• Clean Technology
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• v.11 no.3
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• pp.117-122
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• 2005

N-vinyl caprolactam (NVCL), a kind of N-vinyl amide monomer, must be dissolved in continuous phase ($scCO_2$) for dispersion polymerization in supercritical carbon dioxide. Phase behavior of $CO_2$+NVCL is very important and necessary for determining initial polymerization condition and for monomer extraction from final polymer. There is the limitation of experimental method for obtaining pure properties of the monomer because of the possibility of polymerization. And N-methyl caprolactam (NMCL) is the useful solvent for the gas treating process. In the viewpoint of molecular thermodynamics, NVCL and NMCL have same functional group i.e. ${\varepsilon}$-caprolactam. In the case of NVCL, hydrogen of amide group is substituted with vinyl group and for NMCL, hydrogen of amide group is substituted with methyl group. We suggested modified group contribution method for this ${\varepsilon}$-caprolactam derivatives. This new group contribution parameter was applied to correlate $CO_2$ + N-vinyl caprolactam or N-methyl caprolactam system.

• Journal of the Korea Concrete Institute
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• v.20 no.6
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• pp.671-679
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• 2008

The near surface mounted (NSM) FRP strengthening method has been conventionally applied for strengthening the deteriorated concrete structures. The NSM strengthening method, however, has been issued with the problem of limitation of the cutting depth which is usually considered as concrete cover depth. This may be related with degradation of bonding performance in long-term service state. To improve the debonding problem, in this study, the Stirrup partial-cutting NSM (SCNSM) strengthening method using CFRP plate was newly developed. SCNSM strengthening method can be effectively applied to the deteriorated concrete structure without any troubles of insufficient cutting depth. To experimentally verify the structural behavior, the flexural test of the concrete beam by using the SCNSM strengthening method was conducted with the test variable as the strengthening length (32%, 48%, 70%, 80%, 96% of span length). In the result of the test, the NSM and SCNSM strengthened specimen showed similar structural behavior with load-deflection, mode of failure. Additionally, there was no apparent structural degradation by the stirrup partial-cutting. Consequently, it was evaluated that the SCNSM strengthening method can be useful for seriously damaged concrete structures that is hard to apply the conventional NSM strengthening method for increasing the structural capacity.

• Journal of the Mineralogical Society of Korea
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• v.20 no.1 s.51
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• pp.21-33
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• 2007

The dispersion/flocculation behavior of bentonite is a major concern in performance of drilling fluid. We studied the dispersion/flocculation characteristics of three commercial bentonites [two CMC (carboxymethyl cellulose) treated and one untreated] in waters of different pHs and salt concentrations. We also examined changes in the viscosity of bentonite suspensions in such waters as a major rheological property of drilling fluid. The dispersion/flocculation behaviors of bentonites were measured by two methods: colorimetric and light scattering method. Light scattering method allows estimating the floc diameter and flocculation rate. The dispersion and flocculation behaviors were diverse with the different bentonites and water qualities. In distilled water, all the bentonites were well dispersed up to first 10 minutes. After that, the CMC-bearing bentonites were flocculated. In salt waters, all the samples were flocculated and the flocculation rate is varied with salt concentration and polymer content. The volume of settled flocs decreased with increasing salt concentration. The flocculation rate and floc diameter increased with decreasing pH of solutions, whereas the volume of settled flocs increased with increasing pH of solutions. The bentonites of fast flocculation behavior had low viscosity. The results of the present study will be helpful in applying bentonites to drilling fluids in diverse environments.

• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.1
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• pp.199-207
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• 2018

Experimental programs were performed to evaluate the flexural performance of fiber reinforced concrete(FRC) beams using a hybrid double-layer arrangement of steel bars and fiber reinforced polymer(FRP) bars or using FRP bars only. A total of seven beam specimens were produced with type of tensile reinforcing bar(CFRP bar, GFRP bar, steel bar) and the poly vinyl alcohol(PVA) fiber mixing ratio(0.5%, 0%) as variable. An analysis method for predicting the flexural behaviors of FRC beams with hybrid arrangement of heterogeneous reinforcing bars through finite element analysis was proposed and verified. In case of the specimens with the double-layer reinforcing bars, the test results showed that the first cracking load of specimen with a double-layer arrangement of steel bars was greater by 26-34% than specimens with a hybrid double-layer arrangement of steel and FRP bars. In maximum flexural strengths, the specimen that used CFRP bars as bottom tensile reinforcing bar showed the greatest strength among the specimens with the double-layer reinforcing bars. When the maximum moment value obtained through experiments was compared with that obtained through analysis, the ratio was 1.2 on average, the standard deviation was 0.085, and the maximum error rate was 22% or less. Based on these results, the finite element analysis model proposed in this study can effectively simulate the actual behavior of the beams with hybrid double-layer reinforcing bars.

• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.4
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• pp.100-107
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• 2018

The objective of this study is to assess the strengthening effects of fiber reinforced polymer(FRP) sheets such as Carbon fiber, Glass fiber, and PET(polyethylene terephthalate) on reinforced concrete flexural members. Variables of theoretical analysis are types of strengthening materials, material properties and amount of strengthening materials. A virtual flexural member without FRP sheets was created as a control specimen to understand the structural behavior of the non-strengthened specimen in terms of elastic and ultimate cross section. In total, 11 specimens including one non-strengthened and ten strengthened specimens were investigated. Various variables such as types of strengthening, strengthening properties, and amount of strengthening were studied to compare the behavior of the control specimen with those of strengthened specimens with regard to moment-curvature relationship. Results of theoretical analysis showed that the moment capacity of strengthened specimens was superior to that of the control specimen. However, the control specimen indicated the best ductility among all the specimens. As the amount of strengthening increased, flexural performance was improved. Furthermore, the results indicated that the ductile effect of members was affected by the ultimate strain of FRP sheets. The strengthening effect on the damaged member was similar to that on the non-damaged one since there was less than 10% difference in terms of flexural strength and ductility. Therefore, even if a damaged member is treated as non-damaged for analysis there is probably no noticeable difference.

• Korean Chemical Engineering Research
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• v.58 no.1
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• pp.44-51
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• 2020

The basic catalyst 1-benzyl-3-methyl-imidazolium hexafluoroantimonate (BMH) was synthesized and analyzed by FT-IR and ¹H-NMR. A crystalized biphenyl-based epoxy was synthesized by using tetramethyl biphenol (TMBP) and epichlorohdrine. In order to consider the curing tendency of the synthesized BMH, the mass ratio was changed to 0.5, 1.0, 2.0 wt.% under heated conditions and the curing tendency was analyzed by differential scanning calorimeter (DSC). As a result, the BMH catalyst showed a fast curing result in the stepwise heating pr℃ess of the biphenol-A epoxy and the cationic polymer. From these results, the BMH catalyst showed excellent thermal stability as a potential heat curing catalyst. In addition, we considered the application possibility of epoxy molding compound (EMC) which required a skeleton structure and a high heat resistance because the synthesized biphenyl epoxy had a characteristic of rapidly lowering viscosity at a constant temperature and a rigid skeleton structure of biphenol. As a result, it was confirmed that the TMBP-based epoxy developed in this study was composed of a crystalline structure, and a curing reaction was observed with a Novolac resin at a high temperature. In the presence of a catalyst, a curing reaction was observed around 150 ℃ and thus TMBP-based epoxy was successfully applied as a raw material of EMC.

