• Title/Summary/Keyword: Poly-Ethylene

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Maleic Anhydride Effect on the Properties of Poly(ethrlene terephthalate)/Maleic Anhydride-Grafted PP/Poly(styrene-co-maleic anhydride) Ternary Blends (Poly(ethylene terephthalate)/Maleic anhydride-grafted PP/Poly(styrene-co-maleic anhydride) 삼상블렌드의 성질에 있어서의 무수말레인산의 효과)

  • 윤관한;이형욱;박오옥
    • Polymer(Korea)
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    • v.25 no.2
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    • pp.226-232
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    • 2001
  • The properties of poly(ethylene terephthalate) (PET)/maleic anhydride-grafted polypropylene (MAgPP)/poly(styrene-co-maleic anhydride)(PScMA) ternary blend were investigated. The ternary blend was immiscible based on the glass transition temperatures measured by dynamic mechanical analyzer (DMA). The degradation of MAgPP during melt mixing for 30 min at 280$^{\circ}C$ did not affect the properties of the ternary blend. The interaction among the components was confirmed from the rheological properties, which was increased with the PSCMA contents. In terms of the mechanical properties, it was observed to satisfy the mixture rule for a multiple system.

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Phase Behavior of Ternary Mixture of Poly(ethylene-co-octene) - Ethylene - 1-Octene (Poly(ethylene-co-octene) - Ethylene - 1-Octene 3성분계 혼합물의 상거동)

  • Lee, Sang-Ho;Sohn, Jin-Eun;Chung, Sung-Yoon;Han, Sang-Hoon
    • Elastomers and Composites
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    • v.41 no.2
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    • pp.116-124
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    • 2006
  • Cloud-point data to $160^{\circ}C$ and 1,000 bar are presented with poly(ethylene-co-15.3 mole% octene) copolymers ($PEO_{15}$) in pure 1-octene and mixtures of ethylene - 1-octene. The cloud-point curves for $PEO_{15}$ - ethylene - 1-octene mixture dramatically increase in pressure to as high as 1,000 bar with an increasing ethylene concentration. At ethylene concentrations less than 18 wt%, the ternary mixture has bubble- and cloud-point curves. As the ethylene concentration of the ternary mixture increases, the bubble-point curve and the single-phase region reduce. The reduction in the single phase region with increasing ethylene concentrations is the result of reduced dispersion interactions between $PEO_{15}$ and the mixed solvent. The single-phase region decreases with increasing temperatures when ethylene concentrations are lower than 36 wt%, whereas the single-phase region increases with temperatures at ethylene concentrations greater than 50 wt%. At ethylene concentrations greater than 50 wt% the effect of the polar interactions of the mixed solvent, which is unfavorable to dissolve PEO, is greater than the effect of the density of the mixed solvent. Therefore, the cloud-point pressures increase with a decreasing temperature. However, at ethylene concentrations less than 50 wt%, the cloud-point pressures decrease with temperature, because the effect of the polar interactions is less than the density effect.

Kinetics of Isothermal Crystallization in Poly(ethylene oxide) and Poly(styrene-co-acrylic acid)Blends (Poly(ethylene oxide)/Poly(styrene-co-acrylic acid) Blends의 등온 결정화 속도에 관한 연구)

  • Lee, Sang-Cheol;Lee, Mu-Seong;Jo, Won-Ho
    • Korean Journal of Materials Research
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    • v.1 no.3
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    • pp.151-155
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    • 1991
  • The kinetics of isothermal crystallization in blends of poly(ethylene oxide) (PEO) and poly(styrene-co-acrylic acid) (SAA) has been examined as a function of the blend ratio, the copolymer composition, and the crystallization temperature, based on the Avrami eauation. The Avrami exponents were mostly chose to 2, independent of the crystallization temperature. The crystallization rate of PEO in PEO/SAA blends decreased with the increase of SAA content. And also, the higher the acrylic acid content in the SAA copolymer, 7he slower the crystallization rate of PEO in the blends.

