• Title/Summary/Keyword: Polymer Material

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A Comparison Study of CFD Analysis and Flow Visualization on Behavior of Liquid Water in Cathode Channels of PEM Fuel Cells (PEM 연료전지 공기극 유로에서 물의 거동에 대한 CFD 해석과 가시화 실험의 비교 연구)

  • Kim, Hyun-Il;Nam, Jin-Hyun;Shin, Dong-Hoon;Chung, Tae-Yong;Kim, Young-Gyu;Seo, Won-Seok;Lee, Jung-Woon
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2008.04a
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    • pp.101-108
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    • 2008
  • Polymer electrolyte membrane (PEM) fuel cells are promising power generation devices which are ideal for residential and automobile applications, thanks to their fast transient characteristics. However, liquid water produced in PEM fuel cells should be properly managed to enhance the performances and durabilities of the cells. In this study, a visualization experiment was conducted to investigate the flow behavior of water droplets in cathode channels. The visualization experiment was done with four different model flow channels which were made by varying the material (Acrylic and Teflon) and the channel width (1 mm and 2 mm). Acrylic is hydrophilic (contact angle is about $80^{\circ}$) while Teflon is hydrophobic (contact angle is about $120^{\circ}$). A computational fluid dynamics (CFD) analysis was also performed to compare the observed and the simulated two-phase water/air flow characteristics in cathode channels. The computational models were made to be consistent with the geometries and surface properties of the model flow channels. Both the experimental and numerical results showed that the Teflon cathode channel with 1 mm width has the best water management performance among four model flow channels considered. A close correlation was found between the experimental visualization results and the numerical CFD simulation results.

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Effect of Solvent Annealing on the Characteristics of PEDOT:PSS as a Ammonia Gas Sensor Film (용매열처리에 따른 PEDOT:PSS 암모니아 가스 감지막 특성 변화)

  • Noh, Wang Gyu;Yeom, Se-Hyuk;Lee, Wanghoon;Shin, Han Jae;Kye, Ji Won;Kwak, Giseop;Kim, Se Hyun;Ryu, Si Ok;Han, Dong Cheul
    • Journal of Sensor Science and Technology
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    • v.26 no.2
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    • pp.96-100
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    • 2017
  • Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) has been extensively studied as the active material in ammonia gas sensor because of its fast response time, high conductivity and environmental stability. It is well known that a post annealing process for organic devices based on PEDOT:PSS significantly increases the device performance. In this study, we propose the solvent annealing of PEDOT:PSS and investigated its effects. As a results, post solvent annealing on PEDOT:PSS lead to the surface chemical and physical properties change. These changes result in improved conductivity of the PEDOT:PSS. In additional, ammonia sensitivity of solvent annealed PEDOT:PSS become higher than pristine polymer film. The enhancement is mainly caused by the depletion of gas barrier PSS and structural re-forming PEDOT networks. We believe that the post solvent annealing is a promising method to achieve highly sensitivity PEDOT:PSS films for applications in efficient, low-cost and flexible ammonia gas sensor.

The study on Development and characteristic of ultrasound biopsy training phantom of breast (유방 초음파 팬텀의 제작과 특성에 관한 연구)

  • Ma, Sang-Chull;Kong, Young-Kun;Ahn, Young-Man
    • Journal of radiological science and technology
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    • v.26 no.3
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    • pp.19-24
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    • 2003
  • We carried out studies on development and characteristic of ultrasound brast training biopsy phantom. the major finding were of follow ; (1) C type TMM was shown good homogeneity, brightness and attenuation as like human soft tissue. (2) $TiO_2$ 4.10%w/v TMM was shown good homogeneous echo texture and propagated speed as like the human Tissue. (3) $TiO_2$ type TMM was appeared lower brightness and higher penetration rate than C type TMM. Therefor, Breast TM phantom and target material TMM will be useful $TiO_2$ 4.10 %w/v TMM and C 2.09 %w/v TMM.

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Evaluation of the Adhesive Strength and the Drying Energy of Corrugated Board Using a Mixed Adhesive (혼합접착제 적용에 따른 골판지의 접착강도와 건조에너지 평가)

  • Lee, Ji Young;Kim, Chul Hwan;Kim, Eun Hea;Park, Tae Ung;Choi, Jae Sung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.3
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    • pp.51-56
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    • 2016
  • The most widely used glue in a corrugator is starch, which is a natural polymer. This material needs thermal energy to achieve a binding force, so a heating section is installed in a corrugator. However, this heating section can cause quality problems in linerboards and corrugating medium and increase the production cost because of the high cost of fossil resources. Therefore, a new adhesive that provides the binding force at lower temperatures than the conventional one must be developed. In this study, SB-latex was selected as a co-adhesive and added to the starch solution. The addition of the SB-latex was determined based on the viscosity of the new adhesive. The adhesive strength and the drying energy reduction of a corrugated board were measured to evaluate the functionalities of the new adhesive. The addition of SB-latex was determined to be under 20% of the oven-dried starch based on the viscosity of the new adhesive. The adhesive strength was improved and the drying energy was reduced by applying the new adhesive.

