• Proceedings of the Membrane Society of Korea Conference
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• 1996.10a
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• pp.86-87
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• 1996

IPN (Interpenetrating Polymer Network) is a mixture of two or more crosslinked polymers with physically interlocked network structures between the component polymers. IPN can be classified as an alloy of thermosets and has the characteristics of thermosets such as the thermal resistance and chemical resistance and also has the characteristics of polymer alloys with enhanced impact resistance and amphoteric properties. The physical interlocking during the synthesis restricts the phase separation of the component polymer with chemical pinning process, thus the control of morphology is possible through variations of the reaction temperature and pressure, catalyst concentration and crosslinking agent concentration. Finely dispersed domain structure can be obtained through IPN synthesis of polymer components with gross immiscibility. In membrane applications, particularly for the separation of liquid mixtures, crosslinked polymer component with specific affinity to the permeate is needed. With the presence of the permeant-inert polymer component, the mechanical strength and the selectivity of the membranes are enhanced by restricting the swelling of the transporting polymer component networks.

• Journal of Korean Society of Water and Wastewater
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• v.22 no.6
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• pp.627-632
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• 2008

It is necessary to investigate methods for improvement by diagnosing sludge settling characteristics on inflow of slurry to thickener. The results of the settling tests are correlated to determine zone settling velocities at the various sludge solids concentrations. Conditioning of WTP residuals is generally done by either chemical or physical treatment. The settling test was conducted with 1m columns dosing polymer to WTP residuals at various solids concentration. The estimated results for dosing to WTP residuals for a sludge of 2,100 ~ 16,012 mg/L solids concentration were the zone settling velocities of 48.38 ~ 6.8 m/day, supernatant solid concentration of 3.2 ~ 19 mg/L and solid flux of $101.6{\sim}317.61kg/m^3{\cdot}day$. The values for non-polymer treatment were the zone settling velocities of 28.37 ~ 0.12 m/day, supernatent solid concentration of 8.5 ~ 108 mg/L and solid flux of $59.58{\sim}1.92kg/m^2{\cdot}day$. The limiting solid flux value by Yoshioka methods was $4.0kg\;TS/m^3{\cdot}day$ for Non-polymer and $228.0kg\;TS/m^3{\cdot}day$ for dosing polymer. These results are to indicate a possibility of improvement on the thickening characteristics and the quality of supernatant as increasing the settling velocities by dosing polymer to WTP residuals.

• Membrane and Water Treatment
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• v.13 no.3
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• pp.139-145
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• 2022

Development in advanced separation processes leads to the significant advancement in polymeric membrane preparation methodology. Therefore, present research investigated the preparation and characterization of cellulose acetate membrane by phase inversion separation method to determine optimized operating parameters. Prepared CA membrane's performance was been analyzed in terms of % rejection and flux. Investigation was conducted to study effect of different parameters such as polymer concentration, evaporation rate, thickness of film, coagulation bath properties, temperature of polymer solution and of the coagulation bath etc. CA membrane was fabricated by taking polymer concentration 10wt% and 11wt% with zero second evaporation time and varying film thickness over non-woven polyester fabric. Effect of coagulation bath temperature (CBT) and casting solution temperature were also been studied. The experimental results from SEM showed that the surface morphology had been changed with polymer r concentration, coagulation bath and casting solution temperature, etc. Lower polymer concentration leads to lower precipitation time giving porous membrane. The prepared membrane was tested for advanced waste water treatment of relevant effluent stream in pilot plant to study flux and rejection behavior of the membrane.

• Macromolecular Research
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• v.10 no.5
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• pp.246-252
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• 2002

In order to the development of the delivery device of long-acting local anesthetics for postoperative analgesia and control of chronic pain of cancer patient, fentnyl-loaded poly (L-lactide-co-glycolido) (PLGA, molecular weight, 5,000 g/mole; 50 : 50 mole ratio by lactide to glycolide) microspheres (FMS) were studied. FMS were prepared by an emulsion solvent-evaporation method. The influence of several preparation parameters such as initial drug loading, PLGA concentration, emulsifier concentration, oil phase volume, and fabrication temperature has been investigated on the fentanyl release profiles. Generally, the drug showed the biphasic release patterns, with an initial diffusion followed by a lag period before the onset of the degradation phase, but there was no lag time in our system. Fentanyl was slowly released from FMS over 10 days in vitro with a quasi-zero order property. The release rate increased with increasing drug loading as well as decreasing polymer concentration with relatively small initial burst effect. From the results, FMS may be a good formulation to deliver the anesthetic for the treatment of chronic pain.

