• Title/Summary/Keyword: Polymer Development

검색결과 1,390건 처리시간 0.031초

Development of SPR Gas Sensor for Small Molecules Using Molecularly Imprinted Polymer Thin Films

  • 장성우;진성일;박찬량
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 춘계학술발표대회
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    • pp.242.2-242.2
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    • 2011
  • Molecularly imprinted polymer thin films were applied to develop a gas sensor based on the surface plasmon resonance phenomenon for small gaseous molecules such as toluene and xylene. The imprinted polymer films were synthesized via photo-polymerization method using various combination of templates, functional monomers and cross-linkers. The temperature of pre-polymerization solutions and the power of UV light were controlled for optimized performance of gas sensing. The morphology and porosity of the polymer films were controlled by varying the mixing ratios of the pre-polymerization solutions and confirmed by atomic force microscopy. By fitting the adsorption/desorption sensorgrams to conventional kinetic models, the effects of different templates and cross-linkers were interpreted in term of the structural differences of the polymer networks formed on the gold film. The sensitivity and selectivity of sensors were estimated for toluene and xylene, and also for humidity and other gaseous molecules such as formaldehyde and ammonia.

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Renewable green polymers

  • Albertsson, Ann-Christine;Edlund, Ulrica;Hakkarainen, Minna;Sjoberg, John
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.121-122
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    • 2006
  • Paralleled with the development of new materials we need to develop methods and techniques to reveal the environmental interaction and impact of the new materials. Small changes in the chemical structure or product formulation may render the product less environmentally adaptable. Degradation products formed from PLLA were identified after aging in different environments and their assimilation in the biotic environment was shown. Green and degradable hydrogels could be designed from renewable hemicelluloses and lactic acid. Hemicelluloses are a renewable and highly interesting raw material source for new green polymers.

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Properties of Polymer-Modified Mortars Using VAE Redispersible Powders

  • Joseph Ango, Aaron;Yang-Seob, Soh
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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    • pp.252-255
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    • 2003
  • Recently, there is a growing trend in the United States toward replacing latex additives in polymer-modified cement mortars with redispersible polymer powders. This movement is relatively new in the U.S. but is further advanced in Europe due to the more extensive use of cement and concrete in residential construction. Hitherto, in Korea - there is a very diminutive movement towards this growing trend. Thus, there is limited availability of data on redispersible polymer powders. This study investigates the effectiveness of redispersible polymer powder on improvement of the mechanical properties of modified mortar. It was concluded from the results of the experiments that the size of the dispersed polymer particles, variations in glass transition points (Tg), and variations in minimum film formation temperature (MFT) influenced the strength development of the modified mortars, and optimum strength in modified mortars using redispersible powders can be achieved when the Tg which accounts for the degree of powder flexibility is considered.

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인공경량골재를 활용한 경량 폴리머 콘크리트의 개발 및 바닥배수구조물에의 적용 (Development of Lightweight Polymer Concrete Using Synthetic Lightweight Aggregate and Application for Bottom Draining Structure)

  • 성찬용;김영익;윤준노
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2003년도 봄 학술발표회 논문집
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    • pp.846-851
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    • 2003
  • This study was performed to develop the lightweight polymer concrete using expanded clay and perlite to improve workability, durability and chemical resistance for bottom draining structure under severe condition. This paper was composed of two parts. One is to invest the physical and mechanical properties of lightweight polymer concrete using synthetic lightweight aggregate, the other is to the develop products for bottom draining structure. Physical and mechanical test for lightweight polymer concrete was performed unit weight, compressive and flexural strength, chemical resistance, accelerated weathering test, absorption ratio and optimum mix for lightweight polymer concrete was designed. Also, products for bottom draining structures by optimum mix of lightweight polymer concrete was made draining trench of small size.

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프린팅 방법을 통한 Micro-Nano 시스템을 위한 all polymer flexible cuircuit 개발 (Development of all-polymer flexible circuit for micro-nano system using printing method)

  • 이정훈;황교일;신창용;류경주;김훈모
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2002년도 추계학술대회 논문집
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    • pp.750-753
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    • 2002
  • At present, almost circuits are wired using copper in flexible circuits. But, these circuit have limit to flexibility so it occurs fracture about cyclic bending and, thermal load of bending stress occur a circuit trouble. a study of all-polymer flexible circuits get over that problem. Established fabrication method of all-polymer circuits is photolithograph. This method can not have mass production, so this method wastes time and human effort. In this study, all polymer flexible circuits are fabricated using the inkjet process.

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폴리머 수용액 주입에 의한 난류마찰저항 감소에 대한 실험 연구 (Experimental Study on Frictional Drag Reduction of Turbulent Flow by Polymer Solution Injection)

  • 김형태;김덕수;김우전
    • 대한조선학회논문집
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    • 제40권3호
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    • pp.9-15
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    • 2003
  • An experimental study has been carried out as a basic research for development of the friction drag reduction technology for ships by polymer injection. Experimental apparatus and procedures have been devised and prepared to measure the changes of the wall friction with injection of a polymer solution and basic experimental data on the friction drag reduction are obtained for a turbulent fiat-plate boundary layer and fully-developed channel flows. Variations of the friction drag reduction with some important parameters of polymer injection, such as the concentration of polymer solution, its injection flow rate and the measuring position downstream from the injection slot, are also investigated. Important experimental data and results obtained in the present study are presented. The amount of friction drag reduction up to 50% is observed.

