• Journal of Hydrogen and New Energy
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• v.21 no.4
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• pp.307-312
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• 2010

Poly (ether sulfone)s with Bisphenol-TP and Bisphenol-AF were prepared with Bisphenol-TP <4,4-dihydroxy tetraphenyl methane>, 4-Fluorophenyl sulfone, and Bisphenol-AF <4,4-(hexafluoroisopropylidene) diphenol> using Potassium carbonate in Sulfolane at $210^{\circ}C$. Sulfonated PBTP-AF were obtained by reaction of Chlorosulfuric acid with copolymers. A series of copolymers were studied by $^1H$-NMR spectroscopy, Differential Scanning Calorimeter (DSC), and Thermo Gravimetric Analysis (TGA). Sorption experiments were conducted to observe the interaction of polymers with water and methanol.

• KEPCO Journal on Electric Power and Energy
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• v.3 no.2
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• pp.141-146
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• 2017

In this work, a simulation study on net 500 MW class of Poly-Generation was conducted for the retrofit of an aged natural gas combined cycle. An entrained gasifier which has a capacity of maximum $260,000Nm^3/h$, 50 MW class of a Polymer Electrolyte Membrane Fuel Cell, and H-class Gas Turbine were selected as key processes. After unit design for those employed processes was set up and combined, the simulation was carried out with Gate-Cycle software (Ver. 6.0) for two cases. The selected cases are a retrofit type (Poly-Gen 1) and a new type (Poly-Gen 2). It was found that the efficiency of the retrofit case is 2.7% lower than that of the new case.

• 한국신재생에너지학회:학술대회논문집
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• 2009.11a
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• pp.247-250
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• 2009

This study considers the feasibility of using the low cost assembled separator. The graphite plate has been widely used as the separator in the field of PEMFCs(Polymer electrolyte membrane fuel cell) industry because of its excellent material properties such as good corrosion resistance, good electrical conductance and so on. However, there are some problems for the commercialization due to its poor cost effectiveness for the large volume manufacturing and lack of mechanical strength. From this respect, this study has focused on the manufacturing technology in order to reduce the price for the commercialization of separator. This study also shows that the assembled separator of the suggested structure, which is composed of grafoil and PC(PolyCarbonate) materials, could be manufactured at low cost enough for the mass production. The flow fields produced by cutting foils and the base plates of the separators were simply made by mechanical work.

• Journal of the Korean Electrochemical Society
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• v.17 no.3
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• pp.201-208
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• 2014

A Pt catalyst ($Pt/G_xC_y$) supported on the hybrid supporting materials composed of graphene oxide (GO) and carbon black (C) was fabricated using polyol method to improve the durability of electrocatalysts. The electrochemical performances measured by cyclic voltammograms using three-electrode system revealed that the properly designed $Pt/G_xC_y$ catalyst exhibited higher durability than that of Pt/C catalyst without sacrificing an electrocatalytic acivity. In the oxygen reduction reaction (ORR) performed in acid solution with the rotating disk electrode, the $Pt/G_xC_y$ catalyst showed greater mass and area-specific activity than those of Pt/C catalyst.

• Journal of the Korean Ceramic Society
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• v.50 no.6
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• pp.390-395
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• 2013

Nanocrystalline CrN films were deposited on Si (100) substrates by means of asymmetric pulsed DC reactive magnetron sputtering. We investigated the growth behavior, corrosion resistance and mechanical properties of CrN films with a change in the duty cycle and pulse frequency. The grain size of the CrN films decreased from 25.4 nm to 11.2 nm upon a decrease in the duty cycle. The corrosion potentials for the CrN films by DC sputtering was approximately - 0.6 V, and it increased to - 0.3 V in the CrN films which underwent pulsed sputtering. The nanoindentation hardness of the CrN films also increased with a decrease in the duty cycle. This enhancement of the corrosion resistance and mechanical properties of pulsed sputtered CrN films could be attributed to the densification and surface smoothness of the microstructure of the films.

• Journal of Hydrogen and New Energy
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• v.30 no.6
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• pp.601-607
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• 2019

Ammonia would be formed in natural gas containing small amount of nitrogen reforming process in the process natural gas, which might damage the Pt catalyst and Prox catalyst. In the article, the effect of nitrogen contents on the formation of ammonia in the reforming process has been studied. In the experiments, Ru based and Ni based catalysts were used and the concentration of ammonia in the reformate gas at various gas hourly space velocity was measured. Experimental result shows that relatively higher ammonia concentration was measured with Ru based catalyst than with Ni based catalyst. It also shows that the concentration of ammonia increased rapidly after most of the methane converted into hydrogen. Based on the experimental results to reduce ammonia concentration it might be better to finish methane conversion at the exit position of the reforming reactor to minimize the contact time of catalyst and nitrogen with high concentration of hydrogen.

