• Title/Summary/Keyword: Polymer degradation

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Analysis of Polymer Carbonization using Lasers and its Applications for LCD Manufacturing Process (레이저를 이용한 폴리머 탄화현상 해석 및 LCD 제조공정에서의 응용)

  • Ahn, Dae-Hwan;Bak, Byoung-Gu;Kim, Dong-Eon;Kim, Dong-Sik
    • Journal of the Korean Society for Precision Engineering
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    • v.27 no.6
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    • pp.24-31
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    • 2010
  • Laser carbonization of a polymer layer can be employed in various applications in the microelectronics industry, e.g repairing brightness pixels of an LCD panel. In this work, the process of thermal degradation of LCD color filter polymer by various laser sources with pulsewidths from CW to fs is studied. LCD pixels are irradiated by the lasers and the threshold irradiance of LCD color filter polymer carbonization is experimentally measured. In the numerical analysis, the transient temperature distribution is calculated and the number density of carbonization in the polymer layer is also estimated. It is shown that all the lasers can carbonize the polymer layers if the output power is adjusted to meet the thermal conditions for polymerization and that pulsed lasers can result in more uniform distribution of temperature and carbonization than the CW laser.

A Study on Joining Technology of 3D Printed Metal-polymer Interlocking Structures Using an Induction Heating Process (3D 프린팅 된 금속-고분자 맞물림 구조의 유도 가열 공정을 이용한 접합 기술 연구)

  • Yuk, Ju-Chan;Kim, Yeong-Seo;Park, Suk-Hee
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.21 no.2
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    • pp.87-93
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    • 2022
  • The demand for metal-polymer joining technology have been increasing, especially in the industrial fields of automotive and aerospace, which require the manufacturing of various lightweight parts. Conventional joining processes have technical hurdles on aspects such as thermal degradation, need for chemical surface treatment, or complicated process settings. These issues can be alleviated by employing interlocking structures for the metal-polymer joined interface. In this study, we joined 3D-printed metal and polymer parts, which were featured with 3D-printed interlocking structures at their interface. By using high frequency induction heating, the joined region could be locally heated to reduce the thermal degradation and distortion of polymer parts. In addition, through the adjustment of interface morphologies and compression conditions, the polymer flow could be optimized to completely fill the interlocking grooves on metal parts, thereby achieving high joining strength. This suggests feasible guidelines for manufacturing metal-polymer joined structures involving 3D-printed architectures.

DNA Dynamics under Turbulent Flow

  • Choi, Hyoung-Jin
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.206-206
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    • 2006
  • Polymer induced turbulent drag reduction achieved by adding minute amounts of high molecular weight DNAs in aqueous solution was investigated using a rotating disk apparatus. The DNAs in this study include ${\lambda}-DNA$ and calf-thymus (CT) DNA. By putting emphasis on effect of CT-DNA concentration, its DR characteristics were compared with that of ${\lambda}-DNA$ possessing monodisperse molecular weight characteristics based on both DR efficiency and a mechanical degradation under turbulence. The DNA chains having much higher molecular size than that of ${\lambda}-DNA$ are observed to be more susceptible to mechanical degradation in a turbulent flow. This result was verified via electrophoresis. Furthermore, the coil to globule phase transition of DNA was also investigated under a turbulent flow.

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A Study on Synthetic Failure-finding Method for Electrical and Thermal Degradation of Polymer Insulator by Surface Discharge

  • Lee, Kang-Won;Jang, Dong-Uk;Park, Cheol-Hyun
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.3
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    • pp.143-146
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    • 2007
  • Polymer insulators are used widely in variable fields for high voltage insulation and separating people from high voltage charging parts for safety and also supporting overhead power line in electric railway. But it may be broken down by tracking path resulting from continuous surface discharge. This paper has investigated synthetically both the characteristics of electrical aging using precision CT(current transformer) and the thermal aging using thermography method. Electrical aging was analyzed for time-frequency region and thermal aging was illustrated by image processing method. This synthetic method may be an appropriate one to evaluate the surface degradation of polymer insulator.

