• Title/Summary/Keyword: Polymer Film

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Influence of Methylcellulose on Properties of Wheat Gliadin Film Cast from Aqueous Ethanol

  • Song, Yihu;Li, Lingfang;Zheng, Qiang
    • Food Science and Biotechnology
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    • v.18 no.4
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    • pp.910-916
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    • 2009
  • Present work was focused on the influence of methylcellulose (MC) on steady rheology of wheat gliadin solution and the properties of glycerol plasticized gliadin films. The presence of MC below 0.99 wt% improved viscosity and flow activation energy of the 10 wt% gliadin solution significantly. In the casting films containing 0.2 g glycerol/g dry protein, the MC component aggregated in the gliadin matrix. The blend films containing less than 7.7 wt% MC exhibited higher Young's modulus (E) and tensile strength (${\sigma}_b$) and lower elongation at break (${\epsilon}_b$) in comparison with the pure gliadin film, which was related to the intermolecular interaction between MC and gliadins, the brittle fracture of the aggregated MC component, and the increase in glass transition temperature ($T_g$) of the gliadin phase. Increasing MC content led to a slight increase in water vapor permeability (WVP) without significant influence on the moisture absorption (MA).

Analysis of Mechanical Characteristics of ionic Polymer-Metal Composite Actuators Fabricated by Casting Method (캐스팅 방법에 의해 제작한 이온성 고분자-금속 복합체 액추에이터의 기계적 특성 분석)

  • 이승기;김병목;김병규;박정호
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.3
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    • pp.144-151
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    • 2003
  • IPMC(Ionic Polymer-Metal Composite) is promising candidate material for bio-related actuators mainly due to its biocompatibility and wet and soft properties. The widely used commercialized Nafion film has a few kinds of fixed thicknesses but more various film thicknesses are required for extensive applications. Especially for the enhanced force as an actuator, the thick film is essential. Various Nafion films with thickness of 0.4-1.2mm have been prepared by casting of liquid Nafion. Also, IPMC actuators using casted Nafion films have been fabricated and the basic mechanical properties such as stiffness, displacement and force were measured and analyzed. These results can be used for the optimized design of actuators for different applications.

Order-to-disorder Behavior of Block Copolymer Films

  • Ryu, Du-Yeol;Kim, Eun-Hye;Choe, Seung-Hun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.6.2-6.2
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    • 2011
  • Block copolymer (BCP) self-assembly in a film geometry has recently been the focus of increased research interest due to their potential use as templates and scaffolds for the fabrication of nanostructured materials. The phase behavior in a thin film geometry that confines polymer chains to the interfaces will be influenced by the interfacial interactions at substrate/polymer and polymer/air and the commensurability between the equilibrium period (L0) of the BCP and the total film thickness. We investigated the phase transitions for the films of block copolymers (BCPs) on the modified surface, like the order-to-disorder transition (ODT) by in-situ grazing incidence small angle x-ray scattering (GISAXS) and transmission electron microscopy (TEM). The selective interactions on the surface by a PS-grafted substrate provide the preferential interactions with the PS component of the block, while a random copolymer (PS-r-PMMA) grafted substrate do the balanced interfacial interactions on the surface. The thickness dependence of order-to-disorder behavior for BCP films will be discussed in terms of the surface interactions.

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In-Situ Cross-linked Polymer Electrolyte Membranes from Thermally Reactive Oligomers for Direct Methanol Fuel Cells

  • Kim, Hae-Kyoung;Lee, Won-Mok;Park, Sam-Dae;Chang, Yoon-Ju;Jung, Jin-Chul;Chang, H.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.271-271
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    • 2006
  • The present article describes a novel method of preparing the sulfonated polysulfone-based PEMs for DMFC, which are excellent in film quality, proton conductivity, methanol impermeability and mechanical properties. No depression in film quality or difficulty in film preparation is observed, even though sulfonated group of the PEMs are kept as high as 70 mol %. Allyl-terminated cooligo-PESs containing the organic sulfonate groups were solvent-cast into films and then thermally treated for cross-linking. Cross-linked sulfonated polysulfone-based PEMs gave unprecedented reduction of methanol cross-over and high ionic conductivity through in-situ thermal polymerization and cross-linking of telechelic sulfonated sulfone oligomers during a membrane preparation.