• Journal of the Korea Concrete Institute
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• v.23 no.3
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• pp.273-280
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• 2011

Ten high-strength concrete beam specimens, which have various combinations of different types of flexural reinforcement and short fibers were constructed and tested. Six beams were reinforced with two layers of steel, CFRP, and GFRP bar combinations. The other four beams were reinforced with two layers of single type CFRP and GFRP bars, with steel and synthetic short fibers. An investigation was performed on the influence of the parameters on the load-carrying capacity, post cracking stiffness, cracking pattern, deflection behavior, and ductility. The low post cracking stiffness, large deflection, deep crack propagation, large crack width, and low ductility of FRP bar-reinforced beams were controlled and improved by positioning steel bars in the inner layer of the FRP bar layer. In addition, the addition of fibers increased the first-cracking load, ultimate flexural strength, and ductility as well as the deep propagating cracks were controlled in the FRP bar-reinforced concrete beams. The increased ultimate concrete strain of fiber-reinforced concrete should be determined and considered when FRP bar-reinforced concrete members with fibers are designed.

• Elastomers and Composites
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• v.36 no.2
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• pp.111-120
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• 2001

Mechanical properties and their adhesion behavior with zinc- and brass-plated steel cords of natural rubber/acrylonitrile-butadiene blend compounds were investigated as a function of blend ratio. The Mooney viscosity and stress relaxation time were found to be lowered with increasing NBR content. Tensile modulus generally increased with increasing NBR content. Tensile stress at break stayed constant up to about 40 phr and showed minimum at $50{\sim}60 phr$, and thereafter increased with increasing NBR content. Strain at break decreased linearly below 50 phr, and above the level it showed nearly constant value. Based on the abrupt drops in elastic modulus and tan ${\delta}$ peak, the glass transition temperature of NR and NBR were found to be -55 and $-10^{\circ}C$, respectively. In the case of NR/NBR blend compounds, two distinct transition points were observed and each transition position was not affected by NBR level indicating an incompatible nature of NR/NBR blend system. The pullout force and rubber coverage decreased to the level of about 40% to that of pure m compound, when the 50 phr of NR was replaced by NBR. However, the pure NBR compound showed the comparable adhesion performance with NR(${\sim}90%$). The sulfur concentration was found to become lower with the increased NBR content at the adhesion interface based on the Auger spectrometer results, representing a lack of adhesion layer formation, and this was explained for a possible cause of low adhesion performance with adding NBR.

• Journal of the Korea Concrete Institute
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• v.20 no.2
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• pp.239-247
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• 2008

Use of both carbon fiber (CF) and glass fiber (GF) at the same time to strengthen existing flexural members was exploited. Using a proper volumetric GF / CF ratio, the CF can rupture first followed by subsequent rupture of GF at higher stress and strain showing a pseudo-ductile behavior. A theoretical study indicated that the ratio is 4.62 : 1 and higher where the pseudoductile effect can be shown. Flexural tests of plain concrete beams strengthened using fibers were first carried out. Hybrid FRP sheet using 8.8 : 1 ratio was then fabricated and the sheet was used to strengthen reinforced concrete beams. The RC beams strengthened using 1-ply and 2-ply hybrid sheets both revealed increased strength over a non-strengthened beam and ductile flexural behavior. A comparable beam strengthened using CF also showed increased strength but with limited ductility.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.9 no.6
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• pp.1775-1781
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• 2008

The effects of the type of curing agent on the swelling of the natural rubber(NR) sponge applicable to the self-sealing layer of a helicopter fuel tank were investigated. The curing systems employed were peroxide and mixed ones of sulfur and peroxide. The NR compounds were prepared in a kneader and a roll-mill. The compounds were partially cured in a press at high pressure and subsequently cured fully with expansion in another press at atmospheric pressure. The apparent density of the NR sponge was measured and the cell structure was observed with scanning electron microscopy. The swelling experiments were performed at room temperature using toluene, iso-octane, and an aircraft fuel as a solvent. More rapid volume swelling of the NR sponge cured by peroxide was achieved than cured by sulfur and peroxide with similar amount of curing agent added in rubber compounds. The apparent density and cell structure of the sponge were extremely sensitive to the amount of peroxide, which influences again the swelling behavior of the NR sponge. It is important to control properly two reactions of decomposition of foaming agent and crosslinking of NR in the mold to obtain rapid swelling of the NR sponge on contact of the fuel.