• E2M - 전기 전자와 첨단 소재
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• 제10권5호
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• pp.461-466
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• 1997

In this paper, we developed the new non-rubbing liquid crystal (LC) alignment techniques in the cell with slanted non-polarized ultraviolet (UV) light irradiation on polyimide (PI) film. It is shown that the uniform alignment for nematic (N) LC is obtained by using slanted non-polarized UV light irradiation on PI surface. We successfully obtained that the pretilt angle of NLC is generated about 3.3 degree in the cell with slanted non-polarized UV light irradiation with 70 degree on PI surface, for the first time. It is considered that the pretilt angle generation in NLC is attributed to interaction between the LC molecular and the PI, which is broken the polymer by slanted non-polarized UV irradiation. Therefore, we concluded that the uniform LC alignment is attributed to anisotropic dispersion force due to photo depolymerization with slanted non-polarized UV light irradiation on PI surface.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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• pp.514-517
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• 2002

We investigated response characteristics of twisted nematic (TN) cell with different nematic liquid crystals (NLCs) and cell gap d on a rubbed polyimide (PI) surface. High transmittance and fast response time of the TN cell on the rubbed PI surface were achieved by using high birefringence (${\Delta}n$) and low cell gap d. The response time of TN cell on the rubbed PI surface was measured 5.1 ms. The transmittance and response time of the TN cell on the rubbed PI surface decreased with decreasing ${\Delta}nd$.

• 한국전기전자재료학회논문지
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• 제11권12호
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• pp.1128-1132
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• 1998

We have investigated the relationship between the polar anchoring energy and the surface order parameter in nematic liquid crystal (NLC), 4-n-pentyl-4-cyanobiphenyl (5CB), on the two kinds of the weakly rubbed polyimide (PI) surfaces. The observed polar anchoring energy of 5CB is approximately 2${\times}10^{-4}(J/m^2$) and then increases with increasing the rubbing strength (RS) on weakly rubbed surface (RS=57mm) with side chain at $30^{\circ}C$; same results are obtained on weakly rubbed PI surface without side chain. The surface order parameter of 5CB on rubbed PI surfaces increases with increasing the RS at a weak rubbing region. The surface order parameter of 5CB is strongly related to the characteristics of PI material. Consequently, we suggest that the polar anchoring energy of NLC is strongly attributed to the surface order parameter on rubbed PI surfaces.

• 한국전기전자재료학회논문지
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• 제12권1호
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• pp.75-80
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• 1999

In this study, we have investigated the relationship between the generation of pretilt angle and the polarization component in cells with UV light irradiation on polyimide (PI) surface. It was found that the generated pretilt angle is about $1.4^{\circ}$ with S-polarized UV light irradiation of $75^{\circ}$ on PI surface; it may be attributed to the asymmetry triangular of polymer surface with oblique S-polarized UV light irradiation on PI surface. Also, we measured that the generated pretilt angle is about $2.0^{\circ}$ with oblique P polarized UV light irradiation of $75^{\circ}$ on PI surface. Consequently, we suggest that the generated pretilt angle of the NLC is attributed to the interaction between the LC molecules and the polymer surface with oblique polarized UV light irradiation on PI surface.

• 마이크로전자및패키징학회지
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• 제29권2호
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• pp.59-64
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• 2022

연성인쇄회로기판에 사용되는 스크린 프린팅(screen-printing, SP) Ag/폴리이미드(polyimide, PI) 구조의 필 테스트 시 필링 속도 및 박막 적층 구조가 필 강도에 미치는 영향을 분석하기 위해, PI/SP-Ag, PI/SP-Ag/전해도금 Cu, 전해도금 Cu/SP-Ag/PI의 3가지 적층 구조에 대해 필링 속도에 따른 90° 필 테스트를 수행하였다. PI 박막을 필링하는 2가지 구조에서는 필링 속도에 상관없이 필 강도가 거의 일정하게 유지된 반면, Cu/Ag 금속 박막 필링 구조에서는 필링 속도가 증가할수록 필 강도가 크게 증가하는 경향을 보였다. 이는 필링 속도에 따른 90° 굽힘 소재의 소성변형에너지 차이에 기인한 것으로 판단된다. 인장속도에 따른 인장 시험 결과, 변형 속도 증가에 따른 Cu/Ag 금속 박막의 유동응력 및 인성 증가가 Cu/Ag/PI 구조에서의 필링 속도에 따른 금속 박막의 90° 굽힘 소성변형에너지 및 필 강도 증가의 주 원인으로 판단된다. 반면, 점탄성 소재인 PI의 경우 변형 속도에 따른 기계적물성 차이가 금속에 비해 상대적으로 작아서, PI/Ag 및 PI/Ag/Cu 구조에서는 필링 속도에 따른 PI의 90° 굽힘 소성변형에너지 및 필 강도 변화가 상대적으로 적은 것으로 판단된다.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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• pp.633-636
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• 2008