고흡수성 수지를 활용한 다공질 구조 콘크리트 개발을 위한 기초적 연구 (Fundamental Study on the Development of Porous Concrete Using Super Absorbent Polymer)

  • 조재현;백성진;임군수;한준희;김종;한민철
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2023년도 가을학술발표대회논문집
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    • pp.217-218
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    • 2023
  • This study is to develop porous concrete using super absorbent polymer, which possesses insolubility and high absorption capacity, as a substitute material for lightweight soil. Various mixtures were prepared using aggregates, cement, mixing water, and super absorbent polymer, and the absorption ratio and compressive strength were examined for each mixture. As the amount of super absorbent polymer added increased, the absorption ratio also increased, reaching up to 35-105%. However, the compressive strength decreased by 49.5% to 65.3%. This is believed to be due to the inherent properties of super absorbent polymer, which led to an increase in the absorption ratio but, in turn, reduced the binding strength of cement paste particles, resulting in a decrease in compressive strength.

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우주 안테나 설계용 형상기억 폴리머 시편의 전개 시험 (Deployment test of shape memory polymer specimens for space antenna design)

  • 구남서;레반르엉;안용산;유웅열;황진옥;박종규
    • 한국항공우주학회지
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    • 제45권12호
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    • pp.1007-1012
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    • 2017
  • 본 연구에서는 우주 안테나 설계용 형상기억 폴리머 시편의 전개 시험을 수행하였다. Poly(cyclooctene)을 dicumyl peroxide를 이용하여 가교시켜 PCO 형상기억 폴리머를 제조하고, 이를 이용하여 지름이 120 mm인 전개형 안테나의 축소 모델을 제작하였다. 전개 성능 시험을 위하여 원형 형태의 형상기억 폴리머 시편을 반으로 접어 임시 형상을 만든 후 두 개의 히터로 형상기억 폴리머의 유리 전이 온도보다 $15^{\circ}C$ 높은 온도로 시편을 가열하였다. 먼저 시편을 수평 설치하여 전개 실험을 수행하였다. 시편의 전개 영상을 디지털 카메라를 사용하여 촬영한 후 트래커 프로그램을 이용하여 분석하였다. 중력의 효과를 최소화하기 위하여 수직 설치하여 다시 실험을 수행하였다. 두 실험의 결과를 비교하여 형상기억 폴리머 시편의 전개 성능을 고찰하였다.

폴리모 모르터를 이용한 강화목재보의 개발 (Development of Reinforced Wood Beams Using Polymer Mortar)

  • 연규석
    • 한국농공학회지
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    • 제32권3호
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    • pp.79-86
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    • 1990
  • Based on limited number of tests on reinforced wood beams using polymer mortar in this study, following conclusions were drawn ; 1.Reinforcing compression side of wood beam using polymer mortar was effective in reducing deflection. 2.By increasing thickness of polymer mortar, effective beam stiffness was improved, but energy absorption was reduced. 3.Polymer mortar reinforcement improved compressive strength and reduced strain in compression side of the beam. Therefore, it was possible to change the failure mode from by compression in control beam to by tension in composite beams. 4.The composite beams that have more than 2cm of polymer mortar layer did not perform well because a strain redistribution and separation of meterials at interface were induced in moment span. 5.To maximize the load carrying capacity of composite beam, it is necessary to make polymer mortar and wood behave together without failing at interface. To do this, it is needed to use a polymer mortar which has high strength with such elastic modulus that is closer to elastic modulus of wood. otherwise, it is recommended to use shear connectors at interface to prevent separation of materials under ultimate load.

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리튬이차전지용 고분전해질의 무기물의 첨가에 대한 영향 (The Effect of Inorganic Material in Polymer Electrolyte for Lithium Secondary Battery)

  • 박수길;박종은;이홍기;이주성
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 추계학술대회 논문집 학회본부 C
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    • pp.822-824
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    • 1998
  • The lithium polymer battery with polymer electrolyte is expected as a safe and long cycle life battery. This paper reports primarily the recent development results of a solid polymer electrolyte, which is a key point of the secondary battery system. The new type of polymer electrolyte was prepared under a dry Ar atmosphere by dissolving $LiCIO_4$ in a matrix of EC, PC and then dispersing polyacrylonitrile(PAN). Also adding some inorganic filler $Al_2O_3$. The dispersed solution heated at $120^{\circ}C$. The polymer electrolyte were characterized by EIS(Electrochemical Impedance Spectroscopy), TGA(Thermo Gravimetric analysis), DMA(Dynamic Mechanical Analyzer), DSC (Differential Scanning Calorimetry). The lithium ion yield is 0.29 when PAN-$Al_2O_3$ which was applied DC 5mV. The ionic conductivity of PAN, PAN-$Al_2O_3$ polymer electrolytes were showed $1.0{\times}10^{-4}S/cm$, $8.4{\times}10^{-4}S/cm$ at room temperature. When inorganic filler was added in the polymer electrolyte, ionic conductivity and lithium yield more larger than without inorganic filler.

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