• Title/Summary/Keyword: Polymer Composite Material

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Electrochemical Properties of Conducting Polymer for Supercapacitor (Supercapacitor용 도전성 고분자의 전기화학적 특성)

  • 강광우;김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.332-334
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    • 2000
  • The purpose of this study is to research and develop conducting polymer(CP) composite electrode for supercapacitor. Supercapacitor cell of CP composite electrode with 1M LiClO$_4$/ PC bring out good capacitor performance below 4V. The radius of semicircle of CP composite cell with PAn composite electrode adding 30wt% acetylene black was absolutely small. The total resistance of supercapacitor cell mainly depended on internal resistance of the electrode. The discharge capacitance of supercapacitor cell with PAn composite electrode adding 30wt% acetylene black in 1st and 50th cycles was 27F/g and 31F/g at current density of 1mA/$\textrm{cm}^2$. Supercapacitor cell with PAn composite electrode adding 30wt% acetylene black performed a good cycliability.

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Electrical Properties of Supercapacitor with Polyaniline and Polythiophene (Polyaniline과 Polythiophene을 사용한 supercapaccitor의 전기적 특성)

  • 강광우;김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.487-490
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    • 2000
  • The purpose of this study is to research and develop conducting polymer(CP) composite electrode for supercapacitor. Electrochemical capacitor(supercapacitor) cell of CP composite electrode with 1M LiClO$_4$PC bring out good capacitor performance below 4V. The radius of semicircle of CP composite cell with PAn composite electrode adding l5wt%SP270(PAnS15) and PT composite electrode adding 50wt%SP270 (PTS50) was absolutely small. The total resistance of supercapacitor cell mainly depended on internal resistance of the electrode. The discharge capacitance of supercapacitor cell with PTS50(+)/PAnS15(-) in 1st and 20th cycles was 38F/g and 28F/g at current density of 1mA/cm$^2$. Supercapacitor cell with PTS50(+)/PAnS15(-) showed good capacitance and stability with cycling.

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Evaluation of Piezoelectric Properties in Pb(Zr1Ti)O3-PVDF Composites for Thick Film Speaker Application (후막 스피커 응용을 위한 Pb(Zr1Ti)O3-PVDF 복합체의 압전 특성 평가)

  • Son Yong-Ho;Kim Sung-Jin;Kim Young-Min;Jeong Joon-Seok;Ryu Sung-Lim;Kweon Soon-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.10
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    • pp.966-970
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    • 2006
  • We reported on characteristics of the piezoelectric ceramic-polymer composite for the application of the thick-film speaker. The PVDF-PZT composites were fabricated to incorporate the advantages of both ceramic and polymer with various mixing ratios by 3-roll mill mixer. The composite solutions were coated by the conventional screen-printing method on ITO electrode coated PET (Polyethylene terephthalate) polymer film. After depositing the top-electrode of silver-paste, 4 kV/mm of DC field was applied at $120^{\circ}C$ for 30 min to poling the composite films. The value of $d_{33}$ (piezoelectric charge constant) was increased when the PZT weight percent was increased. The maximum value of the $d_{33}$ was 24 pC/N at 70 wt% PZT. But the $g{33}$ (piezoelectric voltage constant) showed the maximum value of $32mV{\cdot}m/N$ at 65 wt% of PZT powder. The SPL (sound pressure level) of the speaker fabricated with the 65:35 composite film was about 68 dB at 1 kHz.

A Study on the Additive Manufacturing Process using Copper Wire-Nylon Composite Filaments (구리 와이어-나일론 복합소재 필라멘트를 이용한 적층제조 공정에 관한 연구)

  • Kim, Ye Jin;Kim, Seok;Cho, Young Tae
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.21 no.5
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    • pp.1-8
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    • 2022
  • Fused deposition modeling (FDM), based on stacking a continuous filament of polymer or composite materials, is well matured and is thus widely used in additive manufacturing technology. To advance FDM-based 3D printing technology, the mechanical properties of additively manufactured composite materials must be improved. In this study, we proposed a novel FDM 3D printing process using metal wire-polymer composites, enabling enhanced mechanical properties. In addition, we developed a new type FDM filament of copper wire wrapped in nylon material for stable 3D printing without thermal damage during the printing process. After FDM printing of the copper wire-nylon composite filament, we conducted a tensile test to investigate the mechanical behavior of the printed composite materials. The experimental results confirmed that the tensile strength of the 3D-printed metal wire-polymer composites was higher than that of the conventional single polymer material. Thus, we expect that the FDM printing process developed in this study may be promising for high-load-bearing applications.

