• Title/Summary/Keyword: PolyUrea

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Experimental Study on Bond Behavior of Retrofit Materials by Bond-Shear Test (부착전단 실험에 의한 보강재료의 부착거동 실험 연구)

  • Ha, Ju-Hyung;Yi, Na-Hyun;Cho, Yun-Gu;Kim, Jang-Ho Jay
    • Journal of the Korea Concrete Institute
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    • v.24 no.1
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    • pp.45-52
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    • 2012
  • A variety of retrofit material such as CFRP, GFRP, and PolyUrea have been developed for strengthening RC structures and infrastructures. From previously reported research results, the capacity of strengthened concrete structures was dictated by the behavior of the interface between retrofit material and concrete. In this study, bond-shear test was carried out to estimate the bond behavior between retrofit material and concrete using a newly developed test grip. The test results of load and slip relation and energy absorption capacity of each retrofit material were obtained. These test results will provide basic information for retrofit material selection to achieve target retrofit performance.

Durability Performance Evaluation of PolyUrea for Seismic Retrofitting of RC Structures (구조물 내진 보강용 폴리우레아의 내구 성능 평가)

  • Cho, Chul-Min;Kim, Jang Jay Ho;Lee, Doo-Sung;Kim, Tae-Kyun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.3
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    • pp.1-8
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    • 2017
  • An experimental study is needed a reinforcing method for seismic load to apply for RC structures because a lot of earthquakes have frequently happened in the world and those also collapsed infrastructures or damaged human lives. The reinforcing effect of PolyUrea (PU) appeared to be excellent under blast and impact about RC structures. In this study, Stiff Type PolyUrea (STPU) had developed by manipulating the ratio of the components of prepolymer and hardener of PU. And the durability performance evaluation of STPU for deterioration and chemical resistance has been performed. Acid environmental exposure test and ultraviolet (UV) exposure test have been performed as the durability performance evaluation for STPU. Concrete carbonation exposure test and freezing and thawing test for concrete coated with STPU have been performed. The experimental result showed that STPU has high resisting capacity and durability in all tests. Therefore, STPU would be used as seismic reinforcement materials.

Preparation and Properties of Waterborne Poly(urethane-urea) Ionomers -Effect of the Type of Neutralizing Agent-

  • Yang, Jung-Eun;Lee, Young-Hee;Koo, Young-Seok;Jung, Young-Jin;Kim, Han-Do
    • Fibers and Polymers
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    • v.3 no.3
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    • pp.97-102
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    • 2002
  • A series of waterbome poly(urethane-urea) anionomers were prepared from isophorone diisocyanate (IPDI), polycaprolactone diol (PCL), dimethylol propionic acid (DMPA), ethylene diamine (EDA), and triethylamine (TEA), NaOH, or Cu($(COOCH_3)_2$) as neutralizing agent. This study was performed to decide the effect of neutralizing agent type on the particle size viscosity, hydrogen bonding index, adhesive strength, antistaticity, antibacterial and mechanical properties. The particle size of the dispersions decreased in the following order: TEA based samples (T-sample), NaOH based samples (N-sample), and Cu($(COOCH_3)_2$) based sample (C-sample). The viscosity of the dispersions increased in the order of C-sample, N-sample, and T-sample. Metal salt based film samples Of and C-sample) had much higher antistaticity than TEA based sample. By infrared spectroscopy, it was found that the hydrogen bonding index (or fraction) of samples decreased in the order of T-sam-pie, N-sample, and C-sample. The adhesive strength and tensile modulus/strength decreased in the order of T-sample, N-sam-pie, and C-sample. The C-sample had strong antibacterial halo, however, T- and N-samples did not

Preparation and Properties of Waterborne Polyurethane-Urea/Poly(vinyl alcohol) Blends for High Water Vapor Permeable Coating Materials

  • Yun, Jong-Kook;Yoo, Hye-Jin;Kim, Han-Do
    • Macromolecular Research
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    • v.15 no.1
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    • pp.22-30
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    • 2007
  • High water vapor permeable coating materials were prepared by blending aqueous poly(vinyl alcohol) (PVA) solution with waterborne polyurethane-urea (WBPU) dispersions synthesized by prepolymer mixing process. Stable WBPU/PVA dispersions were achieved at PVA content below 30 wt%. As the water soluble polymer PVA content increased, the number and density of total micro-pores (tunnel-like/isolated micro-pores) formed after the dissolution of PVA in water increased, and the water vapor permeability of coated Nylon fabric also increased significantly. Using WBPU/water soluble polymer PVA blends as a coating material and then dissolving PVA in water was confirmed to be an effective method to obtain prominent breathable fabrics.

