• KEPCO Journal on Electric Power and Energy
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• 제3권2호
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• pp.141-146
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• 2017

In this work, a simulation study on net 500 MW class of Poly-Generation was conducted for the retrofit of an aged natural gas combined cycle. An entrained gasifier which has a capacity of maximum $260,000Nm^3/h$, 50 MW class of a Polymer Electrolyte Membrane Fuel Cell, and H-class Gas Turbine were selected as key processes. After unit design for those employed processes was set up and combined, the simulation was carried out with Gate-Cycle software (Ver. 6.0) for two cases. The selected cases are a retrofit type (Poly-Gen 1) and a new type (Poly-Gen 2). It was found that the efficiency of the retrofit case is 2.7% lower than that of the new case.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 추계학술대회 논문집
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• pp.247-250
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• 2009

This study considers the feasibility of using the low cost assembled separator. The graphite plate has been widely used as the separator in the field of PEMFCs(Polymer electrolyte membrane fuel cell) industry because of its excellent material properties such as good corrosion resistance, good electrical conductance and so on. However, there are some problems for the commercialization due to its poor cost effectiveness for the large volume manufacturing and lack of mechanical strength. From this respect, this study has focused on the manufacturing technology in order to reduce the price for the commercialization of separator. This study also shows that the assembled separator of the suggested structure, which is composed of grafoil and PC(PolyCarbonate) materials, could be manufactured at low cost enough for the mass production. The flow fields produced by cutting foils and the base plates of the separators were simply made by mechanical work.

• 전기화학회지
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• 제17권3호
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• pp.201-208
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• 2014

본 연구에서는 산화그래핀과 카본블랙의 혼합담체를 이용하여 내구성이 향상된 백금촉매를 폴리올법으로 제조하였다. 삼전극 순환전압전류법을 이용한 전기화학성능 측정결과 적절한 비율로 조절된 혼합담지체에 백금을 담지시켰을 경우 초기 성능 감소없이 장기내구성이 향상되는 것으로 나타났다. 또한 회전원판전극을 이용하여 산소환원반응을 수행한 결과 혼합담체에 담지된 백금촉매가 카본블랙 단일담체에 담지된 백금촉매보다 우수한 고유활성값을 나타내었다.

• 한국세라믹학회지
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• 제50권6호
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• pp.390-395
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• 2013

Nanocrystalline CrN films were deposited on Si (100) substrates by means of asymmetric pulsed DC reactive magnetron sputtering. We investigated the growth behavior, corrosion resistance and mechanical properties of CrN films with a change in the duty cycle and pulse frequency. The grain size of the CrN films decreased from 25.4 nm to 11.2 nm upon a decrease in the duty cycle. The corrosion potentials for the CrN films by DC sputtering was approximately - 0.6 V, and it increased to - 0.3 V in the CrN films which underwent pulsed sputtering. The nanoindentation hardness of the CrN films also increased with a decrease in the duty cycle. This enhancement of the corrosion resistance and mechanical properties of pulsed sputtered CrN films could be attributed to the densification and surface smoothness of the microstructure of the films.

• 한국수소및신에너지학회논문집
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• 제30권6호
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• pp.601-607
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• 2019

Ammonia would be formed in natural gas containing small amount of nitrogen reforming process in the process natural gas, which might damage the Pt catalyst and Prox catalyst. In the article, the effect of nitrogen contents on the formation of ammonia in the reforming process has been studied. In the experiments, Ru based and Ni based catalysts were used and the concentration of ammonia in the reformate gas at various gas hourly space velocity was measured. Experimental result shows that relatively higher ammonia concentration was measured with Ru based catalyst than with Ni based catalyst. It also shows that the concentration of ammonia increased rapidly after most of the methane converted into hydrogen. Based on the experimental results to reduce ammonia concentration it might be better to finish methane conversion at the exit position of the reforming reactor to minimize the contact time of catalyst and nitrogen with high concentration of hydrogen.

• 한국표면공학회지
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• 제45권2호
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• pp.75-80
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• 2012

A sputter-sublimation source was tested for high rate deposition of protective coating of PEMFC(polymer electrolyte membrane fuel cell) with high electrical conductivity and anti-corrosion capability by DC biasing of a metal rod immersed in inductively coupled plasma. A SUS(stainless steel) tube, rod were tested for low thermal conductivity materials and copper for high thermal conductivity ones. At 10 mTorr of Ar ICP(inductively coupled plasma) with 2.4 MHz, 300 W, the surface temperature of a SUS rod reached to $1,289^{\circ}C$ with a dc bias of 150 W (-706 V, 0.21 A) in 2 mins. For 10 min of sputter-sublimation, 0.1 gr of SUS rod was sputter-sublimated which is a good evidence of a high rate deposition source. ICP is used for sputter-sublimation of a target material, for substrate pre-treatment, film quality improvement by high energy particle bombardment and reactive deposition.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2011년도 임시총회 및 하계학술연구발표회
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• pp.129-129
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• 2011