Cell-Interactive Polymers for Tissue Engineering

  • Lee, Kuen Yong;Mooney, David J.
    • Fibers and Polymers
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    • v.2 no.2
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    • pp.51-57
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    • 2001
  • Tissue engineering is one exciting approach to treat patients who need a new organ or tissue. A critical element in this approach is the polymer scaffold, as it provides a space for new tissue formation and mimics many roles of natural extra-cellular matrices. In this review, we describe several design parameters of polymer matrices that can significantly affect cellular behavior, as well as various polymers which are frequently used to date or potentially useful in many tissue engineering applications. Interactions between cells and polymer scaffolds, including specific receptor-ligand interactions, physical and degradation feature of the scaffolds, and delivery of soluble factors, should be considered in the design and tailoring of appropriate polymer matrices to be used in tissue engineering applications, as these interactions control the function and structure of engineered tissues.

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A Study on the Degradation Characteristics of Polymer Insulating Materials using TSC Technique (TSC 기법에 의한 고분자 절연재료의 열화특성 연구)

  • 박재세;성낙진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.285-288
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    • 1995
  • In this Study, it worked to get the degradation characteristics of polymer insulating materials using TSC technique. So, it prepared epoxy composities with sample, the TSC spectroscopy was applied to investigate the influence of interfacial deformation due to inorganic filler and treatments of coupling agents on the network structure and the electrical properties of epoxy composites.

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Study of test method of tracking degradation for polymer insulation (폴리머 애자의 트래킹 열화 평가방법 연구)

  • 심대섭;박병락;박성균;소진중
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.391-394
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    • 2000
  • EPDM/silicone blend was prepared with polyorganosiloxane compatibilizer for out-door polymer insulation used to shed. Each blend had various weight ratios, 100/0, 90/10, 70/30, 50/50, 30/70, 10/90, and 0/100 as EPDM to silicone, and electrical and tracking characteristics were studied with the method of IEC 60587. And also, tracking properties and contact angle related to UV-weathering period were studied to understand the degree of degradation of blend after 1000 h UV-weathering.

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A Comparative study for single-shot immunization of diphtheria toxoid with combined PLGA microspheres.

  • Yoon, Mi-Kyeung;Lee, Jung-Min;Kim, Hee-Kyu;Choi, Young-Wook
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.416.1-416.1
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    • 2002
  • Biodegradable PLGA microspheres(MS) have been widely studied for delivering antigens because PLGA has the characteristics of various degradation rate. In general. since MS have shown potential for single-dose vaccines. the degradation rate of PLGA is determined by their molecular weight. polymer composition, etc. We studied the influences of molecular weight of PLGA. polymer composition and surfactant on in vitro release and in vivo effects. (omitted)

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Structural Changes of Biodegradable Poly(tetramethylene succinate) on Hydrolysis

  • Shin, Jick-Soo;Yoo, Eui-Sang;Im, Seung-Soon;Song, Hyun-Hoon
    • Macromolecular Research
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    • v.9 no.4
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    • pp.210-219
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    • 2001
  • Quenched and slow cooled as well as isothermally crystallized poly(tetramethylene succinate)(PTMS) films at two different temperatures were prepared. In the process of hydrolysis of the four specimens, structural changes such as the crystallinity, crystal size distribution, lattice parameter, lamellar thickness, long period and surface morphology were investigated by using wide and small angle X-ray scattering (WAXS and SAXS), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). The hydrolytic degradation of quenched film was faster than that of slow cooled and isothermally crystallized films. The film crystallized at 100$\^{C}$ exhibited extensive micro voids and thus showed faster degradation than that crystallized at 75$\^{C}$, demonstrating surface morphology is another important factor to govern degradation rate. The crystallinity of the specimen increased by 5-10% and long period decreased after hydrolysis for 20 days. At the initial stage of degradation, the lamellar thickness of quenched film rather increased, while that of slow cooled and isothermally crystallized films decreased. The hydrolytic degradation preferentially occurred in the amorphous region. The hydrolytic degradation in crystal lamellae are mainly at the crystal surfaces.

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