Material Performance Evaluation of PolyUrea for Structural Seismic Retrofitting (구조물 내진 보강용 폴리우레아의 재료 성능 평가)

  • Cho, Chul-Min;Choi, Ji-Hun;Rhee, Seung-Hoon;Kim, Tae-Kyun;Kim, Jang-Ho Jay
    • Journal of the Korea Concrete Institute
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    • v.29 no.2
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    • pp.131-139
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    • 2017
  • Recently, earthquakes have frequently occurred near Korean peninsula. An experimental study is needed for developing a reinforcing method for seismic strengthening to apply to RC structures. Recently, PolyUrea (PU) as structural reinforcement materials has been receiving great interest from construction industry. The reinforcing effect of PU appeared to be excellent under blast and impact as well as earthquakes. In this study, Flexible Type PolyUrea (FTPU) developed in preceding studies was modified to develop Stiff Type PolyUrea (STPU) by varying the ratio of the components of prepolymer and hardener of FTPU. The material performance evaluation has been performed through hardening time, tensile strength and percent elongation test, pull-off test, and shore hardness test. The experimental results showed that STPU has higher tensile strength and lower elongation than FTPU. Therefore, STPU coating agent can be used for semi-permanent products. By using STPU with Fiber-Reinforced Polymer (FRP) on concrete columns, confinement effect can be enhanced to maximize seismic strength and ductility.

The Effect of Urea on Volumetric and Viscometric Properties of Aqueous Solutions of Poly(ethylene oxide)

  • 전상일;백경구
    • Bulletin of the Korean Chemical Society
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    • v.19 no.11
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    • pp.1194-1198
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    • 1998
  • The density and the viscosity of aqueous PEO solutions are observed with the several concentrations of PEO at 20 ℃. The effects of urea on them are also observed. The apparent and the partial specific volumes of PEO are calculated from the density data, which result that the polymer-polymer interaction is dominating in the binary aqueous PEO solutions, while the polymer-solvent interaction is dominating in the ternary aqueous urea-PEO solutions. It is explained by the urea induced breakage of the structured water originated from the hydrophobic interactions and the binding of the urea to the PEO chain. The concentration dependence of relative viscosity and the density dependence of fluidity is also discussed with the concept of the polymersolvent and the polymer-polymer interactions of aqueous urea-PEO solutions.

Transport of Some Solutes in Blood Plasma Through Poly(2-Hydroxyethyl Methacrylate) Hydrogel Membrane (혈장내 염의 Poly(2-Hydroxyethyl Methacrylate) 격막 투과현상)

  • Jee Jong Gi;Jhon Mu Shik;Ree Tai Kyue
    • Journal of the Korean Chemical Society
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    • v.22 no.5
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    • pp.304-310
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    • 1978
  • The relative permeabilities, distribution coefficients and diffusion coefficient of some salts which are important components in blood plasma through a poly(HEMA) membrane were measured. The crosslinker which was used for preparing the membrane was tetraethylene glycol dimethacrylate(TEGDMA), the weight percentage of the latter was about 2.8. We found that the diffusion coefficients ($D_m$) of the solutes decrease exponentially with increasing molecular weight, and also that $D_m$'s decrease linearly (except urea) with cylindrical radius (a). These facts were explained by a sieve pore flow model. The relative permeability and diffusion coefficient of urea at various temperature were larger than those of other solutes such as glycine, ${\beta}$-alanine, D-glucose, saccharose and maleic acid. The result indicates that the poly(HEMA) membrane might be suitable for hemodialysis application.

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A Study on the Thermal Performance change due to amount of Carbon Fiber in Poly-Urea Waterproofing Material (폴리우레아 방수재의 탄소섬유함량에 따른 내열성능 변화추이 연구)

  • Park, Wan-Goo;Park, Jin-Sang;Choi, Su-Young;Kim, Dong-Bum;Kim, Byoung-Il;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.126-127
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    • 2017
  • This study investigates the effect of improving the heat resistance performance when carbon fiber is mixed in the polyurea coating material. A tensile strength test method was carried out with the carbon fiber mixed polyurea specimens at an interval of 7, 14, and 21 days after heat treatment at 140±2℃. The test results showed that there was a significant decrease in the tensile strength performance. While the elongation and tensile performance decreased greatly, it was confirmed nevertheless the overall performance was maintained. This study proposes that mixing carbon fiber to the polyurea resin can effectively secure long-term heat resistance, thereby solving the problem of deterioration of physical properties caused by exposure to ultraviolet rays.

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