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Antistatic Property and Crystalization Behavior of Polyester Fiber (폴리에스터섬유의 제전성 및 결정화 거동)

  • Kim, Moon-Chan;Lee, Cheal-Gyu
    • Analytical Science and Technology
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    • v.12 no.5
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    • pp.436-440
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    • 1999
  • Antistatic property and crystallization behavior of antistatic poly(ethylene terephthalate) (PET) were studied by feeding antistatic agents into polycondensation reactor. Glass transition and melting temperature of antistatic PET were decreased by poly(ethylene glycol) (PEG) component of antistatic agent. The crystallization rate of antistatic PET was inhibited by decreasing crystallization temperature. Thermal properties and crystallization behavior was affected POAG content of antistatic agent rather than sodium alkylsulfonate of it. The main antistatic component of antistatic agent was POAG. The main role of sodium alkylsulfonate was increasing melt viscosity of antistatic poly(ethylene terephalate) polymer.

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Effect of Preheat-Treatment Temperature on Weight Loss of Poly(Ethylene Terephthalate) Fiber by Low-Temperature Oxygen Plasma Treatment (산소 저온 플라즈마 처리한 PET 직물의 열처리 온도가 감량에 미치는 영향)

  • Kang Koo;Tomiji Wakida;Mitsuo Ueda
    • Textile Coloration and Finishing
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    • v.7 no.3
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    • pp.11-14
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    • 1995
  • Effect of low temperature oxygen plasma treatment on the weight loss of poly (ethylene terephthalate) fiber heat-treated at various temperatures was studied using two kinds of plasma apparatus. Investigation was done on the basis of the increased crystallinity up to about 160 $^{\circ}C$, above this temperature weight loss increased significantly with the increased crystallinity in spite of crystallinity increased according to the increased heat-set temperature. The weight loss showed a minimum at about 160 $^{\circ}C$ just like in dyeing of poly(ethylene terephthalate) fiber with disperse dye.

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Fine Structural Formation and Physical Properties of Poly(ethylene 2,6-naphthalene dicarboxylate) Fibers Prepared by Vibrating Annealing (Poly(ethylene 2,6-naphthalene dicarboxylate) 섬유의 진동 열처리에 따른 미세구조 형성과 물성)

  • 이화경;김경효;조현혹
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.251-254
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    • 2002
  • Poly(ethylene 2,6-naphtalenen dicarboxylate)(PEN)에 관한 연구는 1948년 Cook 등에 의해 처음으로 PET의 benzene ring을 naphthalene ring으로 대체하는 새로운 합성방법이 보고되었다[1]. 그 역사는 비교적 오래 되었지만 1980년대까지 PEN의 구조에 관한 연구는 거의 이루어지지 않았다. 그러나 1980년대 후반이 되면서 소위 "high performance polymers"에 관한 관심의 증가로 매우 좋은 기계적 물성과 열 안정성을 가지고 있는 PEN은 매우 중요한 소재로 인식되었다[2]. (중략)

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Dyeing Properties of 4-Amino-4′-fluorosulfonylazobenzene Disperse Dyes on Poly(ethylene terephthalate)

  • Koh, Joonseok;Cho, Dae Hwan
    • Fibers and Polymers
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    • v.5 no.2
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    • pp.134-138
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    • 2004
  • Dyeing properties of a series of 4-amino-4'-fluorosulfonylazobenzene disperse dyes on poly(ethylene terephthalate) (PET) were investigated. Build-up properties and color properties on PET were examined. In particular, the 4-aminoazobenzene dyes containing a nitro group instead of a fluorosulfonyl group at 4'-position were also synthesized in order to compare their dyeing properties on PET with that of 4'-fluorosulfonyl analogues.

Preparation and characterization of Poly (ethylene terephthalate) (PET) (가지 달린 poly (ethylene terephthalate) (PET)의 제조와 물성에 관한 연구)

  • Kim, Soochan;Park, Sungshin;Sooyun Jung;Kim, Jungsoo;Seungsoon Im
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.203-204
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    • 2003
  • Generally, polymeric foam has many advantages, such as light-weight, good impact absorptivity and adiabatic properties. Poly (ethylene terephthalate) PET has good recyclability and no toxicity. Hence, if we make foam of PET, it could be used for various applications such as heat insulating material, recyclable packing material, and food vessel. Thus these properties are attractive interests to manufacturers. (omitted)

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