• Title/Summary/Keyword: Polyester resin

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Sputtering에 의한 polyester 직물의 박막내구성 개선을 위한 수지처리 효과 (The Effect of Resin Treatment for Improving of the Metal Thin Membrane Fastness on Polyester Fabrics by Sputtering)

  • 구강;전상민;송병갑;박영미
    • 한국염색가공학회지
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    • 제18권3호
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    • pp.31-41
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    • 2006
  • Functional properties are available with sputtering. But sputtering treatment alone cannot got a good fastness performance to washing, rubbing and light. This research was objected to investigate optimum condition by sputtering on polyester through various processing conditions such as ion current and treatment time, and then various resin treated onto metal coated polyester fabrics in order to increase washing fastness of metal membrane. As the results, the optimum conditions revealed 1500 mA of ion current, 2 min of treatment time in sputter, and suitable resin concentrations were 2% of o.w.s (on the weight of solution) in resin treatment. Therefore, we could get enhanced anti-static effect and flex stiffness as well as washing fastness in sputtered polyester fabric with various resin treatment, for example, melamine and polyurethane.

산업부산물을 이용한 강섬유보강 폴리에스터 수지복합체의 제조 및 역학적 특성 (Fabrication and Mechanical properties of Steel Fiber Reinforced Polyester Resin Composites Utilizing by-Products (Fly Ash))

  • 박승범;윤의식
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1992년도 봄 학술발표회 논문집
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    • pp.35-40
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    • 1992
  • Results of an experimental study on the manufacture, the workability and mechanical properties of steel fiber reinforced polyester resin composites utilizing industrial waste products are presented in this paper. The fly ash polyester resin composites using steel fiber, fly ash and calcium carbonic acid (CaCo3), unsaturated polyester resin, styrene monomer, cobalt octate and methyl ethyl ketone peroxide, fine and coarse aggregates are prepared with various filler~binder rations, binder rates and mixing conditions. As a test results, the workability of steel fiber reinforced polyester resin composites are considerably dropped with increasing fly ash-binder ratio and steel fiber volume. And compressive, flexural strength and bending toughness of the composites are remarkably improved with augmenting fiber contents.

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섬유강화 복합재료의 물성향상을 위한 몰비가 다른 매트릭스 수지에 관한 연구 (Matrix Resin Systems with Different Molar Ratios to Improve the Properties of Fiber-reinforced Composites)

  • 이상효;이장우
    • 폴리머
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    • 제24권4호
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    • pp.459-468
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    • 2000
  • 유리 또는 아라미드 섬유를 보강재로 사용한 섬유강화 복합재료의 기계적 물성을 증진시키기 위하여 복합재료 적층판을 서로 다른 매트릭스 수지와 섬유를 선정하여 이들의 인장, 굴곡 특성을 조사하였다. 불포화 폴리에스테르와 개질된 표면의 아라미드 섬유 복합재료의 경우, 굴곡 물성의 최대값은 실란 농도가 0.5 wt%일 때 관찰되었다. 불포화 폴리에스테르 수지와 유리섬유 복합재료의 인장 물성은 vinylester계가 가장 높게 나타났으며, 굴곡물성은 isophthalic계가 가장 높은 물성을 나타내었다. 유리섬유와 불포화 폴리에스테르 수지 복합재료의 기계적 물성을 증진시키기 위해 겹침 적층판과 기계적 물성과의 상관 관계에 대해서도 연구가 병행되었다.

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폴리우레탄 액상고무를 이용한 불포화 폴리에스테르 모르터의 인성개선에 관한 실험 연구 (An Experimental Study on Toughening of Unsaturated Polyester Mortar Using Polyuretane Liquid Rubber)

  • 박준철;배근철;박준호;최영준;김화중
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2001년도 봄 학술발표회 논문집
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    • pp.371-376
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    • 2001
  • The purpose of this study is to investigate toughening of unsaturated polyester resin by addition of polyuretane liquid rubber. In general, unsaturated polyester resin has strong brittleness in spite of its high strength Therefore; it is difficult to use unsaturated polyester mortar for the place where impact resistance is demanded. In this study, it was evaluated strength and Gf by using to polyurethane liquid rubber. As a result, the toughness of unsaturated polyester mortar was increased by polyuretane liquid rubber.

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HNBR compound와 RFL 처리된 Polyester 섬유의 접착 연구 (Adhesion Between HNBR Compound and Polyester Fabric Treated with RFL)

  • 이주희;강윤희;박득주;김욱수;손우정;변영후;김원호
    • Korean Chemical Engineering Research
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    • 제48권5호
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    • pp.568-573
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    • 2010
  • 본 연구에서는 polyester 섬유표면에 활성기를 부여하기 위한 전처리제로 isocyanate를 이용하여 농도에 따른 접착력을 평가하였다. 이 후 HNBR compound와 polyester fabric의 접착 시 접착력이 우수한 RFL 용액용 latex 선정 및 F/R mole ratio, F/R resin/latex 무게 비에 따른 실험을 진행하였다. 그 결과 전처리제의 농도가 7 wt%인 경우 가장 높은 접착력을 나타내었으며, RFL 용액용 latex로는 HNBR 컴파운드와 상용성이 높은 NBR latex가 우수한 결과를 나타내었고 F/R mole ratio, FR resin/latex 무게비가 각각 1/1, 20%일 때 가장 높은 접착력을 나타내었다. 또한, peel test와 FTIR 분석을 이용해 RF resin의 열처리 온도에 따른 접착강도와 spectra의 peak 변화를 평가해 본 결과 최적의 열처리 온도는 $200^{\circ}C$이었다.

