• Title/Summary/Keyword: Polymeric

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Biodegradability and Risk Assessment of Biomass-based Polymeric Materials

  • Han, Song Yi;Park, Chan Woo;Jang, Jae Hyuk;Lee, Seung Hwan
    • Journal of Forest and Environmental Science
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    • v.31 no.4
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    • pp.297-302
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    • 2015
  • With the intention to solve environmental problems caused by synthetic plastics from petroleum resources, biodegradable polyurethane foams and thermosetting moldings were prepared from biomass, such as wood and wheat bran by liquefaction method. Biodegradability of these biomass-based polymeric materials was investigated. In activated sludge, polyurethane foams from liquefied wheat bran and thermosetting molding from phenolated wood were decomposed approximately 14% and 29% for 20 days, respectively. One of the wood fungi, Coriolus versicolor was able to grow without supplemental nutrition, only with distilled water and polyurethane foam as a nutrition source. Risk assessments were also conducted and results showed that estrogenicity, mutagenicity, and carcinogenicity were not observed in the extractives of biomass- based polymeric materials.

Modified membrane with antibacterial properties

  • Aryanti, P.T.P.;Sianipar, M.;Zunita, M.;Wenten, I.G.
    • Membrane and Water Treatment
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    • v.8 no.5
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    • pp.463-481
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    • 2017
  • Bacteria have been considered as a major foulant that initiates the formation of biofilm on the polymeric membrane surface. Some polymeric membranes are naturally antibacterial and have low fouling properties, however, numerous efforts have been devoted to improve their antibacterial performance. These modifications are mostly carried out through blending the membrane with an antibacterial agent or introducing the antibacterial agent on the membrane surface by chemical grafting. Currently, a significant number of researches have reported nanocomposite membrane as a new approach to fabricate an excellent antibacterial membrane. The antibacterial nanoparticles are dispersed homogenously in membrane structure by blending method or coating onto the membrane surface. Aim of the modifications is to prevent the initial attachment of bacteria to membrane surface and kill bacteria when attached on the membrane surface. In this paper, several studies on antibacterial modified membranes, particularly for water treatment, will be reviewed comprehensively. Special attention will be given on polymeric membrane modifications by introducing antibacterial agents through different methods, such as blending, grafting, and coating.

Synthesis of Block Copolymers Composed of Poly(N,N-dimethylamino ethyl methacrylate) and PEG and Formation of Nanoaggregation (Poly(N,N-dimethylamino ethyl methacrylate)와 PEG로 이루어진 블록공중합체 합성 및 나노복합체 형성)

  • 김은정;최호석;이지나;박기동;육순홍
    • Polymer(Korea)
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    • v.24 no.6
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    • pp.854-859
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    • 2000
  • The synthesis of poly(N,N-dimethylamino ethyl methacrylate (DMAEMA)-block-poly(ethylene glycol) (PEG)) copolymer has been carried out and the block copolymer was characterized by FT-IR, DSC, and $^1$H-NMR. The formation of polymeric nanoaggregation was observed in the solution mixture of poly(DMAEMA) -block-PEG copolymer and poly (ethyl acrylamide) (EAAm) due to the intermolecular interaction via hydrogen bond between DMAEMA and poly(EAAm). The formation of polymeric nanoaggregation was observed above critical micelle concentration (CMC).

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Chromatographic Separation of Maltopentaose from Maltooligosaccharides

  • Lee, Jae-Wook;Kwon, Tae-Ouk;Moon, Il-Shik
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.8 no.1
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    • pp.47-53
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    • 2003
  • An experimental study on the chromatographic separation of maltopentaose from a mixture, including glucose, maltose, maltotriose, and maltopentaose, was carried out in a nonionic polymeric sorbent column while varying the operating conditions, such as the solution pH, buffer contents, and isopropyl alcohol (1PA) concentration. Unlike the pH and buffer contents, the IPA concentration had a Significant impact on the single component chromatograms for maltopentaose. The retention times of the maltooligosaccharides with the nonionic polymeric sorbent Sp207 were in the following order: glucose < maltose < maltotriose < maltopentaose. From the experimental binary, ternary, and quaternary chromatograms, gradient chromatographic separation with a changing IPA concentration as a function of time was required to obtain high-purity maltopentaose and reduce the elution time.

