• Title/Summary/Keyword: Polymer nanocomposites

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Preparation and Characterization of Poly(vinyl alcohol)/bentonite Nanocomposites Films with Modified Bentonites (개질된 벤토나이트가 혼입된 폴리비닐알코올/벤토나이트 나노복합 필름의 제조 및 특성분석)

  • Ji, Byung Chul;Yang, Seong Baek;Lee, Jungeon;Park, Jae Min;Han, Myung-Dong;Kim, Ui Ju;Yeum, Jeong Hyun
    • Textile Coloration and Finishing
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    • v.33 no.3
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    • pp.161-167
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    • 2021
  • Polymer nanocomposite is considered a great alternative to solve the limitations that exist in a simple combination material, as well as to produce multifunctional and high-performance results. In this research, PVA/bentonite nanocomposite films were prepared based on the presence or absence of modification of nano-clay(bentonite) a SUPERGEL® product, modification conditions and content, and the structural variation of the prepared PVA/bentonite nanocomposite films were examined. The effect of variations in the internal structure of the nanocomposite on mechanical and thermal properties was investigated. As a result of evaluating the thermal characteristics of the PVA/bentonite nanocomposite film based on the concentration of the modified bentonite, it was verified that the thermal characteristics and stability were improved because of interaction between the polymer and the modified nano-clay.

Flexible Energy Harvester Made of Organic-Inorganic Hybrid Piezoelectric Nanocomposite (유기-무기 하이브리드 압전 나노복합체 기반의 플렉서블 에너지 하베스터 제작 및 발전성능 평가)

  • Kwon, Yu Jeong;Hyeon, Dong Yeol;Park, Kwi-Il
    • Korean Journal of Materials Research
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    • v.29 no.6
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    • pp.371-377
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    • 2019
  • A flexible piezoelectric energy harvester(f-PEH) that converts tiny mechanical and vibrational energy resources into electric signals without any restraints is drawing attention as a self-powered source to operate flexible electronic systems. In particular, the nanocomposites-based f-PEHs fabricated by a simple and low-cost spin-coating method show a mechanically stable and high output performance compared to only piezoelectric polymers or perovskite thin films. Here, the non-piezoelectric polymer matrix of the nanocomposite-based f-PEH is replaced by a P(VDF-TrFE) piezoelectric polymer to improve the output performance generated from the f-PEH. The piezoelectric hybrid nanocomposite is produced by distributing the perovskite PZT nanoparticles inside the piezoelectric elastomer; subsequently, the piezoelectric hybrid material is spin-coated onto a thin metal substrate to achieve a nanocomposite-based f-PEH. A fabricated energy device after a two-step poling process shows a maximum output voltage of 9.4 V and a current of 160 nA under repeated mechanical bending. Finite element analysis(FEA) simulation results support the experimental results.

Improving the mechanical properties of table tennis by adding nanocomposite in its polymer matrix

  • Shuping Xu;Lixin Liang
    • Advances in nano research
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    • v.16 no.4
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    • pp.365-374
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    • 2024
  • This study delves into the significant impact of integrating nanomaterials, specifically carbon and graphene nanoparticles, into the polymer matrix of aluminum alloy 356, utilizing the vortex casting technique, with the aim of improving the mechanical properties of table tennis equipment. Athletes and their coaching teams have long been on a quest for high-performance sports gear, recognizing its pivotal role in unlocking the full potential of players. The dedication of engineers to craft designs, select materials with precision, and uphold stringent testing standards reflects the commitment to meeting the demands of the sporting world. Yet, to remain at the forefront, sports engineering must continually align with contemporary technologies, and nanotechnology has emerged as a transformative force in this regard. This study not only underscores the meticulous efforts in material integration but also highlights the remarkable strides made possible by nanotechnology. Aluminum nanocomposites, particularly, showcase a groundbreaking fusion of exceptional strength and reduced weight, marking a notable achievement in sports equipment innovation. The research outcomes are compelling, revealing a substantial enhancement in the mechanical performance of the sports structures under scrutiny. This promising development hints at a potential paradigm shift in the manufacturing of sports equipment, promising a new era of elevated athlete performance and enhanced safety during the rigors of physical education training. This study stands as a testament to the tangible impact of nanotechnology on the ever-evolving landscape of sports equipment.

Nanocomposites for microelectronic packaging

  • Lee, Sang-Hyeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.99.1-99.1
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    • 2016
  • The materials for an electronic packaging provide diverse important functions including electrical contact to transfer signals from devices, isolation to protect from the environment and a path for heat conduction away from the devices. The packaging materials composed of metals, ceramics, polymers or combinations are crucial to the device operating properly and reliably. The demand of effective charge and heat transfer continuous to be challenge for the high-speed and high-power devices. Nanomaterials including graphene, carbon nanotube and boron nitride, have been designed for the purpose of exploiting the high thermal, electrical and mechanical properties by combining in the matrix of metal or polymer. In addition, considering the inherent electrical and surface properties of graphene, it is expected that graphene would be a good candidate for the surface layer of a template in the electroforming process. In this talk, I will present recent our on-going works in nanomaterials for microelectronic packaging: 1) porous graphene/Cu for heat dissipations, 2) carbon-metal composites for interconnects and 3) nanomaterials-epoxy composites as a thermal interface materials for electronic packaging.