Microstructural Properties of the Polymer/MWCNT Transparent Conduction Film Fabricated on the $50{\mu}m$ Kepton Substrate ($50{\mu}m$ 켑톤 기판에 성막된 Polymer/MWCNT 투명 전도막의 미세구조)

  • Jang, Kyung-Uk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.253-253
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    • 2010
  • The Polymer/MWCNT composite films were fabricated by air-spray method under the 2 kg/$cm^2$ pressure using the multi-walled CNTs solution and the polymer on a $50{\mu}m$ kepton film substrates. We obtained the composite films which were sprayed with the MWCNT dispersion. In order to analysis the microstructure for the fabricated Polymer/MWCNT film, we used the X-ray diffraction (XRD) and SEM.

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$MoSi_2$/SiC Ceramic Composites Prepared by Polymer Pyrolysis (고분자 열분해에 의한 $MoSi_2$/SiC 세라믹 복합체)

  • 김범섭;김득중;김동표
    • Journal of the Korean Ceramic Society
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    • v.37 no.8
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    • pp.805-810
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    • 2000
  • The formation, microstructure and properties of MoSi2/SiC ceramic composites by polymer pyrolysis were investigated for the application of heating element material. Polymethylsiloxanes were mixed with Si, SiC, MoSi2 as filler and ceramic composites prepared by pyrolysis in N2 atmosphere at 1320~145$0^{\circ}C$ were studied. Dimensional change, density variation and phases were analyzed and correlated to the resulting material properties. Microstructures of ceramic composite prepared by polymer pyrolysis were composed of MoSi2, SiC and silicon oxycarbide glass matrix. Depending on the pyrolysis conditions, ceramic composites with a density of 86~90 TD%, a fracture strength of 213~284 MPa, a thermal expansion coefficient of 4~7$\times$10-6 were obtained. The electrical resistivity of the specimen decreased with increasing of temperature up to 50$0^{\circ}C$.

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The Electrical Characteristic of Composite Film for Lithium Secondary Battery by adding DMSO (DMSO 첨가에 따른 리튬이차전지용 복합필름의 전기적 특성)

  • 박수길;김종진;이창진;김상욱;김현후;임기조;이주성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.269-272
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    • 1997
  • The Lithium ion secondary battery has been developed for high energy density of portable electrical device and electronics. Among the many conductive polymer materials, the positive active film for Li polymer battery system was synthesized successfully from polyphenylene diamine(PPD) by chemical polymerization in our lab. And PPD-DMcT(2, 5-dimercapto-1, 3, 4-thi-adiazole) composite flim conductive material, at high temperature was also prerared with the addition of dimethylsulfoxide(DMSO). The surface morphology and thermal stability of prepared composite flim was carried out by using SEM and TGA, respectively. Electrochemical and electrical conductivity of composite flim were also discussed by cyclic voltammetry and four-probe method in dry box(<27pm). And the electrode reaction mechanism was detected and analyzed from the half cell unit battery system.

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An Experimental Study on the Behavior of Carbon Fiber Grid Reinforced Flexural Members (탄소섬유그리드 보강 휨부재의 거동에 대한 실험적 연구)

  • 박제용;안동준;정상균;윤순종
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 1999.11a
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    • pp.154-159
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    • 1999
  • In this paper we present tile results of an experimental investigation on the physical and mechanical properties of carbon fiber grid, polymer mortar, and carbon fiber grid reinforced plain concrete flexural members. In order to repairing and reinforcing damaged and/or deteriorated existing concrete structural members, new materials have been developed and utilized in the construction industries. But the physical and mechanical behaviors of the material are not well understood. To use the material effectively various aspects of the material must be throughly investigated analytically as well as experimentally. In this investigation we found the physical and mechanical properties of carbon fiber grid and polymer mortar which are directly utilized in the repair and reinforcement design of damaged or deteriorated concrete structures. In addition, we also investigate the strengthening effect of carbon fiber grid on the plain concrete flexural test specimens. It was found that the material can be used to repair and strengthen the concrete structures effectively.

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