불포화 폴리에스터 수치의 고온경화특성 연구 (High Temperature Cure Behavior of Unsaturated Polyester Resin)

  • 김형근;오제훈;이대길
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2000년도 추계학술발표대회 논문집
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    • pp.38-41
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    • 2000
  • High temperature cure characteristics of polyester resin systems were investigated by isothermal and dynamic differential scanning calorimetries. During isothermal scanning, the experimental procedure was modified to reduce the initial Boss of heat. no kinetic equation from the isothermal experiment was compared with that from the dynamic experiment.

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철도차량용 레졸계 페놀수지의 내열특성 비교 (Fire Characteristics Comparison of Resol-type Phenolic Resin for Interial Materials of Passenger Train)

  • 이철규;이덕희;정우성
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2004년도 춘계학술대회 논문집
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    • pp.277-283
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    • 2004
  • The time to ignition, heat release rate characteristics and carbon monoxide yield of fiber reinforced and sandwich phenol resin were investigated with cone calorimeter. The fire characteristics of unsaturated polyester, mostly being applied to the existing passenger train, and phenolic resin were compared. Thermal gravimetric analysis(TGA) was used to monitor the degree of thermal decomposition for the phenolic resin. According to the cone calorimeter data, the time to ignition, heat release rate and CO yield was faster and higher as the external heat flux increase. Under the same heat flux, the time to ignition of sandwich type phenolic resin was shorter than that of fiber reinforced. The result of comparison between unsaturated polyester and phenolic resin was that phenolic resin was shown to have better fire resistance than that of unsaturated polyester.

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폴리에스테르의 첨가제 분석법(I) (Analytical Method of additive in Polyester (I))

  • 정종화;이경희
    • 분석과학
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    • 제12권1호
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    • pp.84-88
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    • 1999
  • A method to analyze additives in a polyester resin has been studied by utilizing a centrifuge and a thin layer chromatography. Identification of the separated organic and inorganic compounds were carried out by spectrophotometers, such as NMR, UV-VIS, IR and XRD. For the polyester resin studied in this research contained organic and inorganic compounds which were found to be a dimer form of 2-phenylbenzoazole and an anatase form of $TiO_2$, respectively.

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강섬유 보강 플라이애쉬.폴리에스터 수지복합체의 역학적 특성에 관한 실험적 연구 (An Experimental Study on the Mechanical Properties of Steel Fiber Reinforced Fly Ash.Polyester Resin Composites)

  • 박승범;조영찬
    • 콘크리트학회지
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    • 제5권4호
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    • pp.156-166
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    • 1993
  • 본 연구는 산업폐기물인 플라이애쉬를 충전재로 사용한 강섬유보강 폴리에스터 수지 복합체의 워커빌리티 및 그 역학적 특성을 구명하고, 그 제조방법을 실험적으로 검토한 것이다. 동복합체는 강섬유, 충전재(플라이애쉬, 중질탄산칼슘), 불포화 폴리에스터수지(스티타이렌 모노머), 경화촉진제(코발트옥테이트), 촉매(MEKPO) 및 굵은 골재와 잔골재를 사용하여 제조하였고, 배합조건별로 그 특성을 검토하였다. 연구결과, 플라이애쉬$\cdot$폴리에스터 수지복합체의 경우, 플라이애쉬-결합재비의 증가에 따라 압축, 인장, 휨강도 및 경화수축은 현저히 개선되었고 강섬유 보강 플라이애쉬$\cdot$폴리에스터 수지복합체의 경우 워커빌리티는 플라이해쉬-결합재비 및 강섬유혼입율 증가에 따라 저하하였으나, 압축, 휨강도 및 휨인성은 섬유혼입율 증가에 따라 현저히 증가되었다.

성숙도 방법을 이용한 불포화 폴리에스터 수지 폴리머 콘크리트의 압축강도 예측 (Prediction of Compressive Strength of Unsaturated Polyester Resin Based Polymer Concrete Using Maturity Method)

  • 최기봉;김남길;이윤수;연규석
    • 한국농공학회논문집
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    • 제59권6호
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    • pp.19-27
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    • 2017
  • This study investigated to predict the compressive strength of unsaturated polyester resin based polymer concrete using the maturity method. The test results show that the development of the compressive strength increased exponentially until an age of 24 hours. After 24 hours, the development of the compressive strength just increased gradually. This test result shows that the strength of unsaturated polyester resin based polymer concrete was developed mainly at the early age. Estimated datum temperature of unsaturated polyester resin based polymer concrete was $-20.67^{\circ}C$ which was much lower than of datum temperature ($-10^{\circ}C$) of Portland cement concrete. Also, this study result shows that the existing maturity index associated with Portland cement concrete was not applicable for polymer concrete because curing time of Portland cement concrete is different clearly with curing time of polymer concrete. The cause of different curing time was that there were different curing mechanisms between Portland cement concrete and polymer concrete. In order to best apply the experimental data to a model, CurveExpert Professional, the commercial software, was used to determine the predictive model regarding the compressive strength of unsaturated polyester resin based polymer concrete. As a result, Gompertz Relation or Weibull Model was an appropriate model as a predictive model. The proposed model can be used to predict the compressive strength, especially, it is more useful when the maturity is in the range between $40^{\circ}C{\cdot}h^{0.4}$ and $900^{\circ}C{\cdot}h^{0.4}$.