The limited understanding of the surface properties of $Pt_3Ni$ for the oxygen reduction reaction (ORR) in polymer electrolyte membrane fuel cell (PEMFC) has motivated the study of properties and electronic structures of seven layered $Pt_3Ni$ (001), (110), and (111) surfaces. The first principle method based on density functional theory (DFT) is carried out. It is found that the bulk $Pt_3Ni$ has a ferromagnetic ground state with the ordered fcc type L12 structure, which is in good agreement with other results. Non magnetic Pt has the induced magnetic moment due to the strong hybridization between 3d Ni and 5d Pt. The magnetic moment of Pt and Ni enhanced on the surface of each due to surface effect however the magnetic moment of surface Pt in the Pt-segregated Pt3Ni (111) decreased and the magnetic moment of Ni in Ni rich subsurface increased significantly. The calculated d band centers of Pt explain the possibilities for oxygen absorption and play the important roles in altering the catalytic properties. The spin polarized densities of states are presented in order to understand physical properties of Pt in different surfaces in detail.

• 전력전자학회논문지
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• 제15권1호
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• pp.75-85
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• 2010

본 연구에서는 비선형 부하에서 발생되는 기본파 무효전력 및 고조파를 보상하기 위한 종전의 전압형 및 전류형 PWM 능동전력필터를 대체 할 수 있는 Z-소스 인버터 토폴로지의 하이브리드 능동전력필터에 대하여 고찰하였다. Z-소스 토폴로지의 능동전력필터의 보상 DC전원으로는 PEMFC가 사용되며, Z-소스 인버터의 shoot-through 듀티비의 조절에 의하여 낮은 연료전지의 전압을 높은 보상 전압으로 부스트 한다. 제안된 시스템은 병렬형 Z-소스 능동전력필터와 7차 고조파 (420Hz) 동조 필터로 구성되며, 이 구성에 의하여 Z-소스 능동전력필터의 스위치 디바이스의 전압 스트레스는 감소된다. 제안된 Z-소스 하이브리드 능동전력필터의 보상 알고리즘으로는 전류 동기 검출법이 사용되었다. 3상 220V/60Hz, 25A급 비선형 다이오드 부하 조건하에서 PSIM 시뮬레이션을 수행하였으며, 정상상태 및 과도상태에서의 제안된 시스템의 보상 성능을 파악하였다.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2011년도 자성 및 자성재료 국제학술대회
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• pp.14-14
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• 2011

Limited understanding of the surface properties of $Pt_3Ni$ for the oxygen reduction reaction (ORR) in polymer electrolyte membrane fuel cell (PEMFC) has motivated the study of magnetic properties and electronic structures of Pt segregated $Pt_3Ni$ (111) surface during adsorption of oxygen molecule on it. The first principle method based on density functional theory (DFT) is carried out. Nonmagnetic Pt has induced magnetic moment due to strong hybridization between Ni 3d and Pt 5d. It is found that an oxygen molecule prefers bridge site with Pt rich subsurface environment for adsorption on the surface of Pt segregated $Pt_3Ni$ (111). It is seen that there is very small charge transfer from $O_2$ to Pt. The curve of energy versus magnetic moment of the oxygen explains the magnetic moments in transition states. We found the dissociation barrier of 1.07eV significantly higher than dissociation barrier 0.77eV on Pt (111) suggesting that the dissociation is more difficult on Pt segregated $Pt_3Ni$ (111) surface. The spin polarized densities of states are presented in order to understand electronic structures of Pt and $O_2$ during the adsorption in detail.

• 정보관리연구
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• 제43권2호
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• pp.169-197
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• 2012

특허는 신뢰성 있는 최신 기술의 보고이며, 따라서 특허분석은 기술발전의 현황파악 및 기술전략의 수립을 위한 필수적인 단계로 인식된다. 비록 다양한 특허분석 연구 및 보고서들이 발표되어 왔으나, 특허분석 결과를 기반으로 기업 또는 국가관점에서의 불확실한 미래에 대응하기 위한 기술전략을 제시하는 실제적인 연구사례는 미흡한 실정이다. 따라서 본 연구는 특허분석에 따른 미래기술전략수립 사례연구의 제시를 목적으로 하며, 이를 위해 중장기적 미래분석기법 중의 하나인 시나리오 플래닝을 접목한 미래기술전략 수립절차를 제시한다. 사례연구에서는 차세대 에너지원 중의 하나인 고분자 전해질 연료전지와 관련된 특허들을 활용하여 해당 기술과 관련된 미래 시나리오 별 대응전략을 수립한다. 본 연구의 방법 및 사례연구는 중장기 기술전략 수립 프로세스에서 활용될 수 있을 것으로 기대된다.