A series novel films of polyimide (PI) and co-polyimide (Co-PI) containing fluorine with colorless, flexible properties was prepared by a two-step process from various commercial aromatic monomers such as 4,4'-(Hexafluoro iso propylidene) diphthalic anhydride (6FDA), 2,2'-Bis(Trifluoromethyl) benzidine (TFDB), 2,2-bis(3-amino-4-hydroxyphenyl) hexafluoropropane (AH6FP) and Bis(4-(3-aminophenoxy)phenyl)sulfone (BAS). Furthermore, these obtained transparent and flexible Co-PI films exhibited excellent thermal stability with the decomposition temperature (at 5% weight loss) around of $500^{\circ}C$ and the glass transition temperature ($T_g$) in the range of $275-350^{\circ}C$.

• 한국광학회지
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• 제20권5호
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• pp.281-287
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• 2009

편광법을 사용하여 패턴이 있는 LCD 유리기층위에 놓여 있는 러빙된 PI(polyimide)의 광학이방성을 분석하였다. 투과형 편광계를 사용하여 0.4 nm 이하의 극히 작은 위상지연의 크기와 광축의 방향을 정밀하게 측정하였다. 온도에 따르는 광학이방성의 미세변화를 위상지연의 크기 및 광축 방향의 변화곡선으로 나타내고 간단한 광학모델을 사용하여 설명하였다.

• 폴리머
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• 제31권2호
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• pp.117-122
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• 2007

본 연구에서는 제자리 중합에 의해 합성된 기상성장 탄소나노섬유/폴리이미드(VGCNFs/PI) 복합재료 필름의 기계적, 전기적 특성과 열안정성을 만능재료 시험기와 체적저항기, 열중량분석기를 통해 관찰하였다. 그 결과, VGCNFs 일정량 첨가되었을 때 복합재료 필름의 인장강도가 증가한 것을 관찰할 수 있었다. VGCNFs/PI 복합재료 필름의 체적저항 값은 VGCNFs 첨가량이 증가할수록 감소하였으며, 전기적 percolation threshold는 VGCNFs 함량 1과 3 wt% 형성되었는데, 이는 복합재료 내부에서 VGCNFs 상호간 네트워크의 형성으로 인하여 전기적 경로가 만들어졌기 때문이라 판단된다. VGCNFs가 PI 복합재료 필름의 열안정성은 순수한 이미드 필름보다 VGCNFs가 첨가됨에 따라 향상되었으며, 이는 충전제로 사용한 VGCNFs가 PI 수지에 잘 분간됨에 따라 복합재료의 가교화에 영향을 주어 VGCNFs/PI 복합재료 필름의 열안정성이 향상된 것으로 판단된다.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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• pp.1584-1587
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• 2008

We proposed a technique controlling continuously pretilt angle in full range with high process margin. The proposed method is characterized by tuning thickness of heterogeneous polyimide (PI) layer that homeotropic PI is mixed with planar PIs.

• 한국레이저가공학회지
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• 제13권3호
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• pp.13-18
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• 2010

In this paper, polyimide (PI) surface was modified by UV Laser with a low laser fluence and investigated changes of surface geometry and chemical characteristics by SEM (scanning electron microscope), X-ray diffraction (XRD), XPS (x-ray photoelectron spectroscopy) and the measurements of contact angle of water. PI surface was peeled off and modified with microstructure fabrications by photochemical ablation over the laser fluence of 50 mJ/cm2. As laser fluence increased, delamination of PI surface was occurred largely and strongly. In chemical characteristics, the O/C and N/C atomic ratios increased and contact angle decreased from $80^{\circ}$ to $40^{\circ}$.