Enhanced Behaviors of Ionic-Polymer Metal Composite (IPMC) Actuator Coupled with Polymeric Anion-doped Polypyrrole Thin Film

  • Hong, Chan;Nam, Jae-Do;Tak, Yong-Sug
    • Journal of the Korean Electrochemical Society
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    • v.9 no.4
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    • pp.137-140
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    • 2006
  • In order to overcome the weak actuation and relaxation problems during the deformation of IPMC actuator, polymeric anion (polystyrenesulfonate)-doped polypyrrole(Ppy(PSS)) was electrodeposited onto IPMC actuator. Electrochemical quartz crystal microbalance study showed that hydrated cations were instilled into Ppy(PSS) film and polymeric-anion dopants introduced during polymerization were not expelled. Ppy(PSS)-coated IPMC actuator formed two electrode/electrolyte interfaces, Pt/nafion and Ppy(PSS)/bulk solution, and additive volume expansion phenomena at interfaces induced the large deformation compensating the relaxation of actuation by back diffusion of water.

REPONSE OF POLYMERIC MEMBRANES AS SENSING ELEMENTS FOR ELECTRONIC TOUGUE

  • Bae, Y.M.;Cho, S.I.
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2000.11b
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    • pp.219-226
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    • 2000
  • The study was executed for development of sensing elements of electronic tongue which could discriminate taste of liquid and semi-liquid foods. Five polymeric membranes which were composed of polymer, plasticizer, electro-active materials were prepared. After each polymeric membranes were mounted in an electrode body, membrane potentials due to electrochemical reaction with taste stimuli were measured. The experimental results were interpreted in view of the membrane's non-selective responses to stimuli.

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Heat-resistant Enamel Varinish (내열성 에나멜 바니쉬)

  • Kim, Yang-Kook;Bae, Hun-Jai
    • Applied Chemistry for Engineering
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    • v.4 no.2
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    • pp.264-272
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    • 1993
  • Current research aimed at investigating of heat-resistance of magnet wire to endow miniaturizing electronic equipment with a high efficiency or reliability. Thermal stability of magnet wire has a close relationship with physical properties of polymeric coating that is formed from enamel varnish. Design of heat-resistant enamel varnish and coating technology of varnish solution were briefly described. Some factors which have a thermal effect on wire were discussed through the evaluation method of the wire properties.

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Replication of High Density Patterned Media (고밀도 패턴드 미디어 성형에 관한 연구)

  • Lee, Nam-Seok;Choi, Yong;Kang, Shin-Ill
    • Transactions of the Society of Information Storage Systems
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    • v.1 no.2
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    • pp.192-196
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    • 2005
  • In this paper, we investigated the possibility of replicating patterned media by nano-injection molding process with a metallic nano-stamper. The original nano-master was fabricated by E-beam lithography and ICP etching process. The metallic nano-stamper was fabricated using a nanoimprint lithography and nano-electroforming process. The nano-patterned substrate was replicated using a nano-injection molding process without additional etching process. In nano-injection molding process, since the solidified layer, generated during the polymer filling, deteriorates transcribability of nano patterns by preventing the polymer melt from filling the nano cavities, an injection-mold system was constructed to actively control the stamper surface temperature using MEMS heater and sensors. The replicated polymeric patterns using nano-injection molding process were as small as 50 nm in diameter, 150 nm in pitch, and 50 nm in depth. The replicated polymeric patterns can be applied to high density patterned media.

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Analysis of Response Characteristics for Organic Gas of Polymeric Sensitive Films by Using Q. C. M. (수정진동자에 의한 감응성막의 유기가스 응답특성 분석)

  • 김경철;김정명;장상목;권영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.409-412
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    • 1996
  • In this paper, the response characteristics of organic gases were investigated by using quartz crystal microbalance(Q.C.M) with different polymeric sensitive materials. The new linear parameter was discussed in order to develope gas sensing system using neural network and pattern recognition. We analyzed the response characteristics by the area of resonant frequency shift of quartz crystal, which mean affinities of organic gases for polymeric sensitive firm. The experimental results shows that the parameter made by the area of frequency shift which was linear with injection amount of organic gases has possibility to be used for pattern recognition and neural network. And they have different normalized pattern.

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Electric Field Analysis of Polymeric ZnO Surge Arrester for loading in Electric Traction (전철 탑재형 ZnO 고분자 피뢰기의 전계해석)

  • Lee, U.Y.;Jang, D.U.;Kang, S.H.;Lim, K.J.;Han, S.W.;Cho, H.G.
    • Proceedings of the KIEE Conference
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    • 1999.07e
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    • pp.2293-2295
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    • 1999
  • Polymeric ZnO surge arresters are used to protect the electric traction to limit the overvoltage invading into its inner electrical circuits. We have developed polymeric ZnO surge arresters design and investigated electric field analysis of its by FEM(Finite Element Method).

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