• Macromolecular Research
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• v.17 no.5
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• pp.289-295
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• 2009

Low viscosity aromatic hyperbranched polyester epoxy resin (HTBE) was synthesized by the reaction between epichlorohydrin (ECH) and carboxyl-end hyperbranched polyester (HTB) which was prepared from inexpensive materials $A_2$ (1,4-butanediol glycol, BEG) and $B_3$ (trimellitic anhydride, TMA) by pseudo one-step method. The molar mass of the HTB was calculated from its acid value by "Recursive Probability Approach". The degree of branching (DB) of the HTB was characterized by model compounds and $^1H$ NMR-minus spectrum technology, and the DB of the HTB was about $0.47{\sim}0.63$. The viscosity and epoxy equivalent weight of the HTBE were $3,600{\sim}5,000\;cp$ and lower than 540 g/mol respectively. The reaction mechanism and structure of the $AB_2$ monomer, HTB and HTBE were investigated by MS, $^1H$ NMR and FTIR spectra technology. The molecular size of HTBE is under 8.65 nm and its shape is ellipsoid-like as determined by molecular simulation.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2004.08a
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• pp.249-257
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• 2004

Drying and curing characteristics of PCM resins using the induction heater and short-wave infrared emitter module was studied to develop a compact oven system for the high speed CCL and post-treatment equipment. Drying of the polyester resins using the induction heater and infrared heater showed that the blistering tendency of polyester resin coating increased regardless of additives and colors of resins as the heating rate and/or dry film thickness increased. The blistering of polyester resin coating layer occurred when the heating speed was over than $25^{\circ}C/sec$ for the dry film thickness of $19\~20um$, which is the typical thickness of finish coating in CCL. So did it when the heating speed was over than $40^{\circ}C/sec$ for the dry film thickness over than 10 um. The heating efficiency of paint coated steels by the infrared heating was strongly dependent on the colors of paint coating and generally increased for the dark surface and/or coating. But the faster drying of the PCM resin coatings increased the blistering tendency of coating layer. The blistering limit for the typical finish coating by the infrared heating was estimated as the heating rate slower than $20^{\circ}C/sec$ regardless of colors of PCM resins.

• Textile Coloration and Finishing
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• v.11 no.5
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• pp.22-29
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• 1999

The increase in color depth of polyester fiber dyed with black disperse dyes was investigated with respect to the kinds of resins and alkali treatment. The color depth of the dyed polyester fiber increased continuously according to the concentration of resins coated onto the fabrics. The alkali treatment to polyester fiber before dyeing also enhanced the color depth. It was thought that the polyester fiber was hydrolyzed by alkali resulting micropores on the sample. And the following treatment with a resin, Jet Black T-101, to the polyester fiber increased the color depth much higher. The successive process of alkali treatment, dyeing and Jet Black T-101 treatment could give the best color depth to polyester fiber. Although the alkali treatment reduced the tensile strength of polyester fiber, the color depth of polyester fiber enhanced sufficiently within the range of practically acceptable weight loss and strength. To analyze the micropore on the polyester fiber formed by alkali treatment, nitrogen porosimeter was used. As the weight loss of polyester fiber treated with alkali increased, the BET(Brunauer-Emmett-Teller) surface area, total pore volume, and average pore size of the sample increased.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.10b
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• pp.1115-1120
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• 2000

The purpose of this study is to investigate toughening of unsaturated polyester resin by addition of liquid rubber. In general, unsaturated polyester liquid has strong brittleness in spite of if high strength Therefore; it is difficult use polyurethane liquid rubber for the place where impact resistance is demanded. In this study, it was evaluated strength, impact resistance and fracture toughness by adding to polyurethane liquid rubber(0~25%). As a result, it was found that a tendency to be increase bearing impact and fracture toughness as polyurethane liquid rubber increased but strength was decreased.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2001.10a
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• pp.83-86
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• 2001

This paper presents an investigation of the contribution of fibers in energy absorption during impact and the effect of resin types on properties of the high strength polyethylene (Spectra-900 PE) composite. In high strength polyethylene fiber, main impact energy absorbing mechanism was tensile breakage and deformation of fiber. Two types of resin were examined : Unsaturated polyester (UP) and Epoxy. Tensile and 3-point bending test have been performed to investigate the changes of mechanical properties. In tensile and flexural testes, the Spectra Composite prepregged with UP showed higher properties than Spectra Composite prepregged with epoxy.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.05a
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• pp.332-335
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• 2004

Polymethyl Methacrylate(PMMA) mortars using EPS solution-based binders are prepared with various unsaturated polyester resin(UP) contents of binder, and tested for working life. heat exothorm temperature, length change. compressive strength and temperature dependence of compressive strength. As a result, the working life of PMMA mortar is lengthened with raising UP content of binder. Length change of the mortar was condensed from expansion to shrinkage with increasing UP content, and non shrinkage of the mortar is obtained at about UP content of $2.5\%$. The compressive strength of the mortar is increased with an increase in the UP content and reach maximum at UP content of $5\%$. However thermal resistance improvement of the mortar by increasing UP content was not recognized. UP resin was recommended as an effective agent for shrinkage control and strength development of PMMA mortar.