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The Fabrication of polymer-nanoclay composite and electric properties (고분자-세라믹 나노 컴포지트의 제작과 전기적 특성)

  • Noh, Hyun-Ji;Lee, Sung-Gap;Nam, Sung-Pill;Ahn, Byeong-Lib;Won, Woo-Sik;Woo, Hyoung-Gwan;Park, Sang-Man
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.257-258
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    • 2009
  • Nanocomposites of a epoxy resin are synthesized and evaluated the present study investigated. The effect of nanoclay additives on the properties of diglycidyl ether or bisphenol A(DGEBA) epoxy resin. DGEBA was mixed with 3~7 wt% organically modified layered silicate, Cloisite 30B for three hours. The average grain size of the specimens decreased with adding Cloisite 30B. The dielectric constant showed between 3.2 ~ 3.5 and the dielectric loss showed between 3.2 ~ 5.7 % in all specimens.

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Application of Nanotechnology in Food Packaging

  • Rhim, Jong-Whan
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.13 no.1
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    • pp.9-18
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    • 2007
  • Nanocomposite has been considered as an emerging technology in developing a novel food packaging materials. Polymer nanocomposites exhibit markedly improved packaging properties due to their nanometer size dispersion. These improvements include increased barrier properties pertaining to gases such as oxygen, carbon dioxide, and water vapor, as well as to UV rays, and increased mechanical properties such as strength, stiffness, dimensional stability, and heat resistance. Additionally, biologically active ingredients can be added to impart the desired functional properties to the resulting packaging materials. New packaging materials created with this technology demonstrate an increased shelf life with maintaining high quality of the product. Nanotechnology offers big benefits for packaging. Nanocomposite technology paves the way for packaging innovation in the flexible and rigid packaging applications, offering enhanced properties such as greater barrier protection, increased shelf life and lighter-weight materials.

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Preparation of Nanocomposite by Microwave Processing (마이크로파 공정을 이용한 나노복합체의 제조)

  • Kim, Tae-Hoon;Son, Se-Mo;Park, Ji-Hwan;Seo, Geum-Suk;Park, Seong-Soo
    • Journal of the Korean Graphic Arts Communication Society
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    • v.22 no.2
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    • pp.111-122
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    • 2004
  • The purpose of this study was to investigate the possibility of application of microwave energy for the fabrication of polymer/clay nanocomposite. APES/Clay nanocomposites were prepared at $130^{\circ}C$ for 30min with various amount of MMT or OMMT used the melt-intercalation method applied the classical and microwave heating source. APES/Clay samples were characterized by the means of X-ray diffractometry (XRD), transmitted electron microscopy (TEM) differential scanning calorimetry (DSC), and rheometric dynamic analysis (RDA). It was found that intercalated or exfoliated state of the samples could be controlled by the clay type, clay content, and heating type.

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Fabrication of Biodegradable Nanocomposite Using Microwave Melted Intercalation Method (마이크로파 용융삽입법을 이용한 생분해성 나노복합체의 제조)

  • Ha, Won Jo;Sin, Jun Sik;Song, Seung Uk;Kim, Jun Ho;Son, Se Mo;Park, Seong Su
    • Journal of Environmental Science International
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    • v.13 no.4
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    • pp.429-434
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    • 2004
  • The purpose of this study was to investigate the possibility of application of microwave energy for the fabrication of polymer/clay nanocomposite. APES/Clay nanocomposites were prepared at 13$0^{\circ}C$ for 30min with various content of clay by melt-intercalation method under classical and microwave heating source. APES/Clay samples were characterized by the means of X-ray diffractometry(XRD), thermal gravimetric analysis(TGA), and rheometric dynamic analysis(RDA). It was found that intercalated or exfoliated state was obtained in the samples according to the condition of organic modification, clay content, and heating source.

Synthesis of Norbornene Block Copolymers Containing Polyhedral Oligomeric Silsesquioxane by Sequential Ring-Opening Metathesis Polymerization

  • Kwon Young-Hwan;Kim Kyung-Hoe
    • Macromolecular Research
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    • v.14 no.4
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    • pp.424-429
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    • 2006
  • The synthesis of a series of poly(POSS-NBE-b-MTD) copolymers was successfully accomplished, taking advantage of sequential, ring-opening, metathesis block copolymerization using $RuCl_2(=CHPh)(PCy_3)_2$ catalyst. By using cyclopentyl-POSS-norbornene (POSS-NBE) monomer as the first block in the block copolymer, living poly(POSS-NBE) with controlled molecular weight and narrow molecular weight distribution was produced. Then, poly(POSS-NBE-b-MTD) copolymers were successfully prepared, in which sequential monomer addition of methyltetracyclododecene (MTD) to the living poly(POSS-NBE) chain ends was utilized to achieve quantitative crossover efficiency. Characterization by $^1H$ NMR spectroscopy and GPC confirmed the high definition and structural integrity of the poly(PO$S-NBE-b-MTD) copolymers. Thermal properties-and morphologies of the POSS-containing block copolymer nanocomposites were also investigated by using thermogravimetric analysis (TGA), transmission electron microscopy (TEM), and wide-angle X-ray scattering (WAXS).

Nanofibers from electrically driven viscoelastic jets: modeling and experiments

  • Carroll, Colman P.;Zhmayev, Eduard;Kalra, Vibha;Joo, Yong-Lak
    • Korea-Australia Rheology Journal
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    • v.20 no.3
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    • pp.153-164
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    • 2008
  • Modeling and experiments of three electrospinning systems have been presented and they are i) axisymmetric instabilities in electrospinning of various polymeric solutions, ii) non-isothermal modeling of polymer melt electrospinning, and iii) control of nanoparticle distribution and location via confined self-assembly of block copolymers during electrospinning. It has been demonstrated that predicted simulations are in good agreement with corresponding electro spinning experiments, and theoretical analysis provides fundamental understanding of phenomena that take place during electrospinning of various polymeric liquids.