling and free vibration responses of CNTRC beam are discussed.

• Polymer(Korea)
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• v.31 no.6
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• pp.491-496
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• 2007

In the polymeric dental restorative composites, the resin matrix mainly contains 70 wt% 2,2-bis[4-(2-hydroxy-3-methacryloyloxy propoxy) phenyl] propane (Bis-GMA), as a base resin and 30 wt% triethylene glycol dimethacrylate (TEGDMA) as a diluent. Even though the viscosity of the resin matrix is rapidly decreased by adding TEGDMA, addition of TEGDMA to the Bis-GMA results in reduction in the mechanical properties and increase in the curing shrinkage of the dental composite. In order to fabricate dental composite exhibiting excellent properties by reducing TEGDMA content in the resin matrix, in this study, Bis-GMA derivatives, which do not contain hydroxyl groups, were used instead of Bis-GMA. The curing characteristics of Bis-GMA derivatives were similar with those of Bis-GMA, while the former exhibited lower viscosity and water absorption than the latter. Comparing the curing shrinkage of the dental composite containing Bis-GMA derivative with that prepared from Bis-GMA, the reduction in curing shrinkage was about 25%. Dental composites prepared from new resin matrices also exhibited low water uptake and better properties in mechanical strength.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.8
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• pp.3532-3540
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• 2011

In order to improve flux of PTMSP/PDMS dense membrane, PTMSP/PDMS-PEI composite membrane with PEI support was prepared by phase inversion process and dip coating. These membranes were evaluated in terms of the removal of volatile organic compounds such as PCE, TCE, chloroform, 1,1,1-trichloroethane from wastewater by pervaporation. The selectivity and flux of PTMSP/PDMS dense membranes was in the range of 216.2 to 2394.4 and 244.3 to 428.2g/m2h, respectively. And pervaporation property of PTMSP/PDMS-PEI composite membrane was in the range of 215.5 to 2404.2 and 390.4 to 728.6g/m2h, respectively. PTMSP/PDMS-PEI composite membrane has remarkably greater flux than dense membranes with similar selectivity. It was possible for polymeric membranes used in this study to remove PCE selectively which is dissolved small quantity in water among other separable solutes. PTMSP/PDMS-PEI composite membrane showed the best performances among the silicone polymeric membranes, and has better durability and mechanical strength than dense membranes. PTMSP/PDMS-PEI composite membrane should be a useful candidate for the removal of volatile organic compounds dissolved in wastewater.

• Corrosion Science and Technology
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• v.17 no.2
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• pp.74-80
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• 2018

The electronic industries require environmentally-friendly and highly functional materials to enhance the quality of human life. Home appliances require insect repellent steels that work to protect household microwave ovens from incurring damage by insects such as fire ants and cockroaches in tropical regions. Thus, POSCO has developed new types of functional steels, coated with an array of organic-inorganic hybrid composites on the steel surface, to cover panels in microwave ovens and refrigerators. The composite solution uses a fine dispersion of hybrid solution with polymeric resin, inorganic and a pyrethroid additive in aqueous media. The hybrid composite solution coats the steel surface, by using a roll coater and is cured using an induction curing furnace on both the continuous galvanizing line and the electro-galvanizing line. The new steels were evaluated for quality performances, salt spray test for corrosion resistance and biological performance for both insect repellent and antimicrobial activity. The new steels with organic-inorganic composite coating exhibit extraordinarily biological functionalities, for both insect repellent and antimicrobial activities for short and long term tests. The composite-coating solution and experimental results are discussed and suggest that the molecular level dispersion of insecticide on the coating layer is key to biological functional performances.

• Carbon letters
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• v.14 no.1
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• pp.40-44
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• 2013

The bipolar plate is the most important and most costly component of proton exchange membrane fuel cells. The development of a suitable low density bipolar plate is scientifically and technically challenging due to the need to maintain high electrical conductivity and mechanical properties. Here, bipolar plates were developed from different particle sizes of natural and expanded graphite with phenolic resin as a polymeric matrix. It was observed that the particle size of the reinforcement significantly influences the mechanical and electrical properties of a composite bipolar plate. The composite bipolar plate based on expanded graphite gives the desired mechanical and electrical properties as per the US Department of Energy target, with a bulk density of 1.55 $g.cm^{-3}$ as compared to that of ~1.87 $g.cm^{-3}$ for a composite plate based on natural graphite (NG). Although the bulk density of the expanded-graphite-based composite plate is ~20% less than that of the NG-based plate, the I-V performance of the expanded graphite plate is superior to that of the NG plate as a consequence of the higher conductivity. The expanded graphite plate can thus be used as an electromagnetic interference shielding material.