Thermal Characteristics of $H_2O$-NaOH Mixtures Type PCM for the Low Temperature Storage of Food and Medical Products (식.의약품 저온 저장을 위한 $H_2O$-NaOH 혼합형 잠열재의 냉축 열특성)

  • Song, Hyun-Kap;Ro, Jeong-Geun;Moon, Young-Mo
    • Journal of the Korean Solar Energy Society
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    • v.24 no.1
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    • pp.7-12
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    • 2004
  • Mixtures type PCM, $H_2O$-NaOH that has relatively large capacity of the latent heat and long duration of phase change temperature was developed and experimentally analyzed for the low temperature storage of the food and medical products. The results could be summarized as follows; 1. Borax as nucleating agent and acrylic polymer as thickening agent were added to $H_2O$ to prevent the supercooling and phase separation. 2. Phase change (solid$\leftrightarrows$liquid) duration of $H_2O$ added with NaOH was prolonged longer 50% than that of pure $H_2O$. 3. Phase change temperature of the latent heat material, $H_2O$-NaOH was $1.5\sim2^{\circ}C$ the maximum latent Heat was 279 kJ/kg at the NaOH addition of 1.3 wt.%. 4. The specific heat of $H_2O$-NaOH at the solid and liquid state was increased in proportion to the wt.% of NaOH, when NaOH of $1.15\sim1.60$ wt.% was added to $H_2O$, the specific heat of the solid state was increased from 3.19 kJ/kg to 5.84 kJ/kg and that of liquid state from 7.8 kJ/kg to 10.28 kJ/kg. 5. When NaOH of $1.15\sim1.60$ wt.% was added to $H_2O$, the total heat storage capacity composed of sensible and latent heat was $313\sim331.3$ kJ/kg and the maximum heat storage capacity was occurred at NaOH addition of 1.30 wt. %.

Influence Evaluation of Fiber on the Bond Behavior of GFRP Bars Embedded in Fiber Reinforced Concrete (섬유보강 콘크리트에 묻힌 GFRP 보강근의 부착거동에 대한 섬유영향 평가)

  • Kang, Ji-Eun;Kim, Byoung-Ill;Park, Ji-Sun;Lee, Jung-Yoon
    • Journal of the Korea Concrete Institute
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    • v.24 no.1
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    • pp.79-86
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    • 2012
  • Though steel reinforcing bars are the most widely used tensile reinforcement, corrosion problems are encountered due to the exposure to aggressive environments. As an alternative material to steel, the fiber reinforced polymers have been used as reinforcement in concrete structures. However, bond strength of FRP rebar is relatively low compared to steel rebar. It has been reported that fibers in matrix can resist crack growth, propagation and finally result in an increase of toughness. In this study, high-strength concrete reinforced with structural fibers was produced to enhance interfacial bond behavior between FRP rebar and concrete matrix. The interfacial bond-behaviors were investigated from a direct pullout test. The test variables were surface conditions of GFRP bars and fiber types. Total of 54 pullout specimens with three different types of bars were cast for bond strength tests. The bond strength-slip responses and resistance of the bond failure were evaluated. The test results showed that the bond strength and toughness increased according to the increased fiber volume.

Study on Tensile Properties of Polyamide 12 produced by Laser-based Additive Manufacturing Process (레이저 적층제조기술로 제작한 폴리아미드 12 시편의 인장특성 연구)

  • Kim, Moosun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.11
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    • pp.217-223
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    • 2019
  • The application of 3D printing technology is expanding due to the production of the complex-shape parts and the one-step manufacturing process. Moreover, various technical solutions in 3D printing are emerging through continuous research and development. Representative technologies include SLS technology, in which a desired area is sintered and laminated by irradiating a powder-type material with a laser. In addition, high-performance engineering plastic parts are being manufactured in increasing numbers. In this study, tensile specimens were fabricated from polyamide 12, a widely available polymer, and the glass bead-reinforced polyamide 12. The specimen-build orientation was divided into 0°, 45°, and 90° on the fabrication platform, and the tensile test temperature was -25℃, 25℃, and 60℃. The test results showed that the tensile modulus of both materials decreases as the build orientation becomes closer to 90°. In addition, the tensile strength of glass bead-reinforced PA12 showed more dependence on the build orientation than PA12. In addition, the tensile modulus and tensile strength decreased with increasing test temperature.