• Journal of the Korean Applied Science and Technology
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• v.28 no.4
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• pp.386-392
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• 2011

We are crystallized to the linear low density polyethylene(LLDPE) particles by a thermally induced phase separation(TIPS). TIPS process based on the phase separation mechanism was performed for the LLDPE system which undergoes liquid-solid phase separation. The linear low density polyethylene particle formation occurred by the nucleation and growth mechanism in the metastable region. Although the growth rates depended on the experimental conditions such as the polymer concentration and temperature, the particles were larger when the polymer concentration was higher or temperature was higher. The particles were observed by SEM. The LLDPE particle size distribution became broader when the polymer concentration was higher.

• Journal of the korean Society of Automotive Engineers
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• v.15 no.3
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• pp.81-88
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• 1993

This report describes the experimental research on the flow phenomena of the aq uaous polymer solution within the Cuette flow of the concentric, cylinders type with a wide circular gap. We have investigated the phenomena of the fluid flow through torque measuring in the system that the inner cylinder is stationary and the outer one is rotating. Geometrical parameters of the system are the gap ratio of t/R$_{0}$=0.2 and Aspect ratio of l/t=100. The torque increases considerably in about 420-480RPM, So, it is considered a turbulent transition boundary, the higher plymer concentration is, the lower torque value is and the higher transition Reynolds number is. In each of the polymer concentration, the unstable boundary of torque, that is, idiosyncrasies of torque is observed around 220-280RPM. and the boundary is looked upon as a resonant vibration which is caused by the inner cylinder and tortional vibration of torque sensor.r.

• Solar Energy
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• v.19 no.1
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• pp.37-45
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• 1999

As polymer added in flow, the phenomenon of drag reduction effect was found by many experiments and studies. We divided polymer into three molecular weight($2{\times}10^5,\;4{\times}10^5,\;5{\times}10^5$) and into four concentration(1, 5, 10, 20wppm), then we measured the drag reduction effect in the range Reynolds Number with $30000{\sim}60000$. Finally we found that the most effect drag reduction was that molecular weight is $2{\times}10^5$ with 10wppm concentration. Then the concentration was according to PEO molecular weight, and in general DR increase according to Reynolds Number.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.205-205
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• 2006

Adsorption behaviors of positively charged matrix (PAH) onto negatively charged probe (sulfate PS particle) were investigated using DLS (dynamic light scattering) and FPR (fluorescence photobleaching recovery) as view points of matrix and salt concentration. The system experienced sharp decrease of diffusion (flocculation) at dilute condition while the system underwent gradual decrease of diffusion above semi-dilute concentration. With FPR and viscometry experiments, we revealed the probe behaviors in polyelectrolyte solution were strongly affected by the coil overlap concentration (0.5 g/L PAH concentration).

• Polymer(Korea)
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• v.35 no.6
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• pp.531-536
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• 2011

Homopolymer distribution in block copolymer/homopolymer blends was investigated as a function of homopolymer concentration and homopolymer molecular weight. The deuterated poly(methyl methacrylate) or polystyrene was blended with a deuterated polystyrene-poly(methyl methacrylate) diblock copolymer up to a concentration of 20 wt%. Samples were characterized by small-angle X-ray scattering (SAXS), neutron reflectivity and transmission electron microscopy. The block copolymer with a thin-film geometry formed alternating lamellar microdomains oriented parallel to the substrate surface. By adding the homopolymer, the microdomain structure was significantly disturbed. As a consequence, a poorly ordered morphology appeared when the homopolymer concentration exceeded 15 wt%. Increasing the homopolymer concentration and/or the homopolymer molecular weight caused the microdomains to swell less uniformly, resulting in segregation of the homopolymer toward the middle of the microdomains.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.8 no.2
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• pp.198-207
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• 1996

It is well known that drag reduction in single phase liquid flow is affected by polymer material, molecular weight, polymer concentration, pipe diameter, and flow velocity. Drag reduction in two phase flow can be applied to the transport of crude oil, phase change system such as chemical reactor, pool and boiling flow, and to present cavitation which occurs in pump impellers. But the research of drag reduction in two phase flow is not sufficient. The purpose of the present work is to evaluate the drag reduction by measuring pressure drop, void fraction, mean liquid velocity, and turbulent intensity whether polymer is added in the horizontal two phase system or not. Experiment has been conducted in a test section with the inner diameter of 24mm and the length of 1,500mm. The polymer materials used are two kinds of polyacrylamide[PAAM] and co-polymer[A611P]. The polymer concentration was varied with 50, 100 and 200 ppm under the same experimental conditions. Experimental results showed that the drag reduction of co-polymer is higher than that of polyacrylamide. Mean liquid velocities increased as polymer was added, and turbulent intensity decreased inversely near the pipe wall.