• Title/Summary/Keyword: Polychlorinated biphenyls (PCBs)

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Distribution Characteristics of Polychlorinated Biphenyls in Sediments inside Jeju Harbor (제주항내 퇴적물의 PCBs 분포특성)

  • Heo, Ryun-Yong;Kam, Sang-Kyu;Cho, Eun-Il
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.22 no.2
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    • pp.220-227
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    • 2016
  • In this paper, polychlorinated biphenyls (PCBs) were measured in surface sediments collected three times (June, October, December, 2013), inside Jeju Harbor as major harbors of Jeju Island. The concentration of PCBs inside Jeju Harbor was in the range of 1.62~4.45 (mean) ng/g on a dry weight basis and the levels were very low. In the analysis of PCBS homologue patterns, high-chlorinated PCB congeners were dominant in surface sediments inside Jeju Harbor, indicating that their sources were originated from shipping activity. In the relationships between PCBs concentrations and particle size (mud, sand and gravel) in surface sediments, PCBs concentrations were higher in the sediments with higher mud content, indicating that higher PCBs were distributed with increasing sediments of fine gradules. The PCBs concentrations in surface sediments in this study were very low, compared with ER-L (effect range-low) and TEL (threshold effects level) among sediment quality guideleines (SQGs) applied in foreign countries, such as USA, Canada, and Australia, etc), indicating that their biological effects on the bottom organisms in marine environment were expected to be very low.

Distribution of PCBs in Surface Sediments inside Seogwipo and Hallim Harbors of Jeju Island, Korea (제주도 서귀포항 및 한림항내 표층퇴적물의 PCBs 분포)

  • Cho, Eun-Il;Heo, Ryun-Yong;Lee, Min-Gyu;Kam, Sang-Kyu
    • Journal of Environmental Science International
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    • v.26 no.5
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    • pp.639-649
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    • 2017
  • Measurements of polychlorinated biphenyls (PCBs) were taken in surface sediments inside Seogwipo and Hallim Harbors of Jeju Island, Korea, to evaluate their distribution. These harbors typically have heavy ship traffic. The samples were collected three times (in June, October, and December, 2013). PCB concentrations in sediments from Seogwipo Harbor were higher than in those from Hallim Harbor, but both levels were very low, compared with those in other parts of the world. Sedimentary PCB levels had a strong correlation with organic carbon and fine granule mud content. PCB concentration values in the examined surface sediments were much lower than Sediment Quality Guidelines (SQGs) such as ER-L (Effect Rrange-Low), TEL (Threshold Effects Level) and ISQG (Interim Sediment Quality Guideline)-low value applied in countries, such as USA, Canada, and Australia. This suggests that the PCBs did not have significant biological effects on benthic organisms in the marine environment.

Evaluation of Polychlorinated Biphenyls and Organochlorine Insecticide Residues in Waters, Sediments and Crucian Carps in Soho Lake (서호(西湖)의 수질 , 저니토(底泥土) , 붕어중(中) Polychlorinated Biphenyls 및 유기염소계(有機鹽素系) 살충제의 잔류평가(殘留評價))

  • Park, Chang-Kyu;Hwang, Eul-Chul
    • Korean Journal of Environmental Agriculture
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    • v.1 no.2
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    • pp.105-115
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    • 1982
  • Environmental samples contaminated with elemental sulfur(waters 22, sediments 20, crucian carps 19) collected from Soho Lake during the period of Sep. 1981 to Apr. 1982 were analyzed for polychlorinated biphenyls(PCBs) and organochlorine insecticides by GLC-ECD. Elemental sulfur was found to interfere in the residue analysis of environmental samples and the sulfur was eliminated, prior to analysis, with copper powder. PCBs residues in Soho lake were temporarily characterized as Aroclor 1254 and were analyzed at minimum detectable quantity of 0.04 ng by derivatizing PCBs to decachlorobiphenyl(DCB). PCBs were positively detected in all samples and its residue levels in waters, sediments, and crucian carps were $0.015{\sim}0.15$ ppb, $0.038{\sim}0.088$ ppm and 0.091 ppm, respectively. The residue levels of PCBs in all samples but sediments at central and outlet site of the lake were higher than those of total p,p'-DDT. The residue levels of PCBs in waters varied with inlets, i.e. those at right inlet site were three times of those at left inlet site. The main source of PCBs residues in the environmental samples of Soho Lake was not evident by present work.