Influence of the Insulating Properties on Charge Injection Phenomena of Biaxially-Drawn Polypropylene Film (이축 연신된 폴리프로필렌 필름의 전하주입 현상이 절연특성에 미치는 영향)

  • 이준웅;김병태;박승협
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.1 no.2
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    • pp.74-81
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    • 1987
  • The reduction in dielectric strength of insulating polymer material when applying electric field is known to be substantial due to the trapped carrier effect. In this study, the carrier property of Biaxially-Drawn polypropylene, which has superior heat-resistance compared to ordinary one, is examined to improve electrical characteristics by measuring TSC spectra as a function of electric field applied to a sample of ($50{\mu}m$) thickness film. The TSC spectra in the temperature range of 303-413(K) and electric field of 2-80(MV/m) have shown no observable effect below 12(MV 1m) but TSC currents of Hetero-and Homo-peaks formed from trapped space charger and space charger injected from electrode have been observed above that point, which seems eventually lead to dielectric breakdown. Finally, this study has shown the superior dielectric proporty of Biaxially-Drawn polypropylene film compared to the non-oriented one for electrical insulation.

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Research of Oyster Shell Recycled Coating Material and its Application to Filter Bed (굴껍질을 재활용한 코팅제의 여과지 코팅 성능평가에 관한 연구)

  • Lee, Hak-Soo;Woo, Dal-Sik;Choi, Myung-Soo;Park, Duck-Weon;Yang, Jae-Sik;Cho, Yun-Sung
    • Proceedings of the KAIS Fall Conference
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    • 2009.12a
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    • pp.1026-1029
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    • 2009
  • 현재 남해안 굴양식산업은 어업인들의 중요한 소득원이 되고 있으나, 굴양식장에서 발생되는 굴패각은 처리곤란 및 악취발생으로 인해 또 다른 해양오염원으로 그 문제성이 심각하게 대두되고 있는 실정이다. 굴양식장에서 연간 약 28~30만여톤의 굴패각이 발생되고 있으며, 그 중 10~20%는 종패부착용이나 비료로 재활용되고 있고, 80~90%는 매립되거나 야적 방치된다고 보고되고 있다. 본 연구에서는 굴패각을 재활용하고자 굴껍질의 성분분석을 실시하여 나노고분자세라믹 코팅제의 세라믹 소재로써의 적용 가능성여부를 확인하였고, 경기도 P정수장 내 여과지 콘크리트 벽면에 코팅처리하여 그 성능을 확인하였다. 그 결과 패각의 굴껍질은 90%이상이 탄산칼슘($CaCO_3$)로 이루어져 있었으며, 굴껍질을 재활용한 나노고분자세라믹 코팅제는 pH 7.5~8.5로서 일반수도를 측정한 pH 7.3~7.8과 유사한 결과를 보였다. 또한, 나노고분자세라믹 코팅제의 콘크리트 벽면에 대한 부착강도는 한국산업규격에 제시된 폴리머의 방수재료 부착강도인 8~10(kg.f/$cm^2$)이상의 값이 나타남에 따라 패각의 굴껍질을 재활용한 나노고분자세라믹 코팅제의 경기도 P정수장 내 여과지 콘크리트 벽면 코팅제로써 적용이 가능한 것으로 확인 되었다.

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Blends containing two thermotropic liquid crystalline polymers: Effects of transesterification on miscibility and rheology

  • Hsieh, Tsung-Tang;Carlos Tiu;Hsieh, Kuo-Huang;George P. Simon
    • Korea-Australia Rheology Journal
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    • v.11 no.3
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    • pp.255-263
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    • 1999
  • Blends of two thermotropic liquid crystalline polymers, HX2000 and Vectra A950, were prepared by melt blending. Effects of transesterification on these blends are investigated by comparing properties of the blends with and without the addition of an inhibitor, in terms of blend miscibility and rheology. Both the uninhibited and inhibited blends are found to be largely immiscible with very limited miscibility in HX2000-rich phase. No strong evidence indicates the occurrence of transesterification in the blends in the solid state. Dynamic rheological behaviour, such as shear storage modulus (G') and shear loss modulus (G") as a function of frequency, of the blends are interpreted by a three-zone model. HX2000 shows terminal-zone and plateau-zone behaviour, whilst Vectra A950 shows plateau-zone and transition-zone behaviour. The un- inhibited blends show plateau-zone behaviour up to 50% Vectra A950 content and the inhibited blends show plateau-zone behaviour up to 60% Vectra A950 content. Compositional dependence of the complex viscosities of the uninhibited and inhibited blends displayed positive deviations from additivity, which is a characteristic feature for the immiscible thermoplastic blends. When under steady shear, both the uninhibited and inhibited blends show shear thinning behaviour and their viscosities decrease monotonically with the addition of Vectra A950. Compositional dependence of the steady shear viscosities of the two sets of blends displayed negative deviations from additivity and the uninhibited blends were more viscous than the inhibited blends for the full composition range. Although limited agreement with the Cox-Merz rule is found for the inhibited blends, these two sets of blends, in general, do not follow the rule due to their liquid crystalline order and two-phase morphology. Despite being immiscible blends, transesterification, such as polymerization, in the blends might occur during the rheological characterization, supported by the facts that uninhibited blends show HX2000-dominant behaviour at lower Vectra A950 content and are more viscous than the inhibited blends. The addition of transesterification inhibitor in such blends is advised if only physical mixing is desired.ired.

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