• Advances in nano research
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• v.4 no.1
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• pp.15-29
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• 2016

A low cost environmentally benign surface coating binder is highly desirable in the field of material science. In this report, castor oil based hyperbranched polyester/bitumen modified fly ash nanocomposites were fabricated to achieve the desired performance. The hyperbranched polyester resin was synthesized by a three-step one pot condensation reaction using monoglyceride of castor oil based carboxyl terminated pre-polymer and 2,2-bis (hydroxymethyl) propionic acid. Also, the bulk fly ash of paper industry waste was converted to hydrophilic nano fly ash by ultrasonication followed by transforming it to an organonano fly ash by the modification with bitumen. The synthesized polyester resin and its nanocomposites were characterized by different analytical and spectroscopic tools. The nanocomposite obtained in presence of 20 wt% styrene (with respect to polyester) was found to be more homogeneous and stable compared to nanocomposite without styrene. The performance in terms of tensile strength, impact resistance, scratch hardness, chemical resistance and thermal stability was found to be improved significantly after formation of nanocomposite compared to the pristine system after curing with bisphenol-A based epoxy and poly(amido amine). The overall results of transmission electron microscopic (TEM) analysis and performance showed good exfoliation of the nano fly ash in the polyester matrix. Thus the studied nanocomposites would open up a new avenue on development of low cost high performing surface coating materials.

• Journal of Adhesion and Interface
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• v.22 no.2
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• pp.63-68
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• 2021

Unsaturated Polyester Resin (UPR) is in general used as a resin to prepare for composite materials with reinforcing materials such as glass fibers. UPR, a thermosetting resin, is used in industry to prepare for sheet molding compound (SMC) molding prepreg that has excellent productivity and is advantageous for mass production among various molding methods of composite materials. The fiber-reinforced composite material using UPR as a matrix material is light and has the advantage of excellent physical properties, but it is weak against impact and is fragile. Four types of polyurethane were synthesized and added to UPR resin to overcome the shortcomings.

• Journal of the Korean Society of Clothing and Textiles
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• v.11 no.1
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• pp.51-62
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• 1987

In this study, electrostatic behavior of polyester and nylon fabric treated with anti-static agents were investigated. The effects of the concentration of the agents and curing conditions on the electrostatic charge of the fabrics were studied. And washfastness, lightfastness and physicalproperties of the treated fabrics were also investigated. The results were as follows: 1) Polyethylene glycol alkylester was more effective in antistatic behavior than polyethylene laurylphosphate, and polyester is more effective in anti-static behavior than nylon. 2) Concentration of anti-static agents were suitable in concentration of $4\%$. 3) Glyoxal resin was more effective in anti-static behavior than melamine resin, and it was also good in the retaing anti-static behavior after treatments of lightfastness and washfastness. 4) As the condition of curing treatment, $190^{\circ}C$, 1min. for glyoxal resin and $130^{\circ}C$, 4min. for melamine resin is appropriate. 5) In comparison of anti-static behavior according to treating conditions, the simultaneous treatment was more effective than any other treatments. 6) Change of electrostatic charge of anti-static nylon cloths after treatments of lightfastness and washfastness increased greatly in above 10 laundering time and 20 fade-O-meter time. 7) In physical properties according to concentration of treating agents. decrease of physical properties scarcely appeared in concentration of treating agents $4\~5\%$.

• Textile Coloration and Finishing
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• v.19 no.1 s.92
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• pp.53-60
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• 2007

In order to optimize the process for development of super deep black fiber, the silica-containing polyester fabric, SN2000, was investigated in terms of mass reduction process by sodium hydroxide, selection of high color strength dyes, and resin treatment. As the results, the mass reduction condition which used 15g/L of sodium hydroxide at $120^{\circ}C$ was determined and Dianix Deep Black Plus was selected for the best deep coloration at around 5% owf. Contrary to the prevailed understanding that the additional use of chromatic dyes would enhance the deep coloration, four kinds of chromatic dyes such as yellow, red, blue, and green dyes did not make great effect on the deep coloration. To increase the effect, the commercial resin that has low refractive index was used additionally and the resin made it possible to lower the lightness of the fabrics down to 8.7 which was generally accepted for super highly deep black fabric.