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Remediation of Soil Contaminated with Persistent Organic Pollutants through Subcritical Water Degradation (아임계수 분해를 이용한 난분해성 물질로 오염된 토양의 정화 연구)

  • Choi, Jae-Heon;Lee, Hwan;Lee, Cheol-Hyo;Kim, Ju-Yup;Oh, Seok-Young
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.2
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    • pp.113-119
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    • 2015
  • This study examined remediation of soil contaminated with polychlorinated biphenyls (PCBs) and other persistent organic pollutants by using subcritical water. Our results showed that removal efficiency of PCBs from soil and treatment temperature were linearly proportional under subcritical conditions. The removal efficiency as increased as reacting period increased. PCBs contaminating fine particles in soil were less effectively removed than those in entire contaminated soil. Reaction of the zero-valent iron and PCBs under subcritical condition produced dechlorinated product, where most of the PCBs were oxidised while little remained as dechlorinated. Other organic pollutants, such as TPH, BTEX, TCE/PCE, and chlorpyrifos, were removed by more than 90% at $300^{\circ}C$. Considering removal efficiency and identification of by-products, we suggest that subcritical water treatment may be effectively applied to soils contaminated with various persistent organic pollutants.

IN VIVO EFFECT OF PCBS (POLYCHLORINATED BIPHENYLS) ON EROD ACTIVITY

  • Min, Kyung-Nan;Cho, Min-Jung;Sheen, Yhun-Yhong
    • Proceedings of the Korean Society of Toxicology Conference
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    • 2002.05a
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    • pp.131-131
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    • 2002
  • PCBs are wide spread persistent environmental pollutants that exert a broad spectrum of toxic effects. PCBs includes 209 possible congeners differing in extent and position of chlorination of their aromatic rings. In order to understand the toxic mechanism of PCBs, we have tested the effect of PCB on the EROD activity in vivo.(omitted)

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PCBS IN KOREAN ADIPOSE TISSUE AND THEIR ENDOCRINE DISRUPTING EFFECTS

  • Kim, Dae-Hyun;Oh, Seung-Min;Ham, Byung-Woo;Chung, Kyu-Hyuck
    • Proceedings of the Korean Society of Toxicology Conference
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    • 2001.10a
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    • pp.177-177
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    • 2001
  • Polychlorinated biphenyls(PCBs) are members of the halogenated aromatic group of environmental pollutants. Because of their unique physical and chemical properties, notably their stability and widespread use, PCBs are sidely distributed and transported throughout the global environment. In fact, residues of PCBs have been identified in air, water, aquatic and marine sediments, and human tissue samples.(omitted)

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Immunotoxicity of Polychlorinated Biphenyls (Aroclor 1254) in Mouse Splenocytes (마우스 비장세포에서의 Polychlorinated Biphenyls(Aroclor 1234)의 면역 독성)

  • 반상자;안광수;김주환;임종준;김수연;기미경;이명숙;조수열;김영훈
    • Toxicological Research
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    • v.19 no.4
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    • pp.277-283
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    • 2003
  • Polychlorinated biphenyls (PCBs) has been widely used as plasticizer, insulator, lubricant, paint and ink. The persistence of PCBs in the environment and their bioaccumulation in living organism make a raise concerns regarding their toxic effects in immune system and subsequent effects on human health. However little has been known about effect of PCB, an endocrine disrupter, on splenocytes. In this study, for identifying the effect on the organs and immune cell of mice by the concentration and time of commercial PCB mixture (Aroclor 1254), each 3 mice were tested at the concentration of 3, 30, 300, 1,000 mg/kg respectively, and their organ's weight were measured in 4, 7, 14 days, respectively. Also according to concentration and time, PCB was evaluated for the effects on splenocyte viability and lipopolysaccaride (LPS) and concanavaline A (Con A)-induced splenocyte proliferation on mice spleen. In liver and lung, there were significantly defferent by concentration and time of PCB (p < 0.0001). In respect of concentration of PCB, no significant effects on mice's liver by Aroclor 1254 concentration below than 300 mg/kg were observed except at the concentration of 1,000 mg/kg doses (p < 0.0001). But there was not significant different change in mice spleen by concentration and time of PCB (p=0.2206) and the mode of weight change of spleen was different to of liver and of lung. Viabilities of splenocytes were decreased following treatment with high concentration of PCB. Also, LPS and Con A-induced cell proliferations were decreased by Aroclor 1254 at 1,000 mg/kg. These data suggest that Aroclor 1254 is the immunotoxic compound that may have an effect on mouse immune system.