• Elastomers and Composites
• /
• v.41 no.3
• /
• pp.157-163
• /
• 2006

In this study, the wettability and mechanical properties of silicone rubber impression material were studied by using precipitated silica and fumed silica with different particle size and polarity (hydrophilic/hydrophobic). Curing time of impression material depended on the particle size of fumed silica. The curing time delayed about 9 minutes by using A300, which was the fumed silica with the smallest particle size among the silica used in this study. Wettability of rubber impression material improved with the introduction oi hydrophobic fumed silica(R972). Also, the optimum flow and mechanical properties could be obtained by using blended silica with the 90: 10 ratio of precipitated and fumed silica.

• Polymer(Korea)
• /
• v.28 no.4
• /
• pp.321-327
• /
• 2004

The applications of dental restorative composite resins containing 2,2-bis [4-(2-hydroxy-3-me-thacryloyloxy propoxy) phenyl] propane as a base resin, and triethylene glycol dimethacrylate, as a diluent, were often limited in dentistry due to the relatively large amount of volumetric shrinkage that occurs during the curing reaction. In this study, in order to reduce volumetric shrinkage of the current dental restorative composite resin, asymmetric spiro orthocarbonates were synthesized and then the characteristics of resin composites containing them were explored. The volumetric shrinkage of the dental composites containing spiro orthocarbonates was decreased approximately 45%. However, the curing characteristics and mechanical properties of the new dental composites were slightly poor than those of the commercially available dental composite.

• Polymer(Korea)
• /
• v.31 no.2
• /
• pp.111-116
• /
• 2007

Polyurethane modified acrylate $(PUA)/SiO_2$ hybrid films were prepared by ultraviolet curing and their surface properties were investigated by hardness and adhesion test. The films were examined by the manipulation of mole-ratio of organic to inorganic components. Under the silica content controlled, highly desirable films were achieved and scratch resistance and hardness property of film were also enhanced, which indicates that the crosslinked silica particles are homogeneously dispersed within PUA film.

• Polymer(Korea)
• /
• v.32 no.4
• /
• pp.313-321
• /
• 2008

Acrylic pressure sensitive adhesive(PSA) was prepared by UV radiation curing and the peel energy and physical properties of PSA were investigated. The increase of amount of acrylic acid leads to improve the peel energy, associated with the substrate having smooth surface and high layer thickness. The high peel energy is obtained when the direction of irregularity in substrate is horizontal with the peeling direction. This is attributed to the increase of resistance to peeling in spite of decrease of wetting and the result corresponds to our supposition.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2002.05a
• /
• pp.215-220
• /
• 2002

Epoxy-coated re-bar was partly used to the structures and put to practical use, but were not economical and appeared to have defects such as the diminishing of long term bond strength between concrete. The study of polymer cement slurry coated re-bar was started in order to complement the defect of epoxy coated re-bar, and ever since the basic properties appeared to be excellent. But, study of bond properties embedded in concrete specimens was insufficient until now. This study attempts to examine the possibility of improving the bond strength of polymer cement slurry coated re-bar between concrete specimens in accordance with ACI Code and KS Code through pull-out test of 150mm$\times$150mm$\times$150mm substrates with polymer cement slurry coated re-bar having polymer cement ratios of 50%, 75% and 100%, coating thickness 250${\mu}{\textrm}{m}$, 450 ${\mu}{\textrm}{m}$ and with curing ages of 3, 7 and 28 days. High strength concrete was designed having a compressive strength of 500kgf/cm2 as specified. Practical bond length ranges of 55 and 85mm were applied to each of specimen. The bond strength of polymer cement slurry coated re-bar using St/BA-1 and St/BA-2 was compared to that of plain re-bar. The results of this study showed that the bond strength of 55mm bond length was much higher than that of 85mm bond length.

• Journal of The Korean Society of Agricultural Engineers
• /
• v.46 no.7
• /
• pp.47-53
• /
• 2004

Permeable polymer concrete can be applied to roads, sidewalks, river embankments, drain pipes, conduits, retaining walls, yards, parking lots, plazas, interlocking blocks, etc. This study was to explore a possibility of using blast furnace slag powder and stone dust of industrial by-products as fillers for Eco-permeable polymer concrete. Different mix proportions were tried to find an optimum mix proportion of the Eco­permeable polymer concrete. The tests were carried out at $20{\pm}1^{circ}C$ and $60{\pm}2\%$ relative humidity. At 7 days of curing, unit weight, coefficient of permeability, dynamic modulus of elasticity, compressive, flexural and splitting tensile strengths ranged between $1,821{\~}1,955 kg/m^{3}$, $0.056{\~}0.081\;cm/s$, $114{\times}0^{2}{\~}157{\times}10^{2}\;MPa,\;17.6{\~}24.7\;MPa,\;5.98{\~}7.94\;MPa\;and\;3.43{\~}4.70\;MPa$, respectively. It was concluded that the blast furnace slag powder and stone dust can be used in the Eco-permeable polymer concrete.