• Journal of Surface Science and Engineering
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• v.45 no.2
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• pp.75-80
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• 2012

A sputter-sublimation source was tested for high rate deposition of protective coating of PEMFC(polymer electrolyte membrane fuel cell) with high electrical conductivity and anti-corrosion capability by DC biasing of a metal rod immersed in inductively coupled plasma. A SUS(stainless steel) tube, rod were tested for low thermal conductivity materials and copper for high thermal conductivity ones. At 10 mTorr of Ar ICP(inductively coupled plasma) with 2.4 MHz, 300 W, the surface temperature of a SUS rod reached to $1,289^{\circ}C$ with a dc bias of 150 W (-706 V, 0.21 A) in 2 mins. For 10 min of sputter-sublimation, 0.1 gr of SUS rod was sputter-sublimated which is a good evidence of a high rate deposition source. ICP is used for sputter-sublimation of a target material, for substrate pre-treatment, film quality improvement by high energy particle bombardment and reactive deposition.

• Proceedings of the Korean Magnestics Society Conference
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• 2011.06a
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• pp.129-129
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• 2011

The limited understanding of the surface properties of $Pt_3Ni$ for the oxygen reduction reaction (ORR) in polymer electrolyte membrane fuel cell (PEMFC) has motivated the study of properties and electronic structures of seven layered $Pt_3Ni$ (001), (110), and (111) surfaces. The first principle method based on density functional theory (DFT) is carried out. It is found that the bulk $Pt_3Ni$ has a ferromagnetic ground state with the ordered fcc type L12 structure, which is in good agreement with other results. Non magnetic Pt has the induced magnetic moment due to the strong hybridization between 3d Ni and 5d Pt. The magnetic moment of Pt and Ni enhanced on the surface of each due to surface effect however the magnetic moment of surface Pt in the Pt-segregated Pt3Ni (111) decreased and the magnetic moment of Ni in Ni rich subsurface increased significantly. The calculated d band centers of Pt explain the possibilities for oxygen absorption and play the important roles in altering the catalytic properties. The spin polarized densities of states are presented in order to understand physical properties of Pt in different surfaces in detail.

• The Transactions of the Korean Institute of Power Electronics
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• v.15 no.1
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• pp.75-85
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• 2010

In this paper, a Z-source hybrid active power filter is proposed to compensate the harmonics and reactive power in power distribution system. The proposed system is composed of a 7th harmonics-tuned passive filter and an active power filter with a Z-source inverter topology, while voltage source PWM inverter or current source PWM inverter are applied as the power converter topology of conventional active power filters. The Z-source impedance network along with shoot through capability would ensure a constant DC voltage across the DC link. A polymer electrolyte membrane fuel cell is employed as an compensation DC energy source of the proposed system and its equivalent R-L-C circuit is modeled for simulation. As the compensation and control algorithm of the proposed system, the current synchronous detection algorithm is applied. The simulation analysis by PSIM is performed under the three-phase 220V/60Hz voltage source and 25A nonlinear diode loads. The effectiveness of the proposed the system is verified in the steady and transient states.

• Proceedings of the Korean Magnestics Society Conference
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• 2011.12a
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• pp.14-14
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• 2011

Limited understanding of the surface properties of $Pt_3Ni$ for the oxygen reduction reaction (ORR) in polymer electrolyte membrane fuel cell (PEMFC) has motivated the study of magnetic properties and electronic structures of Pt segregated $Pt_3Ni$ (111) surface during adsorption of oxygen molecule on it. The first principle method based on density functional theory (DFT) is carried out. Nonmagnetic Pt has induced magnetic moment due to strong hybridization between Ni 3d and Pt 5d. It is found that an oxygen molecule prefers bridge site with Pt rich subsurface environment for adsorption on the surface of Pt segregated $Pt_3Ni$ (111). It is seen that there is very small charge transfer from $O_2$ to Pt. The curve of energy versus magnetic moment of the oxygen explains the magnetic moments in transition states. We found the dissociation barrier of 1.07eV significantly higher than dissociation barrier 0.77eV on Pt (111) suggesting that the dissociation is more difficult on Pt segregated $Pt_3Ni$ (111) surface. The spin polarized densities of states are presented in order to understand electronic structures of Pt and $O_2$ during the adsorption in detail.