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Excimer Laser Micromachining of Polymers Assisted by Liquid (액체 보조 방식의 Excimer 레이저 폴리머 미세가공)

  • Jang, Deok-Suk;Kim, Dong-Sik
    • Laser Solutions
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    • v.10 no.1
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    • pp.19-27
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    • 2007
  • Previous studies demonstrated that laser ablation under transparent liquid can result in ablation enhancement and particle removal from the surface. Although the ablation enhancement by liquid is already known for semiconductor and metal, the phenomena of polymer ablation have not been studied. In this work, tile liquid-assisted excimer laser ablation process is examined for polymer materials, such as polyethylene terephthalate (PET), polymethyl methacrylate (PMMA) with emphasis on ablation enhancement and surface topography. In the case of PET and PMMA, the effect of liquid is analyzed both for thin water film and bulk water. The results show that application of liquid increases the ablation rate of PMMA while that of PET remains unchanged even in the liquid-assisted process. However, the surface roughness is generally deteriorated in the liquid-assisted process. The surface topography is found to be strongly dependent on the method of liquid application, i.e., thin film or bulk liquid.

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A Study on Electroluminescence Device with Polymer (고분자를 이용한 전계발광소자에 관한 연구)

  • Lee, Jong-Chan;Lee, Cheong-Hak;Park, Su-Gil;Lim, Kee-Joe;Park, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1219-1221
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    • 1997
  • Poly(1,4-phenylene(1-methoxyenthylene)), organic water soluble PPV precursor was synthesized for polymer electroluminescence(EL) device. To control the molecular array, deposition method of emitter was Langmuir-Blodgett(LB). PPV precursor layer was treated thermally to conversion of PPV. Optical, electrical and EL properties of PPV LB thin film was estimated. Homogeneous light emission of greenish-yellow in PPV LB thin film can be easily confirmed under normal lighting even at low driving voltage. Polymer EL device using PPV LB thin film as emitter materials had a possibility to apply to next generation display device.

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Effect of Surface Modification of Donor Plate on the Fabrication of OLED Devices by LITI Process

  • Bae, Heung-Kwon;Kim, Jin-Hoo;Kwon, Hyeok-Yong;Lee, Yoon-Soo;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.784-786
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    • 2009
  • Thermal transfer of emitting layer from the donor film to the substrates depends on the physical interaction between the donor film, the emitting layer, and the hole-transport layer (HTL). The interfacial adhesion between the donor film and the EML, the cohesive force of the EML, and the interfacial adhesion between the EML and the HIL have to be optimized to achieve good LITI pattern quality. It was found that surface pretreatment of the donor plate was important on the laser induced thermal transfer of the emitting layer onto the HIL layer of the OLED devices.

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Thermoelectric Characteristics of Bi-Te Module with Thermal Conductivity Change (열전도율 변화에 따른 Bi-Te계 열전모듈의 열전특성)

  • Kim, Bong-Seo;Jeong, Hyun-Uk;Park, Su-Dong;Han, Dong-Hee;Lee, Hee-Woong
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.2025-2027
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    • 2005
  • Thermal conductive polymer film was adopted to reduce the fracture of module during the fabrication of thermoelectric generator. We investigated the thermoelectric output power of module with the change of thickness of polymer film, direct contact and thermal-conductive grease. It is measured that thermoelectric output power is decreased with the increasing thickness of thermal-conductive polymer film. And

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Electrochemical detection effect of hormone in body by using polymer coated boron doped diamond electrode (고분자 막이 코팅된 Boron doped diamond 전극에 의한 호르몬의 전기화학적 검출 효과)

  • Hwang, Jin-Hee;Cho, Eun-In;Park, Soo-Gil;Okajima, Takeyoshi;Ohsaka, Takeo;Fujishima, Akira
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.611-614
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    • 2003
  • The electrochemical oxidation of ascorbic acid(AA), serotonin(SE) and epinephrine(EP) have been performed at poly N,N-dimethylaniline(PDMA) film coated diamond electrode. This cationic polymer film is electrochemically deposited on boron-doped diamond electrode surface. Unlike the bard electrode, the polymer film-coated diamond electrode can well separate the oxidation potential of AA by 200mV. Thus this electrode can be successfully used for the simultaneoud detection of both species. Increases in the concentration of AA do not affect the reponse of EP and SE.

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Study on variation of electrical properties of polymer thick film resistor regarding curing temperature, printing process and substrate (경화 온도와 인쇄 공정 및 기판에 따른 폴리머 후막 저항체의 특성 변화에 대한 연구)

  • Yoo, Myong-Jae;Lee, Sang-Myong;Park, Seong-Dae;Lee, Woo-Sung;Kang, Nam-Kee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.311-312
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    • 2005
  • Applying a designed test coupon pattern for fabricating resistors various resistors were formed using PTF(polymer thick film) pastes. Aspect ratio from 0.25 to 4 were selected for fabricating resistors. Formed resistors were cured at $170^{\circ}C$ and $240^{\circ}C$. Electrical properties of fabricated resistors were measured and their values analyzed in relation to cure temperature and formed geometry via printing. Also effects of substrates used for fabricating resistors were observed.

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