• Elastomers and Composites
• /
• v.55 no.3
• /
• pp.167-175
• /
• 2020

Various studies have been conducted to improve silica dispersion of silica filled tire tread compounds; among them, silica wet masterbatch (WMB) technology is known to be suitable for manufacturing silica filled compounds that have high silica content and high dispersibility. Till now, the WMB study is focused on the natural rubber (NR) or emulsion styrene-butadiene rubber (ESBR) that does not have a silica-affinity functional group, and a study of NR or ESBR having a silica-affinity functional group is still not well known. Unlike the dry masterbatch technology, the WMB technology can solve the problems associated with the high Mooney viscosity when applied to silica-friendly rubber. However, a coagulant suitable for each functional group has not yet been determined. Therefore, in this study, different coagulant applied silica WMB was prepared by applying calcium chloride, sulfuric acid, acetic acid, and propionic acid by using a carboxyl group functionalized reversible addition fragmentation chain transfer ESBR. The evaluation of the WMB compounds revealed that the calcium chloride added WMB compound showed excellent silica dispersion, abrasion resistance, and rolling resistance.

• Applied Chemistry for Engineering
• /
• v.9 no.4
• /
• pp.579-584
• /
• 1998

Polymer dispersed liquid crystal(PDLC) composite films were made by polymerization induced phase separation method using UV-curing to investigate the effect of fabrication conditions, such as photoinitiator concentration, film thickness, polymerization temperature, and electric field during polymerization, etc., on the electro-optic properties. As the amount of photoinitiator increased, the driving voltage of PDLC device increased due to the increase of small-size liquid crystal phases. This was considered as the results from the increased interfacial area between liquid crystal (LC) and polymer matrix, since LC molecules at the interfacial regions were relatively difficult to response for the applied electric field. When the higher molecular weight oligomer (PTDA-1000) was used as matrix, the initial transmittance was observed to be relatively higher than that for the lower molecular weight oligomer (PTDA-250). Saturation transmittance for PTDA-1000 was observed at relatively lower voltage than that for PTDA-250, of which transmittance was not saturated even at 60 V. As polymerization temperature increased, the initial transmittance of resulting PDLC film increased due to the larger LC droplets formation and the more matched refractive index between LC and matrix than those cases for the lower polymerization temperature. Though driving voltage decreased for the thinner film, it was considered that optimum thickness of the film should be maintained to get some practical contrast, which is the ratio of off- and on-state transmittance. Furthermore, electro-optic properties such as initial transmittance, driving voltage, and response time were observed to be considerably affected by application of external field during polymerization.

• KCI Concrete Journal
• /
• v.13 no.2
• /
• pp.42-48
• /
• 2001

The bend resistance of coated reinforcing bar is greatly influenced by both the adhesion strength between bar and coating materials, and the followed transformation of coating material as bars bend. Especially, tearing state or partial microscopic cracks are predicted on the inside and outside of bending angle, because tensile strength and elongation of polymer film are very different according to types of polymer dispersions in bar coating, and these damaged parts are rapidly corroded by penetration of corrosive factors. In this study, polymer cement slurry coated reinforcing bars with various polymer dispersions are prepared by following combined conditions, polymer-cement ratio of 50% and 100%, coating thickness of 250$\mu$m and 450$\mu$m, coating number, curing age of 3, 7, 14 and 28days. Then the specimens are tested for working life and bend resistance at bending angles $90^{\circ}$, $135^{\circ}$and $180^{\circ}$ to observe the microscopic damage effect as the bars bend. Also, epoxy-coated reinforcing bars for control experiment were used with 250$\mu$m of coating thickness. The tensile strength for polymer films is performed. From the test results, the working life of the polymer cement slurry is within 90 seconds. Among four types of polymer dispersion, polymer cement slurry coated reinforcing bar using St/BA-1 emulsion has the excellent bend resistance, which is remarkably improved than that of epoxy-coated reinforcing bar. And the bend resistance is more related to elongation than tensile strength of polymer film. Polymer cement slurry with a polymer-cement ratio of 100%, a coating thickness of $450\mu$m and one coating using St/BA emulsion is selected as a most suitable coating material for coated reinforcing bar.

• Polymer(Korea)
• /
• v.25 no.5
• /
• pp.691-698
• /
• 2001

Nanocomposites based on epoxy acid nanoclay were prepared employing organically modified mica type silicate (OMTS), diglycidyl ether of bisphenol A (DGEBA) type epoxy. curing agent (dicyandiamide; DICY), and catalyst (benzyl dimethyl amine; BDMA). Both melt mixing and solution mixing were und for the sample preparation and structural developments with curing reaction were analyzed using X-ray diffractometer (XRD) and small angle X-ray scattering (SAXS). Because of the different curing rate between extra-gallery and intra-gallery reactions of epoxy mixtures, only intercalated structure was observed for the sample prepared by melt mixing while fully exfoliated structure was observed for the sample prepared by solution mixing. Mechanical properties of exfoliated epoxy nanocomposite were investigated using a dynamic mechanical analyzer (DMA). The dynamic storage modulus of the nanocomposite in both glass and rubbery plateau regions were increased with increasing OMTS contents, but glass transition temperatures ($T_g$) remained unchanged. Thermal properties of epoxy nanocomposite were investigated using thermogravimetric (TGA) and limit oxygen index (LOI) methods. Thermal decomposition onset points and LOI values were increased with increasing OMTS contents due to barrier effects of OMTS sheets.